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20,911 Newest Publications in chemical communication

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Facile synthesis of -C[double bond, length as m-dash]N- linked covalent organic frameworks under ambient conditions

20-Jan-2018 | San-Yuan Ding; Xiao-Hui Cui; Jie Feng; Gongxuan Lu; Wei Wang, Chemical Communication, 2018

We reported herein a facile approach for the synthesis of –C [[double bond, length as m-dash]] N– linked covalent organic frameworks under ambient conditions. Three known (COF-42, COF-43, and COF-LZU1) and one new (Pr-COF-42) COF materials were successfully synthesized using this method. ...

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Facile synthesis of -C[double bond, length as m-dash]N- linked covalent organic frameworks under ambient conditions

20-Jan-2018 | San-Yuan Ding; Xiao-Hui Cui; Jie Feng; Gongxuan Lu; Wei Wang, Chemical Communication, 2018

We reported herein a facile approach for the synthesis of –C [[double bond, length as m-dash]] N– linked covalent organic frameworks under ambient conditions. Three known (COF-42, COF-43, and COF-LZU1) and one new (Pr-COF-42) COF materials were successfully synthesized using this method. ...

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Polymer-mediated metallophilic interactions for gram-scale production, high-yield ([similar]90%) synthesis of ultrathin bismuth nanowires

20-Jan-2018 | Tzu-Lun Kao; Hsing-Yu Tuan, Chemical Communication, 2018

High-yields (∼90%) of ultrathin (<4 nm) bismuth nanowires (Bi UNWs) were obtained by reducing the polymeric strands of oleylamine-bismuth 2-ethylhexanoate complexes formed via metallophilic interactions with the mediation of a copolymer (PVP–HDE).

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Polymer-mediated metallophilic interactions for gram-scale production, high-yield ([similar]90%) synthesis of ultrathin bismuth nanowires

20-Jan-2018 | Tzu-Lun Kao; Hsing-Yu Tuan, Chemical Communication, 2018

High-yields (∼90%) of ultrathin (<4 nm) bismuth nanowires (Bi UNWs) were obtained by reducing the polymeric strands of oleylamine-bismuth 2-ethylhexanoate complexes formed via metallophilic interactions with the mediation of a copolymer (PVP–HDE).

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Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

20-Jan-2018 | Varvara I. Nikolayenko; Leonard J. Barbour; Ana Arauzo; Javier Campo; Jeremy M. Rawson; Delia A. Haynes, Chemical Communication, 2018

Inclusion of the dithiadiazolyl radical PhCNSSN˙ into the dynamically porous metallocycle [Cu2(L1)2Cl4], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, ...

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Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

20-Jan-2018 | Varvara I. Nikolayenko; Leonard J. Barbour; Ana Arauzo; Javier Campo; Jeremy M. Rawson; Delia A. Haynes, Chemical Communication, 2018

Inclusion of the dithiadiazolyl radical PhCNSSN˙ into the dynamically porous metallocycle [Cu2(L1)2Cl4], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, ...

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Ligand-induced reactivity of [small beta]-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

20-Jan-2018 | Laia Davin; Ross McLellan; Alan R. Kennedy; Eva Hevia, Chemical Communication, 2018

Using β-diketiminate Mg(ii) complexes containing either alkyl, aryl or amide groups, the regioselective functionalization of a wide range of fluoroarenes is accomplished but in uniquely different ways. Overcoming common limitations of traditional s-block bases, kinetically activated ...

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Ligand-induced reactivity of [small beta]-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

20-Jan-2018 | Laia Davin; Ross McLellan; Alan R. Kennedy; Eva Hevia, Chemical Communication, 2018

Using β-diketiminate Mg(ii) complexes containing either alkyl, aryl or amide groups, the regioselective functionalization of a wide range of fluoroarenes is accomplished but in uniquely different ways. Overcoming common limitations of traditional s-block bases, kinetically activated ...

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Unprecedented magnetic behaviour in lanthanide-based ionic liquids

20-Jan-2018 | Todd C. Monson; Tyler E. Stevens; Jean L. Leger; Jamie L. Manson; Katherine S. Lovejoy; Aimee L. Newsham; Rico E. De ..., Chemical Communication, 2018

Ionic liquids containing lanthanide halide anions give the opportunity to investigate magnetic behaviour in non-ordered systems. Reported herein is the synthesis and characterization of ionic liquids containing a series of lanthanide halide anions, with the resulting materials displaying unusual ...

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Unprecedented magnetic behaviour in lanthanide-based ionic liquids

20-Jan-2018 | Todd C. Monson; Tyler E. Stevens; Jean L. Leger; Jamie L. Manson; Katherine S. Lovejoy; Aimee L. Newsham; Rico E. De ..., Chemical Communication, 2018

Ionic liquids containing lanthanide halide anions give the opportunity to investigate magnetic behaviour in non-ordered systems. Reported herein is the synthesis and characterization of ionic liquids containing a series of lanthanide halide anions, with the resulting materials displaying unusual ...

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