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18,447 Newest Publications in angewandte chemie international edition

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Ion Specificity on Electric Energy Generated by Flowing Water Droplets

18-Jan-2018 | Junwoo Park, Suhwan Song, ChaeHo Shin, YoungJun Yang, Stefan A. L. Weber, Eunji Sim, Youn Sang Kim, Angewandte Chemie International Edition, 2018

Abstract The development of energy‐conversion devices using water movement has actively progressed. Ionovoltaic devices, which are driven by ion dynamics, show ion specificity by which different ions with identical charges show different output performance. However, the ion specificity remains ...

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Tandem Molecular Self‐Assembly in Liver Cancer Cells

18-Jan-2018 | Jie Zhan, Yanbin Cai, Shuangshuang He, Ling Wang, Zhimou Yang, Angewandte Chemie International Edition, 2018

Abstract We herein describe the tandem molecular self‐assembly of a peptide derivative (1) that is controlled by a combination of enzymatic and chemical reactions. In phosphate‐buffered saline (PBS), compound 1 self‐assembles first into nanoparticles by phosphatase and then into nanofibers by ...

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Norbert W. Mitzel

18-Jan-2018 | Angewandte Chemie International Edition, 2018

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Norbert W. Mitzel

18-Jan-2018 | Angewandte Chemie International Edition, 2018

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Total Synthesis and Conformational Study of The Anti‐tubercular Cyclic Peptide Callyaerin A Bearing a Rare Rigidifying (Z)‐2,3‐ Diaminoacrylamide Moiety

18-Jan-2018 | Margaret Anne Brimble, Shengping Zhang, Luis De Leon Rodriguez, Ivanhoe Leung, Greg Cook, Paul Harris, Angewandte Chemie International Edition, 2018

The first synthesis of the anti‐TB cyclic peptide callyaerin A containing a rare (Z)‐2,3‐diaminoacrylamide bridging motif is reported. Fmoc‐formylglycine‐diethylacetal was used as a masked equivalent of formylglycine in the synthesis of the linear precursor of callyaerin A. Intramolecular ...

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Electrocatalytic Activity of 2D Phosphorene Based Heteroelectrocatalyst for Photoelectrochemical Cells

18-Jan-2018 | Munkhbayar Batmunkh, Aabhash Shrestha, Munkhjargal Bat-Erdene, Md. Julker Nine, Cameron James Shearer, Christopher ..., Angewandte Chemie International Edition, 2018

Research into efficient synthesis, fundamental properties and potential applications of phosphorene is currently the subject of intense investigation. Herein, solution processed phosphorene or few‐layer black phosphorus (FL‐BP) sheets are prepared using microwave‐exfoliation method and used in ...

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Optical structural analysis of individual α‐synuclein oligomers

17-Jan-2018 | Juan Alberto Varela, Margarida Rodrigues, Suman De, Patrick Flagmeier, Sonia Gandhi, Christopher M. Dobson, David ..., Angewandte Chemie International Edition, 2018

Small aggregates of misfolded proteins play a key role in neurodegenerative disorders. Such species are difficult to study due to the lack of methods capable of resolving these heterogeneous aggregates, which are smaller than the optical diffraction limit. We demonstrate here an all‐optical ...

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Solvent‐free enzyme activity: quick, high‐yielding mechano‐enzymatic hydrolysis of cellulose into glucose

17-Jan-2018 | Fabien Hammerer, Leigh Loots, Jean-Louis Do, J. P. Daniel Therien, Christopher W. Nickels, Tomislav Friscic, Karine ..., Angewandte Chemie International Edition, 2018

Mechanochemistry enables enzymatic cleavage of cellulose into glucose without bulk solvents, acids, other aggressive reagents or substrate pre‐treatment. This clean mechano‐enzymatic process is also directly applicable to biomass, avoids many limitations associated with the use of cellulases, ...

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Isotope substitution of promiscuous alcohol dehydrogenase reveals origin of substrate preference in transition state

17-Jan-2018 | Rudolf K Allemann, J Javier Ruiz-Pernia, Louis Luk, Inaki Tunon, Vicent Moliner, Enas Behiry, Angewandte Chemie International Edition, 2018

The origin of substrate preference in promiscuous enzymes was investigated by enzyme isotope labeling of the alcohol dehydrogenase from Geobacillus stearothermophilus (BsADH). At physiological temperature, protein dynamic coupling to the reaction coordinate was insignificant. However, the extent ...

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Isotope substitution of promiscuous alcohol dehydrogenase reveals origin of substrate preference in transition state

17-Jan-2018 | Rudolf K Allemann, J Javier Ruiz-Pernia, Louis Luk, Inaki Tunon, Vicent Moliner, Enas Behiry, Angewandte Chemie International Edition, 2018

The origin of substrate preference in promiscuous enzymes was investigated by enzyme isotope labeling of the alcohol dehydrogenase from Geobacillus stearothermophilus (BsADH). At physiological temperature, protein dynamic coupling to the reaction coordinate was insignificant. However, the extent ...

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