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The British route to innovation

01-Sep-2015 | Nature Materials, 2015

Nature Materials 14, 851 (2015). doi:10.1038/nmat4404 Richard Murray of Innovate UK explains to Nature Materials how innovation derived from research findings can boost...


Thermochemical Characterization of Bio- and Petro-diesel Fuels Using a Novel Laser-Heating Technique

17-Aug-2015 | Cary Presser; Ashot Nazarian; Thomas J. Bruno; Jacolin A. Murray; John L. Molloy, Energy & Fuels, 2015

A state-of-the-art, rapid laser-heating technique, referred to as the laser-driven thermal reactor, was used to characterize National Institute of Standards and Technology Standard Reference Material (SRM) diesel and biodiesel fuels, as well as a prototype biodiesel fuel. Also described are the ...


Dendron-Mediated Engineering of Interparticle Separation and Self-Assembly in Dendronized Gold Nanoparticles Superlattices

17-Aug-2015 | Davit Jishkariani; Benjamin T. Diroll; Matteo Cargnello; Dahlia R. Klein; Lawrence A. Hough; Christopher B. Murray; ..., Journal of the American Chemical Society, 2015

Self-assembly of nanoparticles into designed structures with controlled interparticle separations is of crucial importance for the engineering of new materials with tunable functions and for the subsequent bottom-up fabrication of functional devices. In this study, a series of lipophilic, highly ...


Reactivity of Hydride Bridges in High-Spin [3M–3(μ-H)] Clusters (M = FeII, CoII)

13-Aug-2015 | Yousoon Lee; Kevin J. Anderton; Forrest T. Sloane; David M. Ermert; Khalil A. Abboud; Ricardo García-Serres; Leslie ..., Journal of the American Chemical Society, 2015

The designed [3M–3(μ-H)] clusters (M = FeII, CoII) Fe3H3L (1-H) and Co3H3L (2-H) [where L3– is a tris(β-diketiminate) cyclophane] were synthesized by treating the corresponding M3Br3L complexes with KBEt3H. From single-crystal X-ray analysis, the hydride ligands are sterically protected by the ...


Kinetics of IO Production in the CH2I + O2 Reaction Studied by Cavity Ring-Down Spectroscopy

12-Aug-2015 | Elizabeth S. Foreman; Craig Murray, Journal of Physical Chemistry A, 2015

Cavity ring-down spectroscopy was used to study the kinetics of formation of IO radicals in the reaction of CH2I + O2 in a flow cell at 52 ± 3 Torr total pressure of N2 diluent and a temperature of 295 K. CH2I was produced by photolysis of CH2I2 at 355 nm and IO probed on the A2Π3/2–X2Π3/2 (3,0) ...


Uniform Bimetallic Nanocrystals by High-Temperature Seed-Mediated Colloidal Synthesis and Their Catalytic Properties for Semiconducting Nanowire Growth

10-Aug-2015 | Matteo Cargnello; Rahul Agarwal; Dahlia R. Klein; Benjamin T. Diroll; Ritesh Agarwal; Christopher B. Murray, Chemistry of Materials, 2015

A general procedure to prepare uniform gold-based bimetallic nanocrystals (NCs) is reported. The method relies on a seed-mediated approach in which deposition and in-situ alloying of a second metal (Ag, Pt, Hg, Sn, Cd) onto monodisperse Au seeds are performed at relatively high temperatures, ...


The Effects of Inorganic Surface Treatments on Photogenerated Carrier Mobility and Lifetime in PbSe Quantum Dot Thin Films

09-Aug-2015 | Author(s): E.D. Goodwin, Daniel B. Straus, E. Ashley Gaulding, Christopher B. Murray, Cherie R. Kagan, Chemical Physics, 2015

Publication date: Available online 4 August 2015 Source:Chemical Physics Author(s): E.D. Goodwin, Daniel B. Straus, E. Ashley Gaulding, Christopher B. Murray, Cherie R. Kagan We used...


An In Situ Study on the Effects of Extracts of Taraxacum Officinale, Paulliniia Pinnata and Thonningia Sanguinea on Mitochondrial Function

07-Aug-2015 | A. Ocloo, R. Appiah‐Opong, M.A. Chama, A.A. Appiah, A.J. Murray, Journal of Food Biochemistry, 2015

Abstract Taraxacum officinale leaves are popular among Ghanaians as vegetable and/or beverage while extracts of Taraxacum officinale, Paulliniia pinnata and Thonningia sanguinea are present in common herbal remedies widely available without prescription in Ghana. This study was therefore ...


ChemInform Abstract: Marine Natural Products

06-Aug-2015 | John W. Blunt, Brent R. Copp, Robert A. Keyzers, Murray H. G. Munro, Michele R. Prinsep, ChemInform, 2015

Abstract Review: literature published in 2013; 982 refs.


Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

29-Jul-2015 | Chris Samuel Hawes; Nicholas F Chilton; Boujemaa Moubaraki; Gregory P Knowles; Alan L Chaffee; Keith S. Murray; Stua ..., Dalton Transactions, 2015

The synthesis and structural, magnetic and gas adsorption properties of a series of coordination polymer materials prepared from a new, highly flexible and internally functional tetrakis-carboxybenzyl ligand H4L derived from 1,2-diaminoethane have been examined. The complex ...


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