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27,461 Newest Publications about the topic solution

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The Stabilisation of Gallane and Indane by a Ring Expanded Carbene

25-11-2014 | Anthony R Leverett; Alasdair Iain McKay; Marcus Lawford Cole, Dalton Transactions, 2014

7Dipp Complexes of the group 13 binary hydrides GaH3 and InH3 have been prepared. Both adducts possess excellent thermal stability in the solid state but decompose readily in solution at ambient temperature. The presence of short M-H….H-CAlkyl distances in the structures of both [MH3(7Dipp)] ...

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Oxidation of refractory sulfur-containing compounds with molecular oxygen catalyzed by vanadoperiodate

25-11-2014 | Nanfang Tang; Zongxuan Jiang; Can Li, Green Chemistry, 2014

A new vanadoperiodate [HIV9O28]3- has been synthesized by a simple, one-pot stoichiometric reaction of HIO4•2H2O with NaVO3 in aqueous solution, and then isolated as [C8H17N(CH3)3]3HIV9O28 by cation exchange. We found that [C8H17N(CH3)3]3HIV9O28 shows high catalytic activity in oxidation of ...

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Solution immersed silicon (SIS) based biosensors: a new approach in biosensing

25-11-2014 | Mangesh S. Diware; H. M. Cho; Won Chegal; Y. J. Cho; J. H. Jo; S.W. O; Se-Hwan Paek; Y. H. Yoon; D. Kim, Analyst, 2014

A novel solution immersed silicon (SIS) based sensor has been developed which employs the Non-Reflecting Condition (NRC) for p-polarized wave. The SIS sensor's response is almost independent of change in refractive index (RI) of a buffer solution (BS) which makes it capable of measuring low ...

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Solution Phase Post-modification of Trimesic Acid Network on Au(111) with Zn2+ Ions

25-11-2014 | Jaesung Lee; Jandee Kim; Hyeran Kim; Choong Kyun Rhee; Mike Whangbo, Chemical Communication, 2014

Solution phase post-modification of trimesic acid (TMA) network on Au(111) with Zn2+ ions was found to induce a transformation of a bar-featured scanning tunneling microscopy image of (5√3 × 5√3) to a chevron-pair image of (10√3 × 10√3). Voltammetric determination of Zn coverage in the modified ...

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Synergy of Oxygen and Piranha Solution for Eco-Friendly Production of Highly Conductive Graphene Dispersions

25-11-2014 | keerthi Savaram; Malathi Kalyanikar; Mehulkumar A Patel; Roman Brukh; Carol R. Flach; Ruiming Huang; M.Reza Khoshi; ..., Green Chemistry, 2014

A variety of strategies for the synthesis of solution processable graphene sheets have been developed. However, no approach has been reported to directly produce highly conductive, low-oxygen containing graphene sheets without relying on toxic reagents and metal containing compounds, and without ...

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Representing the potential-energy surface of protonated water clusters by high-dimensional neural network potentials

25-11-2014 | Suresh Kondati Natarajan; Tobias Morawietz; Jörg Behler, Physical Chemistry Chemical Physics, 2014

Investigating the properties of protons in water is essential for understanding many chemical processes in aqueous solution. While important insights can in principle be gained by accurate and well-established methods like ab initio molecular dynamics simulations, the computational costs of these ...

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From oligomers towards a racemic crystal: molecular simulation of DL-norleucine crystal nucleation from solution

25-11-2014 | Dirk Zahn; Philipp Ectors; Patrick Duchstein, CrystEngComm, 2014

We elucidate the evolution of forming nuclei leading towards a racemic molecular crystal by means of computer simulation. Our simulations start with the association of individual D- and L-norleucine molecules and subsequent formation of aggregates, and thus provide molecular scale insights into ...

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Synthesis of ZrO2/Carbon Aerogel Composite with Tetragonal ZrO2 Structures Assisted by the Formation of Phenol-Formaldehyde Resin

25-11-2014 | Yi-Feng Lin; Fang-Ling Liang, CrystEngComm, 2014

In this study, monoclinic ZrO2 nanoparticles were successfully prepared using a hydrothermal process. When phenol was added to the resulting solution for the hydrothermal reaction, ZrO2/phenol formaldehyde (PF) resins with tetragonal ZrO2 crystalline phases were synthesized. Tetragonal ZrO2 ...

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Probing coiled-coil assembly by paramagnetic NMR spectroscopy

25-11-2014 | Tingting zheng; Aimee Boyle; Hana Robson Marsden; Dayenne Valdink; Giuliana Martelli; jan raap; alexander kros, Organic & Biomolecular Chemistry, 2014

Here a new method to determine the oligomeric state and orientation of coiled-coil peptide motifs is described. Peptides K and E, which are designed to form a parallel heterodimeric complex in aqueous solution, were labelled with the aromatic amino acids tryptophan and tyrosine on the C-terminus ...

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Structure and Dynamics of Oligonucleotides in the Gas Phase

21-11-2014 | Annalisa Arcella, Jens Dreyer, Emiliano Ippoliti, Ivan Ivani, Guillem Portella, Valérie Gabelica, Paolo Carloni, Mod ..., Angewandte Chemie International Edition, 2014

Abstract By combining ion‐mobility mass spectrometry experiments with sub‐millisecond classical and ab initio molecular dynamics we fully characterized, for the first time, the dynamic ensemble of a model nucleic acid in the gas phase under electrospray ionization conditions. The studied ...

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