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97 Current news of Wiley-VCHrss
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Rare earth orthoferrite LnFeO3 nanoparticles for bioimaging
Magnetic resonance imaging (MRI) has emerged as one of the most powerful clinical imaging tools because of its superb spatial resolution and soft tissue contrast, especially when using contrast agents. In the European Journal of Inorganic Chemistry, scientists have presented a new kind of ...
Bioinspired enzyme model with a redox switch
Coupled oxygen transfer and electron transfer reactions that use cofactors are enzymatic reactions of crucial significance to all lifeforms from bacteria to vertebrates. In the European Journal of Inorganic Chemistry, scientists have introduced a model for the enzyme sulfite oxidase. It is based ...
Total synthesis of ajoene, a biologically active component in oil extracts of garlic
Fresh garlic extracts contain a variety of healthy organosulfur compounds, among which ajoene forms a major oil-extractable ingredient. Now, chemists in the United Kingdom have synthesized ajoene from readily available components for the first time. The results show that ajoene is accessible on a ...
Modulating photo- and electroluminescence in a stimuli-responsive molecular dye
Controlling the excited electronic states in luminescent systems remains a challenge in the development of fluorescent and phosphorescent dyes. Now, scientists in Japan have developed a unique organic fluorophore that changes its emission color without loss of efficiency when externally ...
Chemo-enzymatic synthesis of fluorinated antibiotics
Fluorinated structures make up more than 20 percent of modern drugs, but benign and fast fluorination schemes are scarce. In a study scientists have now combined dynamic kinetic resolution and nucleophilic fluorination for the asymmetric synthesis of florfenicol, a veterinary antibiotic. After ...
Superflexible aerogels are highly efficient absorbents, thermal insulators, and pressure sensors
Airy, Airier, Aerogel. Until now, brittleness has limited the practical application of these delicate solids, which consist almost entirely of air-filled pores. This may now change: Japanese researchers have now introduced extremely elastic aerogels that are easy to process and can be produced at ...
Efficient chain transfer for 3D-printing of tough photopolymers
An ever-growing number of coatings, including varnishes and printing inks, as well as tooth fillings, are cured with light. Yet, homogenous, tailored, polymer networks cannot be produced, and the materials tend to be brittle, which limits the use of photopolymers in applications like 3D printing, ...
Soft crystal gives a multifunctional, all-in-one material
Crystals are brittle and inelastic? A novel class of smart, bendable crystalline organic materials has challenged this view. Now, scientists have engineered a molecular soft cocrystalline structure that bends and twists reversibly and without disintegration when stimulated by high temperature, ...
Supramolecular complex formation: Anthracene macrocycle and C60 fullerene
Saturn is the second largest planet in our solar system and has a characteristic ring. Japanese researchers have now synthesized a molecular “nano-Saturn”. As the scientists report, it consists of a spherical C60 fullerene as the planet and a flat macrocycle made of six anthracene units as the ...
Highly luminescent inks made from copper–iodine hybrid clusters with aggregation-induced emission
Chinese scientists have turned copper–iodine cluster molecules into aggregated, highly luminescent nanostructures for use in light-emitting diodes (LEDs). The solid-state assemblies made of complexes of the copper–iodine cluster with phosphor–organic compounds as ligands are easily prepared, ...