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Synthesis and magneto-structural studies on a new family of carbonato bridged 3d–4f complexes featuring a [CoII3LnIII3(CO3)] (Ln = La, Gd, Tb, Dy and Ho) core: slow magnetic relaxation displayed by the cobalt(II)–dysprosium(III) analogue

A new family of [3 + 3] hexanuclear 3d–4f complexes [(μ3-CO3){CoIILnIIIL(μ3-OH)(OH2)}3]-(ClO4)·mC2H5OH·nH2O (1–5) [Ln = La (1), Gd (2), Tb (3), Dy (4), and Ho (5)] have been prepared in moderate to high yields (62–78%) following a self-assembly reaction between the ligand 6,6′,6′′-(nitrilotris(methylene))tri

Authors:   Mithun Chandra Majee; Sk Md Towsif Abtab; Dhrubajyoti Mondal; Manoranjan Maity; Marek Weselski; Maciej Witwicki; Alina Bieńko; Michał Antkowiak; Grzegorz Kamieniarz; Muktimoy Chaudhury
Journal:   Dalton Transactions
Volume:   47
edition:   10
Pages:   3425
DOI:   10.1039/C7DT04389A
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