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Hydroxide-bridged dicopper complexes: Influence of secondary coordination sphere on structure and catecholase activity

Amide-based ligands (H2L1-6) appended with assorted functional groups have been used for the synthesis of diopper(II) complexes 1-6 having Cu-μ(OH)-Cu core. Crystal structures of 1-6 display that while every Cu(II) ion is ligated within the N3 pincer cavity of a potentially multidentate ligand; two Cu(II) ce

Authors:   Rajeev Gupta; Deepak Bansal
Journal:   Dalton Transactions
DOI:   10.1039/C6DT04858G
Facts, background information, dossiers
  • functional groups
  • crystal structures
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