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An organic acid is an organic compound with acidic properties. The most common organic acids are the carboxylic acids whose acidity is associated with their carboxyl group -COOH. Sulfonic acids, containing the group OSO3H, are relatively stronger acids. The relative stability of the conjugate base of the acid determines its acidity. Other groups can also confer acidity, usually weakly: -OH, -SH, enol group, and the phenol group. In biological systems organic compounds containing only these groups are not generally referred to as organic acids.
Generally, organic acids are weak acids and do not dissociate completely in water, whereas the strong mineral acids do. Lower molecular weight organic acids such as formic and acetic acids are miscible in water, but higher molecular weight organic acids such as benzoic acid are insoluble in molecular (neutral) form.
On the other hand, most organic acids are very soluble in organic solvents. p-toluenesulfonic acid is a comparatively strong acid used in organic chemistry often because it is able to dissolve in the organic reaction solvent.
Exceptions to these solubility characteristics exist in the presence of other substituents which affect the polarity of the compound.
Simple organic acids like formic or acetic acid are used for oil and gas well stimulation treatments. These organic acids are much less reactive with metals than are strong mineral acids like HCl or mixtures of HCl and HF. For this reason, organic acids are used at high temperatures or when long contact times between acid and pipe are needed.
Biological systems create many and more complex organic acids such as L-lactic, citric and D-glucuronic acids that contain hydroxyl or carboxyl groups. Human blood and urine contain these plus organic acid degradation products of amino acids, neurotransmitters and intestinal bacterial action on food components. Examples of these categories are alpha-ketoisocaproic, vanilmandelic and D-lactic acids, derived from catabolism of L-leucine and epinephrine (adrenaline) by human tissues and catabolism of dietary carbohydrate by intestinal bacteria, respectively.
Commonly used organic acids
CH3COOH (Acetic acid)
HCOOH (Formic acid)
C6H8O7 (Citric acid)
C2H2O4 (Oxalic acid)
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Organic_acid". A list of authors is available in Wikipedia.|