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Binary and Ternary Superlattices Self-Assembled from Colloidal Nanodisks and Nanorods

15-May-2015 | Taejong Paik; Benjamin T. Diroll; Cherie R. Kagan; Christopher B. Murray, Journal of the American Chemical Society, 2015

Self-assembly of multicomponent anisotropic nanocrystals with controlled orientation and spatial distribution allows the design of novel metamaterials with unique shape- and orientation-dependent collective properties. Although many phases of binary structures are theoretically proposed, the ...

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Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures

01-May-2015 | Merete Bilde; Kelley Barsanti; Murray Booth; Christopher D. Cappa; Neil M. Donahue; Eva U. Emanuelsson; Gordon McFig ..., Chemical Reviews, 2015

Chemical Reviews DOI: 10.1021/cr5005502

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Modular design of SPIRO-OMeTAD analogues as hole transport materials in solar cells

30-Apr-2015 | Alexander Murray; Jarvist Moore Frost; Christopher Hendon; Chris D Molloy; D Carbery; Aron Walsh, Chemical Communication, 2015

We predict the ionisation potentials of the hole-conducting material SPIRO-OMeTAD and twelve methoxy isomers and polymethoxy derivatives. Based on electronic and economic factors, we identify the optimal compounds for application as p-type hole-selective contacts in hybrid halide perovskite solar ...

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Correction for Paytan et al., Methane transport from the active layer to lakes in the Arctic using Toolik Lake, Alaska, as a case study [Correction]

28-Apr-2015 | Proceedings of the National Academy of Sciences current issue, 2015

. Lecher, Natasha Dimova, Katy J. Sparrow, Fenix Garcia-Tigreros Kodovska, Joseph Murray, Slawomir Tulaczyk, and John D. Kessler, which appeared......

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Spin Crossover in cis Manganese(III) Quinolylsalicylaldiminates

27-Apr-2015 | Jitnapa Sirirak, David J. Harding, Phimphaka Harding, Keith S. Murray, Boujemaa Moubaraki, Lujia Liu, Shane G. Telfer, European Journal of Inorganic Chemistry, 2015

Abstract Two new MnII/III redox pairs, [Mn(qsal‐Cl)2]0/+ 10/+ and [Mn(qsal‐Br)2]0/+ 20/+ have been synthesized employing the tridentate Schiff base ligands, 5‐X–N‐(8‐quinolyl)salicylaldimine (Hqsal‐X, X = Cl and Br). The neutral MnII complexes 1 and 2 were prepared from MnCl2 and Hqsal‐Cl and ...

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An Air‐ and Water‐Tolerant Zinc Hydride Cluster That Reacts Selectively With CO2

27-Apr-2015 | David M. Ermert, Ion Ghiviriga, Vincent J. Catalano, Jason Shearer, Leslie J. Murray, Angewandte Chemie International Edition, 2015

Abstract The reaction of [Zn3Cl3L], in which L3− is a tris(β‐diketiminate) cyclophane, with K(sBu)3BH afforded [Zn3(μ‐H)3L] (2), as confirmed by NMR spectroscopy, NOESY, and X‐ray crystallography. The complex 2 was air‐stable and unreactive towards water, methanol, and other substrates (e.g., ...

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Graphite Oxide to Graphene. Biomaterials to Bionics

27-Apr-2015 | Brianna C. Thompson, Eoin Murray, Gordon G. Wallace, Advanced Materials, 2015

The advent of implantable biomaterials has revolutionized medical treatment, allowing the development of the fields of tissue engineering and medical bionic devices (e.g., cochlea implants to restore hearing, vagus nerve stimulators to control Parkinson's disease, and cardiac pace makers). ...

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Fibroblastic Synoviocytes Secrete Plasma Proteins via α2‐Macroglobulins Serving as Intracellular and Extracellular Chaperones

21-Apr-2015 | Ke‐Wei Zhao, Elsa J. Brochmann Murray, Samuel S. Murray, Journal of Cellular Biochemistry, 2015

ABSTRACT Changes in plasma protein levels in synovial fluid (SF) have been implicated in osteoarthritis and rheumatoid arthritis. It was previously thought that the presence of plasma proteins in SF reflected ultrafiltration or extravasation from the vasculature, possibly due to retraction of ...

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Selective Targeting of the TPX2 Site of Importin‐α Using Fragment‐Based Ligand Design

21-Apr-2015 | Rhian S. Holvey, Eugene Valkov, David Neal, Murray Stewart, Chris Abell, ChemMedChem, 2015

Abstract Protein–protein interactions are difficult therapeutic targets, and inhibiting pathologically relevant interactions without disrupting other essential ones presents an additional challenge. Herein we report how this might be achieved for the potential anticancer target, the ...

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Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework

15-Apr-2015 | Matthew J. Cliffe; Joshua A. Hill; Claire A. Murray; François-Xavier Coudert; Andrew L. Goodwin, Physical Chemistry Chemical Physics, 2015

Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal–organic framework (MOF). Incorporation of correlated vacancy defects within the framework affects both the extent of thermal ...

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