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27,992 Newest Publications about the topic solution

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Micellar and vesicular nanoassemblies of triazole-based amphiphilic probes triggered by mercury(II) ions in a 100% aqueous medium

22-10-2014 | Inhye Kim; Na-Eun Lee; Yoo-Jeong Jeong; Young-Ho Chung; Byoung-Ki Cho; Eunji Lee, Chemical Communication, 2014

ABA-type amphiphiles bearing a triazole-based aromatic block were easily synthesized using click chemistry, which act as fluorescent turn-off Hg2+–chemoprobes in an aqueous solution. Interestingly, the metal-binding process of amphiphiles induced nanoassemblies even below the CMCs, and the ...


Supramolecular photochemistry: from molecular crystals to water-soluble capsules

22-10-2014 | V. Ramamurthy; Shipra Gupta, Chemical Society Reviews, 2014

Photochemical and photophysical behavior of molecules in supramolecular assemblies are different and more selective than in gas and isotropic solution phases. Knowledge of the inherent electronic and steric properties of the reactant is insufficient to predict the excited state behavior of ...


A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage

22-10-2014 | Hemlata Patil; Wang Xi Zu; Akhil Gupta; Vijila Chellappan; Ante Bilic; Prashant Sonar; Anushri Rananaware; Sidhanath ..., Physical Chemistry Chemical Physics, 2014

A novel solution-processable non-fullerene electron acceptor 6,6′-(5,5′-(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, ...


Hydration of Cyanide Anion: An Ab Initio Quantum Mechanical Charge Field Molecular Dynamics Study

22-10-2014 | Syed Tarique Moin; Thomas Hofer, Physical Chemistry Chemical Physics, 2014

This paper presents an ab initio quantum mechanical charge field molecular dynamics simulation study of the cyanide anion CN- in aqueous solution where hydrogen bond formation plays a dominant role in the hydration process. Preferential orientation of water hydrogens compared to oxygen atoms was ...


A cheap and facile route to synthesize monodisperse magnetic nanocrystals and application as MRI agent

21-10-2014 | guixin yang; fei he; ruichan lv; shili gai; Ziyong Cheng; yunlu dai; piaoping yang, Dalton Transactions, 2014

A facile solution-based thermal decomposition strategy, using very cheap polyisobutene succimide (PIBSI) and paraffin oil as surfactant and solvent, has been developed for the controllable synthesis of magnetic MnFe2O4 and CoFe2O4 nanocrystals (NCs) with high dispersibility, uniform shape, and ...


The solution chemistry and reactivity of lacunary Keggin silicotungstates monitored in real-time by a combination of mass spectrometry and electrochemistry

21-10-2014 | QiaoDi Jia; Jie Cao; YunPeng Duan; Changwen Hu, Dalton Transactions, 2014

The solution chemistry of a series of mono-, di- and trilacunary Keggin silicotungstates was investigated by electrospray mass spectrometry (ESI-MS) and general electrospray features especially for lacunary POMs were summarized. The reactions of vanadium-incorporation into the lacunary structures ...


Synthesis of one-dimensional WO3-Bi2WO6 heterojunctions with enhanced photocatalytic activity

21-10-2014 | An-Wu Xu; yin peng; qing guo chen; dan wang; hai yan zhou, CrystEngComm, 2014

WO3-Bi2WO6 heterostructures were synthesized by a facile hydrothermal method using WO3 nanorods and Bi(NO3)3 solution as raw materials. The Bi2WO6 nanosheets uniformly anchored on the surface of WO3 nanorods. The photocatalytic activity of the samples was assessed for degradation of Rhodamin B ...


Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M–S bonding for MS42− (M = Cr, Mo, W) dianions

21-10-2014 | Angela C. Olson; Jason M. Keith; Enrique R. Batista; Kevin S. Boland; Scott R. Daly; Stosh A. Kozimor; Molly M. MacI ..., Dalton Transactions, 2014

Herein, we have evaluated relative changes in M–S electronic structure and orbital mixing in Group 6 MS42− dianions using solid- and solution-phase S K-edge X-ray absorption spectroscopy (XAS; M = Mo, W), as well as density functional theory (DFT; M = Cr, Mo, W) and time-dependent density ...


Self-catalytic synthesis of metal oxide nanoclusters@mesoporous silica composites based on successive spontaneous reactions at near neutral conditions

21-10-2014 | Fang Cui; Tieyu Cui, Chemical Communication, 2014

A facile self-catalytic approach for the synthesis of metal oxide nanoclusters@mesoporous silica was proposed by subtly making use of successive spontaneous reactions in solution at near neutral conditions.


“Ready-to-Use” Hollow Nanofiber Membrane-Based Glucose Testing Strips

21-10-2014 | Xiaoyuan Ji; Zhiguo Su; Ping Wang; Guanghui Ma; Songping Zhang, Analyst, 2014

A novel “ready-to-use” glucose test strip based on polyurethane hollow nanofibers membrane was fabricated through facile co-axial electrospinning. By involving glucose oxidase and horseradish peroxidase in the core-phase solution, and chromogenic agent either in core-solution (in case of ...


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