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Gold(III) chloride, traditionally called auric chloride, is one of the most common compounds of gold. It has the formula AuCl3. The Roman numerals in the name indicate that the gold has an oxidation state of +3, which is the most stable form for gold in its compounds. Gold also forms another chloride, gold(I) chloride (AuCl), which is less stable than AuCl3. Also, chloroauric acid (HAuCl4), the product formed when gold dissolves in aqua regia, is sometimes referred to rather loosely as "gold chloride", "acid gold trichloride" or even "gold(III) chloride trihydrate".
AuCl3 → AuCl + Cl2 (>160 °C)
3 AuCl → AuCl3 + 2 Au (>420 °C)
HCl(aq) + AuCl3(aq) → H+AuCl4−(aq)
Ionic chlorides such as KCl will also form the AuCl4− ion with AuCl3.
Aqueous solutions of AuCl3 react with alkalis such as sodium hydroxide to form a precipitate of impure Au(OH)3, which will dissolve in excess NaOH to form sodium aurate (NaAuO2). If gently heated, Au(OH)3 decomposes to gold(III) oxide (Au2O3) and then to gold metal.
Gold(III) chloride is most often prepared by direct chlorination of the metal at high temperatures:
Gold(III) chloride is one of the most common gold compounds and it is therefore used as the starting point for the synthesis of many other gold compounds, for example the water-soluble cyanide complex KAu(CN)4:
Gold(III) salts, especially NaAuCl4 (made from AuCl3 + NaCl), provide a non-toxic alternative to mercury(II) salts as catalysts for alkyne reactions. One important reaction of this sort is the hydration of terminal alkynes to produce methyl ketones, for example:
Ketones are generally formed in over 90% yield under these conditions. Also useful is the related amination of alkynes which can use gold(III) catalysis.
In recent years AuCl3 has begun to attract the interest of organic chemists as a mild acid catalyst for other reactions such as alkylation of aromatics and a conversion of furans to phenols (see below). Such reactions find use in organic synthesis and in the pharmaceutical industry. For example, 2-methylfuran (sylvan) undergoes smooth alkylation by methyl vinyl ketone at the 5-position:
The reaction gives a 91% yield in only 40 minutes at room temperature, using only 1 mole% of AuCl3 in acetonitrile. This yield is noteworthy since both the furan and the ketone are normally very sensitive to side-reactions such as polymerisation under acidic conditions. In some cases where alkynes are present, a phenol may be formed:
The reaction undergoes a complex rearrangement that leads to formation of the new aromatic ring
Gold(III) chloride should be handled wearing gloves and goggles; direct contact with the material should be avoided.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Gold(III)_chloride". A list of authors is available in Wikipedia.|