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Poly(hydridocarbyne) (PHC) is one of a class of carbon-based random network polymers primarily composed of tetrahedrally hybridized carbon atoms, each having one hydride substituent, exhibiting the generic formula [HC]n. PHC is made from bromoform, a liquid halocarbon that is commercially manufactured from methane. At room temperature, poly(hydridocarbyne) is a dark brown powder. It can be easily dissolved in a number of solvents (tetrahydrofuran, ether, toluene etc.), forming a colloidal suspension that is clear and non-viscous, which may then be deposited as a film or coating on various substrates. Upon thermolysis in argon at atmospheric pressure and temperatures of 110°C to 1000°C, decomposition of poly(hydridocarbyne) results in hexagonal diamond (Lonsdaleite).
The novelty of PHC (and its related polymer poly(methylsilyne)) is that the polymer may be readily fabricated into various forms (e.g. films, fibers, plates) and then thermolized into a final hexagonal diamond ceramic.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Poly(hydridocarbyne)". A list of authors is available in Wikipedia.|