my.chemeurope.com
With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter.
Two 3D porous terbium(III) mucicate frameworks, {[Tb2(Mu2–)3(H2O)2]·4H2O}n (1) and {[Tb(Mu2–)(Ox2–)0.5(H2O)]·H2O}n (2), have been synthesized under hydrothermal conditions by changing the pH of the reaction medium. Isostructural europium(III) and seven mixed terbium(III)–europium(III) mucicates were synthesized by doping different percentages of EuIII under similar reaction conditions and unveiling different emission colors ranging from green to red under the same wavelength. Both dehydrated TbIII metal–organic frameworks exhibit selective H2O vapor sorption over other solvent molecules (MeOH, MeCN, and EtOH) of less polarity and bigger size and have been correlated to the highly hydrophilic pore surfaces decorated with −OH groups and O atoms from the carboxyl groups of mucicate.
| Authors: | Sudip Mohapatra; Sangita Adhikari; Hiranya Riju; Tapas Kumar Maji | |
| Journal: | Inorganic Chemistry | |
| Year: | 2012 | |
| DOI: | 10.1021/ic300237e | |
| Publication date: | 18-04-2012 |
Watchlist
This is where you can add this publication to your personal favourites.
Additional Information
The two enantiomers of 2-(2-hydroxybiphenyl-4-yl)propanoic acid ((S)- and (R)-BPOH) have been selected as probes for human serum albumin (HSA). Photophysical characterization in the absence of protein led to emission maxima, singlet energies, quantum yields, and fluorescence lifetime values ... more
The photodissociation of H2O in its B band is a prototype for nonadiabatic reaction dynamics. In addition to dissociation via the adiabatic pathway to the OH(Ã2Σ+) + H fragments, it also produces the OH(X̃2Π) + H fragments through two nonadiabatic pathways: the B̃ → X̃ transition via two co ... more
Due to the widespread occurrence in the environment and potential risk toward organisms of fluoroquinolones (FQs), it is of importance to develop high efficient methods for assessing their occurrence and environmental risk. A monoclonal antibody (Mab) with broad cross-reactivity to FQs was ... more
Rohm and Haas Powder Coatings is delighted to announce that its Reading, Pennsylvania, facility is the first site in the world to receive the RCMS® Site Certification awarded by the American Chemical Council (ACC). When Raj Gupta, Chairman and CEO of Rohm and Haas Company, became Chairman ... more
Über CHEMIE.DE
CHEMIE.DE Information Service GmbH runs specialist scientific internet portals. The secret to our success? We are familiar with what we publish.
Advertising at CHEMIE.DE
Our advertising formats support you in getting your message across to a clearly defined target audience.
© 1997-2013 CHEMIE.DE Information Service GmbH, All rights reserved
Netmeeting
