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576 Newest Publications of CSIRO PUBLISHING
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Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2′-bim)3}0.5{P2W18O62}]·H2O
17-05-2013 | Yanglei Xu, Jiang Wu, Kai Yu, Zhanhua Su, Chunxiao Wang, Chunmei Wang, Baibin Zhou,, Australian Journal of Chemistry, 2013
Yanglei Xu, Jiang Wu, Kai Yu, Zhanhua Su, Chunxiao Wang, Chunmei Wang, Baibin Zhou As a new 3D unit, two transition-metal complex (TMC) cations [Cu2(2,2′-bim)3]0.52+ and [Cu8(pz)11]0.54+ are introduced to [P2W18O62]6–, leading to assembly of the first Wells-Dawson type framework linked by ...
Stable Molecular Complex of Squaric Acid with 2-(Quinuclidinium)propionate
17-05-2013 | Zofia Dega-Szafran, Andrzej Katrusiak, Miroslaw Szafran,, Australian Journal of Chemistry, 2013
Zofia Dega-Szafran, Andrzej Katrusiak, Miroslaw Szafran Squaric acid (H2SQ) forms a complex with 2-(quinuclidinium)propionate (QNPr). The molecules of H2SQ and zwitterions of QNPr are bridged by two strong non-equivalent O–H?O hydrogen bonds of 2.476(2) and 2.482(1)Å. The complex is ...
Novel Electric Responsive Columnar Liquid Crystals based on Perylene Tetra sec-alkyl Ester Derivatives
15-05-2013 | Lei Wang, Qing Cui, Xiao-Fang Chen, Yang Li, Zheng-Qiang Li, Dong Wang, Huai Yang,, Australian Journal of Chemistry, 2013
Lei Wang, Qing Cui, Xiao-Fang Chen, Yang Li, Zheng-Qiang Li, Dong Wang, Huai Yang A series of perylene tetra sec-alkyl ester compounds were newly synthesised and exhibited a columnar phase at room temperature. PS8 could perpendicularly orient to the applied electric field. Well organised ...
Effects of Nuclear Vibrations on the Energetics of Polythiophene: Quantized Energy Molecular Dynamics
15-05-2013 | Sergei Manzhos,, Australian Journal of Chemistry, 2013
Sergei Manzhos The molecular dynamics of polythiophene were computed with a new algorithm including the quantized nature of vibrations. The algorithm reproduces the quantum energies of vibrational modes (black line and blue dots), lost in standard MD (red line, blue triangles). Nuclear ...
Electrochemical Characterisation of Poly(aniline-co-N-methylaniline) and Poly(aniline-co-N-ethylaniline) Films on Pencil Graphite Electrode for Supercapacitor Applications
14-05-2013 | Andac Arslan, Evrim Hur,, Australian Journal of Chemistry, 2013
Andac Arslan, Evrim Hur Poly(aniline-co-N-methylaniline) and poly(aniline-co-N-ethylaniline) coated pencil graphite electrodes have been electrochemically characterised by different methods and their specific capacitance values have been determined. They can be used as electrode active ...
Ionic Liquids with Solvatochromatic and Charge-Transfer Functionalities Incorporating the Viologen Moiety
09-05-2013 | H. Q. Nimal Gunaratne, Peter Nockemann, Sonia Olejarz, Stephanie M. Reid, Kenneth R. Seddon, Geetha Srinivasan,, Australian Journal of Chemistry, 2013
H. Q. Nimal Gunaratne, Peter Nockemann, Sonia Olejarz, Stephanie M. Reid, Kenneth R. Seddon, Geetha Srinivasan ‘Liquid viologen’ derivatives are synthesised and their solvatochromic and charge transfer properties are demonstrated.
A Much-Needed Mechanism and Reaction Rate for the Oxidation of Phenols with ClO 2 : A Joint Experimental and Computational Study
26-04-2013 | Carlos Alberto Huerta Aguilar, Jayanthi Narayanan, Mariappan Manoharan, Narinder Singh, Pandiyan Thangarasu,, Australian Journal of Chemistry, 2013
Carlos Alberto Huerta Aguilar, Jayanthi Narayanan, Mariappan Manoharan, Narinder Singh, Pandiyan Thangarasu The kinetics of phenol oxidation with chlorine dioxide were analysed; 2,4,6-trichlorophenol exhibits a lower oxidation rate than the other phenols in agreement with the Hammett plot. ...
‘Classical’ and ‘Abnormal’ Bonding in Tin (II) N-Heterocyclic Carbene Complexes
26-04-2013 | Robert S. P. Turbervill, Jose M. Goicoechea,, Australian Journal of Chemistry, 2013
Robert S. P. Turbervill, Jose M. Goicoechea Reaction of Sn(OTf)2 (OTf–=OSO2CF3–) with one and two equivalents of 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) yielded the complexes [Sn(IPr)(OTf)2] (1) and [Sn(IPr)(aIPr)(OTf)][OTf] (2), respectively. Both compounds display an ...
C-Alkynylation of Chromones by Sonogashira Reaction
24-04-2013 | Tamás Patonay, István Pazurik, Anita Ábrahám,, Australian Journal of Chemistry, 2013
Tamás Patonay, István Pazurik, Anita Ábrahám Sonogashira reaction of bromochromones and -flavones with various terminal alkynes gave the desired alkynylated products. Chromones and flavones with ethynyl functionality were prepared by removal of the trimethylsilyl protecting group.
Trichloridothallium(III) Complexes with Bipyridine Derivatives: From Structure to Luminescence Properties
24-04-2013 | Zahra Ghiasi, Vahid Amani, Peiman Mirzaei, Nasser Safari, Anita Abedi,, Australian Journal of Chemistry, 2013
Zahra Ghiasi, Vahid Amani, Peiman Mirzaei, Nasser Safari, Anita Abedi Octahedral thallium(iii) complexes of [Tl(L)Cl3(DMSO)] (where L is a bipyridine derivative) exhibit enhanced fluorescence intensity in comparison with the related unbound bipyridine ligands, where a Tl complex with ...
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