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ChemInform Abstract: Preparation of (Z)‐1‐Fluoro‐1‐alkenyl Carboxylates, Carbonates and Carbamates Through Chromium Mediated Transformation of Dibromofluoromethylcarbinyl Esters and the Reactivity as Double Acyl Group Donors.

Abstract

Cr(II)/Mn‐mediated transformation of dibromofluoromethylcarbinyl esters (I) and (III) into fluoroalkenyl esters (II) and (IV) proceeds stereoselectively via [2,3]‐sigmatropic rearrangement of the ester group under mild conditions.

Authors:   Saito, Akio; Tojo, Manabu; Yanai, Hikaru; Wada, Fukiko; Nakagawa, Muga; Okada, Midori; Sato, Azusa; Okatani, Rieko; Taguchi, Takeo
Journal:   ChemInform
Volume:   43
Issue:   23
Year:   2012
Pages:   no
DOI:   10.1002/chin.201223073
Publication date:   05-06-2012

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