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Atomic hydrogen interactions with gas-phase coronene cations: hydrogenation versus fragmentation

Sequential hydrogenation of polycyclic aromatic hydrocarbon (PAH) cations drives a gradual transition from a planar to a puckered geometry and from an aromatic to an aliphatic electronic structure. The resulting H-induced weakening of the molecular structure together with the exothermic nature of the consecutive H-

Authors:   Mathias Rapacioli; Stéphanie Cazaux; Nolan Foley; Aude Simon; Ronnie Hoekstra; Thomas Schlathölter
Journal:   Physical Chemistry Chemical Physics
DOI:   10.1039/C8CP03024C
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  • gas
  • cations
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