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Synthesis of cationic molybdenum-cobalt heterometallic clusters protected against hydrolysis by macrocyclic triazacyclononane complexes

Four kinds of cobalt-polyoxomolybdenum clusters were synthesized by a combination of polyoxomolybdates and a Co-tacn (tacn = 1,4,7-triazacyclononane) complex. The heterometallic polynuclear clusters were obtained by the reaction of Na2MoO4 and [Co(tacn)(H2O)3](CF3SO3)3∙H2O in aqueous solution. The peripheral

Authors:   Sugiarto .; Tomoko Tagami; Keisuke Kawamoto; Yoshihito Hayashi
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01226A
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