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Abstract
Novel blend‐based gel polymer electrolyte (GPE) films of thermoplastic polyurethane (TPU) and poly(vinylidene fluoride) (PVdF) (denoted as TPU/PVdF) have been prepared by electrospinning. The electrospun thermoplastic polyurethane‐co‐poly (vinylidene fluoride) membranes were activated with a 1M solution of LiClO4 in EC/PC and showed a high ionic conductivity about 1.6 mS cm−1 at room temperature. The electrochemical stability is at 5.0 V versus Li+/Li, making them suitable for practical applications in lithium cells. Cycling tests of Li/GPE/LiFePO4 cells showed the suitability of the electrospun membranes made of TPU/PVdF (80/20, w/w) for applications in lithium rechargeable batteries. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
<!--Unmatched element: w:blockFixed-->| Authors: | Wu, Na; Jing, Bo; Cao, Qi; Wang, Xianyou; Kuang, Hao; Wang, Qiang | |
| Journal: | Journal of Applied Polymer Science | |
| Volume: | 125 | |
| Issue: | 4 | |
| Year: | 2012 | |
| Pages: | 2556 | |
| DOI: | 10.1002/app.36523 | |
| Publication date: | 15-08-2012 |
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