14-06-2013 | Karl J. Koebke; Daniel J. Pauly; Leonid Lerner; Xien Liu; A. Andrew Pacheco, Inorganic Chemistry, 2013

The reaction of nitric oxide with oxy-myoglobin (oxyMb) to form ferric myoglobin (metMb) and nitrate, and the metMb-catalyzed isomerization of peroxynitrite to nitrate, have long been assumed to proceed via the same iron-bound peroxynitrite intermediate (metMb(OONO)). More recent research ...

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14-06-2013 | Roger K. Mah; Melanie W. Lui; George K. H. Shimizu, Inorganic Chemistry, 2013

Metal organic frameworks (MOFs) are noted for crystallinity, stability, and porosity. For many industrial challenges though, beyond stability to pore activation, porous materials require high thermal and moisture stability. Here, we report a Sn(IV) triphosphonate framework, CALF-28, that is ...

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14-06-2013 | Antonio Zucca; Diletta Cordeschi; Luca Maidich; Maria Itria Pilo; Elisabetta Masolo; Sergio Stoccoro; Maria Agostina ..., Inorganic Chemistry, 2013

Rollover cyclometalation of 2-(2′-pyridyl)quinoline, L, allowed the synthesis of the family of complexes [Pt(L-H)(X)(L′)] and [Pt(L*)(X)(L′)][BF4] (X = Me, Cl; L′ = neutral ligand), the former being the first examples of Pt(II) rollover complexes derived from the ligand L. The ligand L* is a ...

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14-06-2013 | Rihong Cong; Tao Yang; Junliang Sun; Yingxia Wang; Jianhua Lin, Inorganic Chemistry, 2013

β-BiB3O6 was compressed in a diamond anvil cell at room temperature and studied using a combinstion of in situ high-pressure Raman scattering and angle-dispersive synchrotron X-ray diffraction. The results reveal that β-BiB3O6 retains its structure below 9.0 GPa and undergoes a structural ...

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13-06-2013 | Angel L. Serrano; Miguel A. Casado; José A. López; Cristina Tejel, Inorganic Chemistry, 2013

A straightforward synthesis of a new hybrid scorpionate ligand [(allyl)2B(CH2PPh2)(Pz)]− ([A2BPN]−) is reported. Coordination to rhodium resulted in square-planar complexes [Rh(κ2-A2BPN)(L)(L′)] [L = L′ = 1/2cod (1,5-cyclooctadiene), CNtBu, CO (6); L = CO, L′ = NH3, pyridine, PPh3, PMe3] for ...

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13-06-2013 | Alexandra V. Soldatova; Mohammed Ibrahim; Thomas G. Spiro, Inorganic Chemistry, 2013

The gaseous ligands, CO, NO, and O2 interact with the Fe ion in heme proteins largely via backbonding of Fe electrons to the π* orbitals of the XO (X = C, N, O) ligands. In these FeXO adducts, the Fe–X stretching frequency varies inversely with the X–O stretching frequency, since increased ...

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13-06-2013 | Pius O. Adelani; Michael Ozga; Christine M. Wallace; Jie Qiu; Jennifer E. S. Szymanowski; Ginger E. Sigmon; Peter C. ..., Inorganic Chemistry, 2013

Two new hybrid uranyl-carboxyphosphonate cage clusters built from uranyl peroxide units were crystallized from aqueous solution under ambient conditions in approximately two months. The clusters are built from uranyl hexagonal bipyramids and are connected by employing a secondary metal ...

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13-06-2013 | Yufeng Chen; Gensheng Yu; Fei Li; Michael Severance, Inorganic Chemistry, 2013

A new composite based on polymolybdate incorporated in layered magadiite has been synthesized via a exfoliation/self-assembly process. Various techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy coupled with energy-dispersive ...

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13-06-2013 | Monica Pica; Anna Donnadio; Elisabetta Troni; Donatella Capitani; Mario Casciola, Inorganic Chemistry, 2013

Gels of α-type zirconium(IV) phosphate alkylphosphonates, ZP(Cn)x, were prepared by reacting, at room temperature, propanol intercalated nanosized α-zirconium phosphate (α-ZrP) with propanol solutions of alkylphosphonic acids (H2Cn, n = number of carbon atoms in the alkyl chain = 4, 5, 6), ...

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13-06-2013 | Małgorzata Hołyńska; Nicolas Frank; Céline Pichon; Ie-Rang Jeon; Rodolphe Clérac; Stefanie Dehnen, Inorganic Chemistry, 2013

Inorganic Chemistry DOI: 10.1021/ic401018w

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