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The British route to innovation

01-Sep-2015 | Nature Materials, 2015

Nature Materials 14, 851 (2015). doi:10.1038/nmat4404 Richard Murray of Innovate UK explains to Nature Materials how innovation derived from research findings can boost...

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Thermochemical Characterization of Bio- and Petro-diesel Fuels Using a Novel Laser-Heating Technique

17-Aug-2015 | Cary Presser; Ashot Nazarian; Thomas J. Bruno; Jacolin A. Murray; John L. Molloy, Energy & Fuels, 2015

A state-of-the-art, rapid laser-heating technique, referred to as the laser-driven thermal reactor, was used to characterize National Institute of Standards and Technology Standard Reference Material (SRM) diesel and biodiesel fuels, as well as a prototype biodiesel fuel. Also described are the ...

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Dendron-Mediated Engineering of Interparticle Separation and Self-Assembly in Dendronized Gold Nanoparticles Superlattices

17-Aug-2015 | Davit Jishkariani; Benjamin T. Diroll; Matteo Cargnello; Dahlia R. Klein; Lawrence A. Hough; Christopher B. Murray; ..., Journal of the American Chemical Society, 2015

Self-assembly of nanoparticles into designed structures with controlled interparticle separations is of crucial importance for the engineering of new materials with tunable functions and for the subsequent bottom-up fabrication of functional devices. In this study, a series of lipophilic, highly ...

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Reactivity of Hydride Bridges in High-Spin [3M–3(μ-H)] Clusters (M = FeII, CoII)

13-Aug-2015 | Yousoon Lee; Kevin J. Anderton; Forrest T. Sloane; David M. Ermert; Khalil A. Abboud; Ricardo García-Serres; Leslie ..., Journal of the American Chemical Society, 2015

The designed [3M–3(μ-H)] clusters (M = FeII, CoII) Fe3H3L (1-H) and Co3H3L (2-H) [where L3– is a tris(β-diketiminate) cyclophane] were synthesized by treating the corresponding M3Br3L complexes with KBEt3H. From single-crystal X-ray analysis, the hydride ligands are sterically protected by the ...

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Kinetics of IO Production in the CH2I + O2 Reaction Studied by Cavity Ring-Down Spectroscopy

12-Aug-2015 | Elizabeth S. Foreman; Craig Murray, Journal of Physical Chemistry A, 2015

Cavity ring-down spectroscopy was used to study the kinetics of formation of IO radicals in the reaction of CH2I + O2 in a flow cell at 52 ± 3 Torr total pressure of N2 diluent and a temperature of 295 K. CH2I was produced by photolysis of CH2I2 at 355 nm and IO probed on the A2Π3/2–X2Π3/2 (3,0) ...

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Uniform Bimetallic Nanocrystals by High-Temperature Seed-Mediated Colloidal Synthesis and Their Catalytic Properties for Semiconducting Nanowire Growth

10-Aug-2015 | Matteo Cargnello; Rahul Agarwal; Dahlia R. Klein; Benjamin T. Diroll; Ritesh Agarwal; Christopher B. Murray, Chemistry of Materials, 2015

A general procedure to prepare uniform gold-based bimetallic nanocrystals (NCs) is reported. The method relies on a seed-mediated approach in which deposition and in-situ alloying of a second metal (Ag, Pt, Hg, Sn, Cd) onto monodisperse Au seeds are performed at relatively high temperatures, ...

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The Effects of Inorganic Surface Treatments on Photogenerated Carrier Mobility and Lifetime in PbSe Quantum Dot Thin Films

09-Aug-2015 | Author(s): E.D. Goodwin, Daniel B. Straus, E. Ashley Gaulding, Christopher B. Murray, Cherie R. Kagan, Chemical Physics, 2015

Publication date: Available online 4 August 2015 Source:Chemical Physics Author(s): E.D. Goodwin, Daniel B. Straus, E. Ashley Gaulding, Christopher B. Murray, Cherie R. Kagan We used...

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An In Situ Study on the Effects of Extracts of Taraxacum Officinale, Paulliniia Pinnata and Thonningia Sanguinea on Mitochondrial Function

07-Aug-2015 | A. Ocloo, R. Appiah‐Opong, M.A. Chama, A.A. Appiah, A.J. Murray, Journal of Food Biochemistry, 2015

Abstract Taraxacum officinale leaves are popular among Ghanaians as vegetable and/or beverage while extracts of Taraxacum officinale, Paulliniia pinnata and Thonningia sanguinea are present in common herbal remedies widely available without prescription in Ghana. This study was therefore ...

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ChemInform Abstract: Marine Natural Products

06-Aug-2015 | John W. Blunt, Brent R. Copp, Robert A. Keyzers, Murray H. G. Munro, Michele R. Prinsep, ChemInform, 2015

Abstract Review: literature published in 2013; 982 refs.

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Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

29-Jul-2015 | Chris Samuel Hawes; Nicholas F Chilton; Boujemaa Moubaraki; Gregory P Knowles; Alan L Chaffee; Keith S. Murray; Stua ..., Dalton Transactions, 2015

The synthesis and structural, magnetic and gas adsorption properties of a series of coordination polymer materials prepared from a new, highly flexible and internally functional tetrakis-carboxybenzyl ligand H4L derived from 1,2-diaminoethane have been examined. The complex ...

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