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Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M12L24/M24L48 switchover.
<!--Unmatched element: w:blockFixed-->| Authors: | Bunzen, Jens; Iwasa, Junji; Bonakdarzadeh, Pia; Numata, Eri; Rissanen, Kari; Sato, Sota; Fujita, Makoto | |
| Journal: | Angewandte Chemie International Edition | |
| Year: | 2012 | |
| Pages: | n/a | |
| DOI: | 10.1002/anie.201108731 | |
| Publication date: | 10-02-2012 |
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