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95 Newest Publications about the topic molecular sieves

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The Interaction of H2O2 with TiAlPO-5 Molecular Sieves. Probing the Catalytic Potential of Framework Substituted Ti Ions.

08-05-2013 | Mario Chiesa; Gloria Berlier; Sara Maurelli; Chiara Novara; Almudena Alfayate, Physical Chemistry Chemical Physics, 2013

A combination of EPR, ENDOR and HYSCORE experiments has been used to investigate the reactivity of hydrogen peroxide with TiAlPO-5 materials under both hydrated and anhydrous conditions. Superoxide radical anions, generated upon reaction, are used as paramagnetic probes to investigate the ...

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A study into Stille cross‐coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N‐donor groups at the surface

29-04-2013 | Miloslav Semler, Jiří Čejka, Petr Štěpnička, Applied Organometallic Chemistry, 2013

Mesoporous molecular sieve SBA‐15 and conventional silica gel were grafted with 3‐[2‐(diethylamino)ethylamino]propyl groups and used as supports for the preparation of deposited palladium catalysts, which were subsequently evaluated in Stille cross‐coupling reaction of aryl bromides. The ...

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Material Advancements in Fabrication of Mixed‐Matrix Membranes

24-04-2013 | R. Nasir, H. Mukhtar, Z. Man, D. F. Mohshim, Chemical Engineering & Technology, 2013

Abstract The mixed‐matrix membrane (MMM) is a new membrane material for gas separation and plays a vital role for the advancement of current membrane‐based separation technology. Blending between inorganic fillers like carbon molecular sieves, zeolite, metal oxides, silica and silica ...

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Aldehyde Self-Condensation Catalysis by Aluminum Aminoterephthalate Metal–Organic Frameworks Modified with Aluminum Isopropoxide

22-04-2013 | Lev Bromberg; Xiao Su; T. Alan Hatton, Chemistry of Materials, 2013

Porous materials based on aluminum(III) 2-aminoterephthalate metal organic frameworks (MOFs NH2MIL101(Al) and NH2MIL53(Al)) and their composites with aluminum isopropoxide (Al-i-Pro) are studied as sorbents of vapors of volatile aldehydes and catalysts of acetaldehyde dimerization to ethyl ...

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Synthesis of DNL‐6 with a High Concentration of Si (4 Al) Environments and its Application in CO2 Separation

18-04-2013 | Xiong Su, Peng Tian, Dong Fan, Qinghua Xia, Yue Yang, Shutao Xu, Lin Zhang, Ying Zhang, Dehua Wang, Zhongmin Liu, ChemSusChem, 2013

Abstract The synthesis of DNL‐6 with a high concentration of Si (4 Al) environments [Si/(Si+Al+P)=0.182 mol, denoted as M‐DNL‐6] is demonstrated. This represents the highest reported concentration of such environments in silicoaluminophosphate (SAPO) molecular sieves. Adsorption studies ...

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Efficient Access to Trifluoromethyl Diarylpyrrolines and their N‐Oxides through Enantioselective Conjugate Addition of Nitromethane to β,β‐Disubstituted Enones

18-04-2013 | Hiroyuki Kawai, Zhe Yuan, Takashi Kitayama, Etsuko Tokunaga, Norio Shibata, Angewandte Chemie International Edition, 2013

The cupreidinium salt 1 catalyzes the highly enantioselective conjugate addition of nitromethane to β‐aryl‐β‐trifluoromethyl aryl enones (2). The biologically important chiral pyrrolines 4 and N‐oxide 5, having a trifluoromethylated all‐carbon quaternary chiral center, were easily ...

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Reduced aggregation of NiS nanoparticles incorporated in AlMCM-41 material by neutron radiation

15-04-2013 | Author(s): D. Rezaei Ochbelagh , N. Morsali Golboos , Sh. Sohrabnezhad, Radiation Physics and Chemistry, 2013

Publication date: June 2013Source:Radiation Physics and Chemistry, Volume 87 Author(s): D. Rezaei Ochbelagh , N. Morsali Golboos , Sh. Sohrabnezhad Nickel sulfide nanoparticles powder was synthesized in AlMCM-41 molecular sieve by using ion exchange method. Sample was irradiated by ...

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Solution–processable exfoliated zeolite nanosheets purified by density gradient centrifugation

26-03-2013 | Kumar Varoon Agrawal, Berna Topuz, Marta Navarro, Zheyu Jiang, Kevin Nguenkam, Bahman Elyassi, Lorraine F. Francis, ..., AIChE Journal, 2013

Abstract Highly crystalline exfoliated MFI‐nanosheets can pave the way for large scale deployment of sub‐500‐nm zeolite membranes due to their processing and packing advantages. Exfoliated MFI‐nanosheets prepared by melt compounding contain a large amount of polymer and unexfoliated ...

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Modeling and optimization of gas transport characteristics of carbon molecular sieve membranes through statistical analysis

25-03-2013 | Vahid Pirouzfar, Seyed Saeid Hosseini, Mohammad Reza Omidkhah, Abdolsamad Zarringhalam Moghaddam, Polymer Engineering and Science, 2013

Abstract This study aims to propose the importance of employing statistical analysis and modeling for investigation on the design and optimization of CMS membranes for gas separation. The factorial methodology is used to optimize permeability and selectivity through implementing the ...

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Gas separation performance of carbon materials produced from phenolic resin: Effects of carbonization temperature and ozone post treatment

25-03-2013 | New Carbon Materials, 2013

February 2013 Publication year: 2013Source:New Carbon Materials, Volume 28, Issue 1 The effect of carbonization temperature and treatment with ozone on the porosity and gas separation behavior of carbons produced from phenolic resin was investigated. Results showed that with ...

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