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A new method has been developed to introduce fluoride in the structure of as-made germanium-containing zeolites prepared under pure alkaline media. Incorporation of fluoride species occurs without modification of the framework composition (Si/Ge ratio) and of the crystallinity, as evidenced by X-ray diffraction and electron microscopy. After incorporation, 19F solid-state NMR has been used to probe the location and distribution of Ge atoms in the framework. In the case of ITQ-13 and ITQ-17, which can be prepared from both hydroxide and fluoride routes, incorporated F anions are located in the same structural units as those occupied when zeolites are prepared in the presence of fluoride. In the case of ITQ-22 and ITQ-24, fluoride goes mainly in D4R units, which appear to be in the most energetically favorable positions for these zeolites. All experiments clearly show that zeolites prepared in the absence of fluoride in the synthesis medium are enriched in germanium, compared to the same materials obtained ...
| Authors: | Xiaolong Liu; Ugo Ravon; Françoise Bosselet; Gérard Bergeret; Alain Tuel | |
| Journal: | Chemistry of Materials | |
| Year: | 2012 | |
| DOI: | 10.1021/cm301511y | |
| Publication date: | 20-07-2012 |
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