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10,093 Newest Publications in inorganic chemistry

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A Constrained Tetrapeptide as a Model of Cu(I) Binding Sites Involving Cu4S6 Clusters in Proteins

12-Jan-2018 | Edit Mesterházy; Colette Lebrun; Attila Jancsó; Pascale Delangle, Inorganic Chemistry, 2018

Peptide design is an efficient strategy to create relevant models of natural metal binding sites found in proteins. The two short tetrapeptides Ac-Cys-dPro-Pro-Cys-NH2 (CdPPC) and Ac-Cys-Pro-Gly-Cys-NH2 (CPGC) were synthesized and studied as mimics of Cu(I) binding sites involved in Cu ...

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A Constrained Tetrapeptide as a Model of Cu(I) Binding Sites Involving Cu4S6 Clusters in Proteins

12-Jan-2018 | Edit Mesterházy; Colette Lebrun; Attila Jancsó; Pascale Delangle, Inorganic Chemistry, 2018

Peptide design is an efficient strategy to create relevant models of natural metal binding sites found in proteins. The two short tetrapeptides Ac-Cys-dPro-Pro-Cys-NH2 (CdPPC) and Ac-Cys-Pro-Gly-Cys-NH2 (CPGC) were synthesized and studied as mimics of Cu(I) binding sites involved in Cu ...

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Self-Assembly of Pseudorotaxane Structures from a Dicopper(II) Molecular Cage and Dicarboxylate Axles

12-Jan-2018 | Valeria Amendola; Ana Miljkovic; Laura Legnani; Lucio Toma; Daniele Dondi; Simone Lazzaroni, Inorganic Chemistry, 2018

In this work, we employed for the first time a dinuclear bis[tris(2-aminoethyl)amine] cryptate to obtain the self-assembly of pseudorotaxane structures in an aqueous solution. The goal was achieved by exploiting the well-known affinity of the dicopper azacryptate with diphenyl spacers for the ...

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Modular [FeIII8MII6]n+ (MII = Pd, Co, Ni, Cu) Coordination Cages

11-Jan-2018 | Sergio Sanz; Helen M. O’Connor; Priyanka Comar; Amgalanbaatar Baldansuren; Mateusz B. Pitak; Simon J. Coles; Høgni W ..., Inorganic Chemistry, 2018

The reaction of the simple metalloligand [FeIIIL3] [HL = 1-(4-pyridyl)butane-1,3-dione] with a variety of different MII salts results in the formation of a family of heterometallic cages of formulae [FeIII8PdII6L24]Cl12 (1), [FeIII8CuII6L24(H2O)4Br4]Br8 (2), [FeIII8CuII6L24(H2O)10](NO3)12 (3), ...

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Modular [FeIII8MII6]n+ (MII = Pd, Co, Ni, Cu) Coordination Cages

11-Jan-2018 | Sergio Sanz; Helen M. O’Connor; Priyanka Comar; Amgalanbaatar Baldansuren; Mateusz B. Pitak; Simon J. Coles; Høgni W ..., Inorganic Chemistry, 2018

The reaction of the simple metalloligand [FeIIIL3] [HL = 1-(4-pyridyl)butane-1,3-dione] with a variety of different MII salts results in the formation of a family of heterometallic cages of formulae [FeIII8PdII6L24]Cl12 (1), [FeIII8CuII6L24(H2O)4Br4]Br8 (2), [FeIII8CuII6L24(H2O)10](NO3)12 (3), ...

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Drastic Redox Shift and Electronic Structural Changes of a Manganese(III)-Salen Oxidation Catalyst upon Reaction with Hydroxide and Cyanide Ion

11-Jan-2018 | Takuya Kurahashi, Inorganic Chemistry, 2018

Flexible redox properties of a metal complex are important for redox catalysis. The present study shows that the reaction of a manganese(III) salen complex, which is a well-known oxidation catalyst, with hydroxide ion gives a transient manganese(III) species with drastically lowered redox ...

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Drastic Redox Shift and Electronic Structural Changes of a Manganese(III)-Salen Oxidation Catalyst upon Reaction with Hydroxide and Cyanide Ion

11-Jan-2018 | Takuya Kurahashi, Inorganic Chemistry, 2018

Flexible redox properties of a metal complex are important for redox catalysis. The present study shows that the reaction of a manganese(III) salen complex, which is a well-known oxidation catalyst, with hydroxide ion gives a transient manganese(III) species with drastically lowered redox ...

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Spark Plasma Sintering (SPS)-Assisted Synthesis and Thermoelectric Characterization of Magnéli Phase V6O11

11-Jan-2018 | Markus Joos; Giacomo Cerretti; Igor Veremchuk; Patrick Hofmann; Hajo Frerichs; Dalaver H. Anjum; Tobias Reich; Ingo ..., Inorganic Chemistry, 2018

The Magnéli phase V6O11 was synthesized in gram amounts from a powder mixture of V6O11/V7O13 and vanadium metal, using the spark plasma sintering (SPS) technique. Its structure was determined with synchrotron X-ray powder diffraction data from a phase-pure sample synthesized by conventional ...

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Transmetalation for Flexible Pendant-Armed Schiff-Base Macrocyclic Complexes Influenced by Halide Effects

11-Jan-2018 | Fei-Fan Chang; Lei Zhang; Pei-Chen Zhao; Wei Huang, Inorganic Chemistry, 2018

Three 46-membered [2 + 2] pendant-armed Schiff-base macrocyclic dinuclear CdII and CuII complexes (2a, 2b, and 3b) and one 23-membered [1 + 1] CuII macrocycle 4a were prepared from the template-directed condensation reactions between 1,2-bis(2-aminoethoxy)-ethane and extended Cl-dialdehyde in the ...

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A Series of Weakley-type Polyoxomolybdates: Synthesis, Characterization, and Magnetic Properties by a Combined Experimental and Theoretical Approach

11-Jan-2018 | Shan She; Chen Gao; Kun Chen; Aruuhan Bayaguud; Yichao Huang; Bing-Wu Wang; Song Gao; Yongge Wei, Inorganic Chemistry, 2018

Using DCC as the dehydrating agent, a series of Weakley-type polyoxomolybdates [Bu4N]3{Ln[Mo5O13(OMe)4(NO)]2} (Ln = Tb, Dy, Ho, Er) were synthesized in a one-pot reaction and structurally characterized by elemental, IR, UV–vis analysis, PXRD, and single-crystal X-ray diffraction. Furthermore, the ...

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