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Installing silicon is easy! A high‐yielding protocol for the palladium‐catalyzed silylation of terminal alkenes is reported. This method allows facile conversion of styrenes to E‐β‐silyl styrenes by using iodotrimethylsilane (TMSI) or chlorotrimethylsilane/lithium iodide (see scheme). Terminal allyl silanes with good E/Z ratios are also readily accessed from α‐olefins.
<!--Unmatched element: w:blockFixed-->| Authors: | McAtee, Jesse R.; Martin, Sara E. S.; Ahneman, Derek T.; Johnson, Keywan A.; Watson, Donald A. | |
| Journal: | Angewandte Chemie International Edition | |
| Volume: | 51 | |
| Issue: | 15 | |
| Year: | 2012 | |
| Pages: | 3663 | |
| DOI: | 10.1002/anie.201200060 | |
| Publication date: | 10-04-2012 |
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