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The bisfacial cobalt(II) complex [(HC(3-Phpz)2(5-Phpz))2Co][BF4]2 (1) was prepared by reaction of the tris(pyrazolyl)methane HC(3-Phpz)3 with Co(BF4)2·6H2O. A remarkable ligand rearrangement reaction occurs resulting in incorporation of the new ligand HC(3-Phpz)2(5-Phpz). Complex 1 was characterised by X-ray crystallography, mass spectrometry, IR spectroscopy and elemental analysis. DFT studies on both ligands as well as on complex 1 complement the experimental investigation.
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The bisfacial cobalt(II) complex [(HC(3-Phpz)2(5-Phpz))2Co][BF4]2 was prepared by reaction of the tris(pyrazolyl)methane HC(3-Phpz)3 with Co(BF4)2·6H2O. A remarkable ligand rearrangement reaction occurs resulting in incorporation of the new ligand HC(3-Phpz)2(5-Phpz).
| Authors: | A. Hoffmann, U. Flörke, S. Herres-Pawlis | |
| Journal: | Inorganic Chemistry Communications | |
| Year: | 2012 | |
| DOI: | 10.1016/j.inoche.2012.05.049 | |
| Publication date: | 02-07-2012 |
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