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1,167 Newest Publications in inorganic chemistry communications
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Adjustment of coordination environment of Ln3+ ions to modulate near-infrared luminescent properties of Ln3+ complexes
29-10-2010 | Yani, Hui , Weixu, Feng , Tao, Wei , Xingqiang, Lü , Jirong, Song , ..., Inorganic Chemistry Communications, 2010
With the Zn-Schiff-base [ZnL(Py)] from the pure Salen-type Schiff-base ligand H2L (H2L=N,N’-bis(salicylidene)ethylene-1,2-diamine) as the precursor, a series of hetero-trinuclear Zn2Ln complexes [Zn2Ln(L)2(NO3)2(SCN)(Py)2] (Ln=Nd, 1; Ln=Yb, 2; Ln=Er, 3 and Ln=Gd, 4) are obtained by the ...
A lvt-type framework material [Pb3Cl3(OH)(succinate)]n with helical sub-structures and incomplete cubane-like clusters
29-10-2010 | Haixia, Zhang , Yao, Kang , Yanxi, Tan , Fei, Wang, Inorganic Chemistry Communications, 2010
Presented here is the hydrothermal synthesis, single crystal XRD characterization and physical property of a polymeric lead(II) compound, [Pb3Cl3(OH)(succinate)]n (1). In the structure of 1, the succinate ligands bridge the trinuclear incomplete cubane-like Pb3O3Cl clusters to form a ...
Biradical Chelating Host 2,2’-bipyridine-6,6’-diyl Bis(tert-Butyl Nitroxide) showing tunable exchange magnetic coupling
29-10-2010 | Kazuya, Koide , Takayuki, Ishida, Inorganic Chemistry Communications, 2010
The title compound was proposed as a paramagnetic host, and its chelation ability was confirmed by inclusion of a size-matching lanthanum(III) ion. The anti configuration of the free ligand was changed to the syn configuration in the complex. The antiferromagnetic coupling was enhanced after ...
Synthesis, Characterization, and MMA Polymerization Activity of Tetrahedral Co (II) Complex Bearing N, N-bis(1-pyrazolyl)methyl Ligand Based on Aniline Moiety
29-10-2010 | Minkyu, Yang , Won Jin, Park , Keun Byoung, Yoon , Jong Hwa, Jeong , Hyosun, Lee, Inorganic Chemistry Communications, 2010
A new series of air-stable Co(II) complexes, [bpmaL1]CoCl2 (1a), [bpmaL2]CoCl2 (2a), [bpmaL3]CoCl2 (3a), and [bpmaL4]CoCl2 (4a), where, for example, [bpmaL1 = N,N-bis{(1-pyrazolyl)methyl}aniline], has been synthesized. X-ray crystallography of 2a indicated that it has a dipper-type structure ...
Ester Catalytic Hydrolysis by a tridentate N,N′,N″-Copper Bridged Cyclodextrin Dimer
29-10-2010 | Si-Ping, Tang , Sha, Chen , Guang-Fei, Wu , Huo-Yan, Chen , Zong-Wan, Mao , ..., Inorganic Chemistry Communications, 2010
A new pyridine bridged cyclodextrin dimer mono-copper complex (CuL) was synthesized and characterized. The hydrolysis of carboxylic acid esters, bis(4-nitrophenyl)carbonate (BNPC) and 4-nitrophenyl acetate (NA), and phosphate ester, a DNA model bis(4-nitrophenyl)phosphate (BNPP), promoted by ...
Novel Mononuclear Mixed Ligand Ce(III) Pivalate with Protonated Cationic Form of Monoethanolamine as Ancillary Ligand
29-10-2010 | Natalia P., Kuzmina , Irina A., Martynova , Dmitry M., Tsymbarenko , Konstantin A., Lyssenko, Inorganic Chemistry Communications, 2010
The mononuclear mixed ligand Ce(III) pivalate with protonated cationic form of monoethanolamine (MEA) as anciallary ligand is reported. Crystal structure consists of mononuclear complex anions [Ce(Piv)5(HOCH2CH2NH3)]- (HPiv – 2,2-dimethylpropionic (pivalic) acid) and cations [HOCH2CH2NH3]+ ...
Synthesis, crystal structures and magnetic properties of two three-dimensional heterotrimetallic compounds [Cu(en)2Li(H2O)][Fe(CN)6] and [Cu(en)2Li(H2O)][Co(CN)6] (en = ethylenediamine)
29-10-2010 | Wei-Wei, Sima , Wen, Zhang, Inorganic Chemistry Communications, 2010
Two heterotrimetallic compounds, [Cu(en)2Li(H2O)][Fe(CN)6] and [Cu(en)2Li(H2O)][Co(CN)6] (en = ethylenediamine), were synthesized and characterized. They are isostructural and crystallize in the orthorhombic space group Pbca at 293 K. The structures of the two compounds are composed of ...
Two Three-dimensional pillar-layer AgI-frameworks with helical arrays containing hexamine
29-10-2010 | Peng, Guo , Jing, Wang , Gang, Wang , Shen-jie, Li , Wen-zhi, Huang , ..., Inorganic Chemistry Communications, 2010
Two three-dimensional pillar-layer AgI-frameworks with helical arrays have been synthesized under room temperature. Compound I, {[Ag2 (H2O) (L2)2L1].H2O}n（L1=hexamethylenetetramine, H1L2=3-Pyridinesulfonic acid), is constructed from two-dimensional (6,3) layers which are braced by helical ...
Trimethylphosphite stabilized N-silver(I) succinimide complexes as CVD precursors
29-10-2010 | Xian, Tao , Yu-Long, Wang , Ke-Cheng, Shen , Ying-Zhong, Shen, Inorganic Chemistry Communications, 2010
The preparation of [(MeO)3Pn⋅AgNC4H4O2] (n = 1, 2a; n = 2, 2b) is described. The molecular structure of 2a was determined by using X-ray single crystal analysis. Complex 2b was tested as Metal Organic Chemical Vapor Deposition (MOCVD) precursor in the deposition of silver for the first time. ...
Syntheses, Crystal Structures, Magnetic Properties of Two Lanthanide-Nitronyl Nitroxide Complexes ( LnIII = GdIII, PrIII)
29-10-2010 | Chen-Xi, Zhang , Na-Na, Sun , Xiang-Yu, Zhao , Yu-Ying, Zhang , Yan-Ling, Guo, Inorganic Chemistry Communications, 2010
Two complexes based on rare-earth-radical of formula {Ln(hfac)3[NITPh(OCH3)3]2} (Ln= Gd (1), Pr(2)); hfac = hexafluoroacetylacetonate; NITPh(OCH3)3 = 2-(3′,4′,5′-trimethoxyphenyl)-4,4,5,5-tetramethylimidazoline -1-oxyl-3-oxide) have been synthesized and characterized by single-crystal X-ray ...
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