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Two steps can be better than one: An efficient synthesis of enantioenriched N‐allylindoles by a one‐pot Ir‐catalyzed asymmetric allylic alkylation/oxidation reaction of indolines has been realized. The current method features high regioselectivity and enantioselectivity together with a broad range of indoles with varying electronic properties. The utility of this method was demonstrated by the synthesis of dihydropyrrolo[1,2‐a]indole derivatives.
<!--Unmatched element: w:blockFixed-->| Authors: | Liu, Wen‐Bo; Zhang, Xiao; Dai, Li‐Xin; You, Shu‐Li | |
| Journal: | Angewandte Chemie International Edition | |
| Volume: | 51 | |
| Issue: | 21 | |
| Year: | 2012 | |
| Pages: | 5183 | |
| DOI: | 10.1002/anie.201200649 | |
| Publication date: | 21-05-2012 |
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