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Regioselective SN2 reactions for rapid syntheses of azido-inositols by one-pot sequence-specific nucleophilyses

Triflates of myo-inositol undergo facile solvolysis in DMSO and DMF giving SN2 products substituted with O-nucleophiles; DMF showed slower kinetics. Axial O-triflate undergoes faster substitution than equatorial O-triflate. By exploiting this difference in kinetics, solvent-tuning and by sequence-controlled

Authors:   Kana M Sureshan; Arthi Ravi; Syed Zahid Hassan; Ajithkumar N Vanikrishna
Journal:   Chemical Communication
DOI:   10.1039/C7CC01219E
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