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An acetal is a molecule with two single bonded oxygens attached to the same carbon atom.
Traditional usages distinguish ketal from acetals; where the acetal has one R group as H-. Current accepted terminology classifies ketals as a subset of acetals. For engineering applications, "acetal" is shorthand for the plastic polyoxymethylene, which is a polyacetal.
Formation of an acetal occurs when the hydroxyl group of a hemiacetal becomes protonated and is lost as water. The oxonium ion that is produced is then rapidly attacked by a molecule of alcohol. Loss of the proton from the attached alcohol gives the acetal. Acetals are stable compared to hemiacetals but their formation is reversible as with esters. As a reaction to create an acetal proceeds, water must be removed from the reaction mixture or it will hydrolyse the product. The formation of acetals reduces the total number of molecules present and therefore is not favourable with regards to entropy. A way to improve this is to use an orthoester as a source of alcohol. Aldehydes and ketones undergo a process called acetal exchange with orthoesters to give acetals. Water produced along with the acetal product is used up in hydrolysing the orthoester and producing more alcohol to be used in the reaction.
Acetals are important in nature, for example in solution the most stable form of glucose is its cyclic hemiacetal and maltose is an acetal made from two glucose units. Acetaldehyde diethyl acetal is an important flavouring compound in distilled beverages.
Acetal based plastics
Advantages of use of acetal based plastics
Disadvantages of use of acetal based plastics
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Acetal". A list of authors is available in Wikipedia.|