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Crystallisation temperature control of stoichiometry and selectivity in host–guest compounds

The host H, 9,9′-(ethyne-1,2-diyl)bis(fluoren-9-ol), has been employed to study its selectivity towards the close boiling alcohol pair, 2-propanol and tertiary butanol. H is selective for tertiary butanol at low temperatures, but includes both guests without discrimination at high temperatures. Concomitantly

Authors:   Nicole M. Sykes; Hong Su; Edwin Weber; Susan A. Bourne; Luigi R. Nassimbeni
Journal:   CrystEngComm
Volume:   19
edition:   39
Pages:   5892
DOI:   10.1039/C7CE01414G
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