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Size Effect Suppresses Brittle Failure in Hollow Cu60Zr40 Metallic Glass Nanolattices Deformed at Cryogenic Temperatures

17-Aug-2015 | Seok-Woo Lee; Mehdi Jafary-Zadeh; David Z. Chen; Yong-Wei Zhang; Julia R. Greer, Nano Letters, 2015

Nano Letters DOI: 10.1021/acs.nanolett.5b01034

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Synthesis and Antiproliferative Properties of a New Ceramide Analog of Varacin

09-Aug-2015 | Author(s): Adaickapillai Mahendran, Ashwini A. Ghogare, Robert Bittman, Gilbert Arthur, Alexander Greer, Chemistry and Physics of Lipids, 2015

Greer A benzopentasulfane was synthesized in 8 steps with a ceramide attached through an amide bond to the 7-position of the heterocycle structure. The anticancer activity of this synthetic ceramide...

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Pervaporation of organic compounds from aqueous mixtures using polydimethylsiloxane‐containing block copolymer membranes

07-Aug-2015 | Douglas R. Greer, A. Evren Ozcam, Nitash P. Balsara, AIChE Journal, 2015

Pervaporation of aqueous mixtures of ethanol, acetone, butanol, isobutanol, and furfural through polystyrene‐b‐polydimethylsiloxane‐b‐polystyrene (SDS) triblock copolymer membranes is reported. These mixtures are important for biofuel production from lignocellulosic feedstocks. Feedstock ...

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Fragile‐to‐Strong Crossover in Supercooled Liquid Ag‐In‐Sb‐Te Studied by Ultrafast Calorimetry

02-Jul-2015 | Jiri Orava, Daniel W. Hewak, A. Lindsay Greer, Advanced Functional Materials, 2015

Phase‐change random‐access memory relies on the reversible crystalline‐glassy phase change in chalcogenide thin films. In this application, the speed of crystallization is critical for device performance: there is a need to combine ultrafast crystallization for switching at high temperature with ...

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Mechanism of Photochemical O-Atom Exchange in Nitrosamines with Molecular Oxygen

05-Jun-2015 | Marilene Silva Oliveira; Ashwini A. Ghogare; Inna Abramova; Edyta M. Greer; Fernanda Manso Prado; Paolo Di Mascio; A ..., The Journal of Organic Chemistry, 2015

The detection of an oxygen-atom photoexchange process of N-nitrosamines is reported. The photolysis of four nitrosamines (N-nitrosodiphenylamine 1, N-nitroso-N-methylaniline 2, N-butyl-N-(4-hydroxybutyl)nitrosamine 3, and N-nitrosodiethylamine 4) with ultraviolet light was examined in an ...

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New horizons for glass formation and stability

01-Jun-2015 | A. Lindsay Greer, Nature Materials, 2015

Nature Materials 14, 542 (2015). doi:10.1038/nmat4292 Author: A. Lindsay Greer It has long been thought impossible for pure metals to form stable glasses. Recent work supports...

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ChemInform Abstract: Aromaticity and Conjugation in 1,2‐Benzoquinone Valence Isomers and Congeners

27-May-2015 | Alexandru T. Balaban, Alexander Greer, Joel F. Liebman, ChemInform, 2015

Abstract Review: 225 refs.

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Development and characterization of novel 8‐plex DiLeu isobaric labels for quantitative proteomics and peptidomics

12-May-2015 | Dustin C. Frost, Tyler Greer, Feng Xiang, Zhidan Liang, Lingjun Li, Rapid Communications in Mass Spectrometry, 2015

Rationale Relative quantification of proteins via their enzymatically digested peptide products determines disease biomarker candidate lists in discovery studies. Isobaric label‐based strategies using TMT and iTRAQ allow for up to 10 samples to be multiplexed in one experiment, but their ...

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Three-Dimensional Au Microlattices as Positive Electrodes for Li–O2 Batteries

12-May-2015 | Chen Xu; Betar M. Gallant; Phillip U. Wunderlich; Timm Lohmann; Julia R. Greer, ACS Nano, 2015

We demonstrate the feasibility of using a 3-dimensional gold microlattice with a periodic porous structure and independently tunable surface composition as a Li–O2 battery cathode. The structure provides a platform for studying electrochemical reactions in architected Li–O2 electrodes with large ...

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Odorant receptors regulate the final glomerular coalescence of olfactory sensory neuron axons [Neuroscience]

05-May-2015 | Diego J. Rodriguez-Gil; Dianna L. Bartel; Austin W. Jaspers; Arie S. Mobley; Fumiaki Imamura; Charles A. Greer, Proceedings of the National Academy of Sciences current issue, 2015

Odorant receptors (OR) are strongly implicated in coalescence of olfactory sensory neuron (OSN) axons and the formation of olfactory bulb (OB) glomeruli. However, when ORs are first expressed relative to basal cell division and OSN axon extension is unknown. We developed an in vivo fate-mapping ...

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