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Aus einfachen Grundchemikalien gelingt die Synthese von Na(OCP) ausgehend von NaPH2 (hergestellt aus Na, P und einer Protonenquelle) und CO (aus Kohle und Luft). Dieses Salz, das Phosphoranalogon zu Natriumcyanat, ist bemerkenswert stabil – anders als das hochgradig instabile HCP, das vor 50 Jahren entdeckt wurde.

Authors:   Puschmann, Florian Frank; Stein, Daniel; Heift, Dominikus; Hendriksen, Coenradus; Gal, Zoltan A.; Grützmacher, Hans‐Friedrich; Grützmacher, Hansjörg
Journal:   Angewandte Chemie
Volume:   123
Issue:   36
Year:   2011
Pages:   8570
DOI:   10.1002/ange.201102930
Publication date:   29-08-2011

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