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Ligand Geometry Directs OO Bond‐Formation Pathway in Ruthenium‐Based Water Oxidation Catalyst

Nimm zwei: Ein zweikerniger Ru‐OH2‐Komplex (siehe Bild: O rot, N hellblau, Ru rosa) katalysiert die Oxidation von Wasser. Strukturanalysen sowie kinetische Studien und Reaktivitätstests belegen, dass die entscheidende O‐O‐Bindungsbildung über einen bimolekularen I2M‐Mechanismus erfolgt. Dieser bimolekulare Prozess wurde erstmals mit 18O‐Markierungsexperimenten verfolgt.

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Authors:   Maji, Somnath; Vigara, Laura; Cottone, Francesca; Bozoglian, Fernando; Benet‐Buchholz, Jordi; Llobet, Antoni
Journal:   Angewandte Chemie
Year:   2012
Pages:   n/a
DOI:   10.1002/ange.201201356
Publication date:   30-04-2012

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