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Thermodynamic Data for the Modeling of Lanthanoid(III) Sequestration by Reduced Glutathione in Aqueous Solution

26-Dec-2014 | Rosalia Maria Cigala; Concetta De Stefano; Anna Irto; Demetrio Milea; Silvio Sammartano, Journal of Chemical & Engineering Data, 2014

This contribution reports the results of an investigation on the speciation of various lanthanoid(III) cations (Ln3+), namely, La3+, Nd3+, Sm3+, Eu3+, Gd3+, Dy3+, and Yb3+, in the presence of reduced glutathione (or simply glutathione, GSH), in NaCl(aq) at I = 0.15 mol·dm–3 and T = 298.15 K. GSH ...


Preparation of a Novel Supported Selenium Nanoparticles Adsorbent and Its Application for Copper Removal from Aqueous Solution

16-Dec-2014 | Lingyan Huang; Xing Tong; Yunzhi Li; Jiuwei Teng; Yan Bai, Journal of Chemical & Engineering Data, 2014

A novel supported nanoadsorbent (nanoSe0-supported/cotton) was prepared by loading selenium nanoparticles with sucrose on absorbent cotton. The feasibility of using nanoSe0-supported/cotton to remove Cu from aqueous solution has been confirmed in batch and continuous systems. Effective ...


Solubilities of Carbon Dioxide in Five Biobased Solvents

15-Dec-2014 | Dongshun Deng; Guoqiang Han; Yaotai Jiang; Ning Ai, Journal of Chemical & Engineering Data, 2014

Solubilities of CO2 in five biobased solvents (BBSs) were measured at temperatures ranging from 283.15 K to 323.15 K with 10 K intervals under a pressure of 0 kPa to 600.0 kPa using an isochoric saturation method. The BBSs include dibutyl succinate (DBS), gamma-valerolactone (GVL), furfuryl ...


Viscosity and Density of Aqueous Solutions of Carbon Dioxide at Temperatures from (274 to 449) K and at Pressures up to 100 MPa

12-Dec-2014 | Mark McBride-Wright; Geoffrey C. Maitland; J. P. Martin Trusler, Journal of Chemical & Engineering Data, 2014

The viscosity and density of aqueous solutions of carbon dioxide having mole fractions of CO2 of 0.0086, 0.0168, and 0.0271 are reported. The measurements were made in the single-phase compressed liquid region at temperatures between (294 and 449) K at pressures up to 100 MPa; additional density ...


Surface Tension Prediction of Ionic Liquid Binary Solutions

01-Dec-2014 | Ensieh Ghasemian Lemraski; Zohre Pouyanfar, Journal of Chemical & Engineering Data, 2014

An ionic liquid is a salt in which the ions are poorly coordinated, which results in these solvents being liquid below 100 °C, or even at room temperature. At least one ion has a delocalized charge, and one component is organic, which prevents the formation of a stable crystal lattice. In the ...


Stable Phase Equilibrium of Aqueous Quaternary System Li+, K+, Mg2+//Borate–H2O at 348 K

01-Dec-2014 | Qi Tan; Ying Zeng; Pengtao Mu; Xudong Yu; Yujuan Zhang, Journal of Chemical & Engineering Data, 2014

The solubility values and physicochemical properties such as densities, refractive indices, and pH values of the equilibrium solution in the quaternary system Li+, K+, Mg2+//borate–H2O at 348 K were measured by isothermal dissolution method. The phase diagram, water content diagram, and the ...


Solid–Liquid Equilibrium for the Ternary Systems (Na2SO4 + NaH2PO4 + H2O) and (Na2SO4 + NaCl + H2O) at 313.15 K and Atmospheric Pressure

26-Nov-2014 | Xiaorui Zhang; Yongsheng Ren; Ping Li; Huijuan Ma; Wenjuan Ma; Chengqi Liu; Ya’nan Wang; Lingxin Kong; Wei Shen, Journal of Chemical & Engineering Data, 2014

Solid–liquid equilibrium in the ternary systems (Na2SO4 + NaH2PO4 + H2O) and (Na2SO4 + NaCl + H2O) at 313.15 K and atmospheric pressure was investigated by using isothermal solution saturation and moist residue method. The solubility and thermodynamic properties of the solution were determined. ...


Measurement and Thermodynamic Modeling Study on the Solid and Liquid Equilibrium of Ternary System NaBr–CaBr2–H2O at 288.15 K

26-Nov-2014 | Lingzong Meng; Dan Li; Tianlong Deng; Yafei Guo; Cunyun Ma; Youcai Zhu, Journal of Chemical & Engineering Data, 2014

The solubilities and refractive indices of the NaBr–CaBr2–H2O system at 288.15 K were determined using the isothermal equilibrium solution method. The phase diagram and refractive index diagram were drawn for this system at 288.15 K. The system belongs to the hydrate II type. The phase diagram is ...


Diffusion Coefficients of Carbon Dioxide in Brines Measured Using 13C Pulsed-Field Gradient Nuclear Magnetic Resonance

24-Nov-2014 | Shane P. Cadogan; Jason P. Hallett; Geoffrey C. Maitland; J. P. Martin Trusler, Journal of Chemical & Engineering Data, 2014

Tracer diffusion coefficients of CO2 in several brines were measured by 13C pulsed-field gradient NMR at a temperature of 298 K and at salt molalities of up to 5 mol·kg–1. The brines studied were NaCl(aq), CaCl2(aq), Na2SO4(aq), and a mixed brine prepared from seven salts: NaCl, CaCl2, MgCl2, ...


Solubilities of Adipic Acid and Succinic Acid in a Glutaric Acid + Acetone or n-Butanol Mixture

10-Nov-2014 | Yanyan Li; Yatao Wang; Zhuoyuan Ning; Jianfang Cui; Qiaoye Wu; Xunqiu Wang, Journal of Chemical & Engineering Data, 2014

In order to provide thermodynamic data for mixed dibasic acid separation technology, the solubilities of adipic acid (AA) and succinic acid (SA) in glutaric acid (GA) + acetone mixture and GA + n-butanol mixture were measured by dynamic method at atmospheric pressure. The mass fraction of GA ...


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