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33,366 Newest Publications about the topic solution

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Particle Size–Related Elemental Fractionation in Laser Ablation in Liquid Inductively Coupled Plasma Mass Spectrometry

14-Oct-2015 | Ryo Machida; Takashi Nakazawa; Yuka Sakuraba; Masahide Fujiwara; Naoki Furuta, Journal of Analytical Atomic Spectrometry, 2015

Particles sampled by means of laser ablation in liquid (LAL) can be analyzed by inductively coupled plasma mass spectrometry (ICPMS) after acid digestion or slurry nebulization. The LAL sampling process is simple, and a standard solution can be used for calibration. In this study, we investigated ...


Simultaneous electrochemical detection of catechol and hydroquinone based on gold nanoparticles@carbon nanocages modified electrode

14-Oct-2015 | Yi Hong Huang; JianHua Chen; Li Jing Ling; Zhen Bo Su; Xue Sun; Shirong Hu; Wen Weng; Yang Huang; Wen Bing Wu; Ya Sh ..., Analyst, 2015

In the present study, carbon nanocages (CNCs) decorated with diameters of 2-5 nm gold nanoparticles (AuNPs) were synthesized by simply mixing their solution. The size of the AuNPs is small enough to diffusion into the inside of CNCs by electrostatic incorporation and their morphologies were ...


Solution based CVD of main group materials

14-Oct-2015 | Caroline E. Knapp; Claire J. Carmalt, Chemical Society Reviews, 2015

This critical review focuses on the solution based chemical vapour deposition (CVD) of main group materials with particular emphasis on their current and potential applications. Deposition of thin films of main group materials, such as metal oxides, sulfides and arsenides, have been researched ...


Oxocomplexes of Mo(VI) and W(VI) with 8-Hydroxyquinoline-5-Sulfonate in Solution: Structural Studies and the Effect of the Metal Ion on the Photophysical Behaviour

14-Oct-2015 | Maria Luísa Ramos; Licinia L. G. Justino; Paulo Eduardo Martins de Castro Nev Abreu; Sofia M Fonseca; H D Burrows, Dalton Transactions, 2015

Multinuclear (1H, 13C, 95Mo and 183W) NMR spectroscopy, combined with DFT calculations, provides detailed information on the complexation between the Mo(VI) and W(VI) oxoions and 8-hydroxyquinoline-5-sulfonate (8-HQS) in aqueous solution. Over the concentration region studied, Mo(VI) and W(VI) ...


pH-dependent solution dynamics of a manganese(II) polyoxometalate, [Mn4(H2O)2(P2W15O56)2]^16-, and [Mn(H2O)6]^2+

14-Oct-2015 | Rupali Sharma; Jie Zhang; C. André Ohlin, Dalton Transactions, 2015

The aqueous reaction dynamics of the manganese(II)-functionalised Wells-Dawson polyoxometalate [Mn4(H2O)2(P2W15O56)2]^16- has been determined as a function of pH using variable temperature 17O NMR, and compared with that of the well-studied monomeric manganese(II) hexa-aqua ion, [Mn(H2O)6]^2+. ...


Structure of P3HT crystals, thin films, and solutions by UV/Vis spectral analysis

14-Oct-2015 | Marcus Böckmann; Thomas Schemme; Djurre H. de Jong; Cornelia Denz; Andreas Heuer; Nikos L. Doltsinis, Physical Chemistry Chemical Physics, 2015

Optical absorption spectra of poly(3-hexylthiophene) (P3HT) are calculated in solution, spin-coated thin films, and the bulk crystal using a multiscale simulation approach. The structure of the amorphous thin film is obtained from coarse grained molecular dynamics (MD) simulations and subsequent ...


Rapid formation of a stable boron–nitrogen heterocycle in dilute, neutral aqueous solution for bioorthogonal coupling reactions

14-Oct-2015 | Ozlem Dilek; Zhen Lei; Kamalika Mukherjee; Susan Bane, Chemical Communication, 2015

Combining 2-formylphenylboronic acid with 4-hydrazinylbenzoic acid in neutral aqueous solution at low, equimolar concentrations of the reagents results in a single, stable product, a 1,2-dihydro-1-hydroxy-2,3,1-benzodiazaborine, in a matter of minutes with no side products. Application of this ...


Experimental and quantum chemical determination of the hydration structure and stability of Pa(IV) and tetravalent actinides up to Bk(IV): the evidence of a curium break

14-Oct-2015 | Nidhu Banik; Valerie Vallet; Florent Réal; Réda Mohamed Belmecheri; Bernd Schimmelpfennig; Joerg Rothe; Remi Marsac; ..., Dalton Transactions, 2015

A century after its discovery, the structure of the Pa4+ ion in acidic aqueous solution has been investigated for the first time experimentally and by quantum chemistry. The combined results of EXAFS data and quantum chemically optimized structures suggest that the Pa4+ aqua ion has an average of ...


Accumulation and spatial distribution of arsenic and phosphorus in the fern Pityrogramma calomelanos evaluated by micro X-Ray fluorescence spectrometry

14-Oct-2015 | Naiara Viana Campos; Marcelo Braga Bueno Guerra; Jaime Wilson Vargas Mello; Carlos Ernesto Gonçalves Reynaud Schaefe ..., Journal of Analytical Atomic Spectrometry, 2015

The accumulation and spatial distribution of arsenic and phosphorus in the As-hyperaccumulator fern Pityrogramma calomelanos were investigated with micro-energy dispersive X-ray fluorescence spectrometry (µ-EDXRF). Ferns were grown in half-strength Hoagland nutrient solution without and with 1.0, ...


Calculation of photon pulse height distribution using deterministic and Monte Carlo methods

12-Oct-2015 | Author(s): Azadeh Akhavan, Naser Vosoughi, Radiation Physics and Chemistry, 2015

Publication date: December 2015 Source:Radiation Physics and Chemistry, Volume 117 Author(s): Azadeh Akhavan, Naser Vosoughi Radiation transport techniques which are used in radiation detection systems comprise one of two categories namely probabilistic and deterministic. However, ...


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