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Fluor macht’s möglich: Eine kationische Fluor‐Gold‐Spezies, die durch Fluorierung eines niedervalenten Goldkomplexes hergestellt wurde, vermittelt die „funktionalisierende Hydratation”︁ von Alkinen. Eine Dreifachbindung wird hierbei genutzt, um in einem Eintopfprozess unter milden Bedingungen eine Carbonylgruppe und zwei neue Bindungen am α‐Kohlenstoffatom einzuführen (siehe Schema).

Authors:   Wang, Weibo; Jasinski, Jacek; Hammond, Gerald B.; Xu, Bo
Journal:   Angewandte Chemie
Volume:   122
Issue:   40
Year:   2010
Pages:   7405
DOI:   10.1002/ange.201003593
Publication date:   24-09-2010

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