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Simon Grabowsky, Jens Beckmann, Peter Luger

Geometry, electron density, and electron localizability properties are used to clarify the nature of unusual hydrogen bonding to the siloxane linkage in a computational study. It is described how the basicity of the siloxane linkage can be significantly increased through variation of the Si–O–Si bond angle and how this is reflected in corresponding indicators of hydrogen bonding.


Authors:   Simon Grabowsky, Jens Beckmann, Peter Luger,
Journal:   Australian Journal of Chemistry
Year:   2012
DOI:   10.1071/CH11468
Publication date:   27-04-2012

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