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The behavior of halide salts at the vapor/water interface has been the focus of a tremendous amount of work in the past ten years. A molecular view of the interface has been introduced with the observation that large anions have some affinity for the interface, but a quantitative description of the driving forces that determine ion adsorption or repulsion at the interface is still missing. This review discusses recent developments that are based on classical and quantum-chemical molecular simulations as well as developments that are based on simple potential models.
| Authors: | Roland R. Netz; Dominik Horinek | |
| Journal: | Annual Review of Physical Chemistry | |
| Year: | 2012 | |
| DOI: | 10.1146/annurev-physchem-032511-143813 | |
| Publication date: | 04-04-2012 |
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