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Sugar-functionalized triptycenes used for dispersion of single-walled carbon nanotubes in aqueous solution by supramolecular interaction

09-Feb-2016 | Hui Li; Qi Chen; Bao-Hang Han, New Journal of Chemistry, 2016

Noncovalent functionalization of carbon nanotubes (CNTs) can not only preserve their unique properties, but also improve nanotube’s solubility in solvent. Herein, two water-soluble sugar-functionalized triptycene derivatives were synthesized and interacted with single-walled carbon nanotubes ...


Easy and eco-friendly synthesis of ordered mesoporous carbons by self-assembly of tannin with a block copolymer

09-Feb-2016 | F. L. Braghiroli; V. Fierro; J. Parmentier; A. Pasc; A. Celzard, Green Chemistry, 2016

Ordered mesoporous carbons were prepared by the self-assembly of Mimosa tannin, a natural polyphenolic molecule, and a micellar solution of Pluronic® F127, used as soft template. The synthesis was carried out at 20 °C using water as the only solvent and without crosslinker agent (i.e., ...


Microfluidic devices with templated regular macroporous structures for HIV viral capture

09-Feb-2016 | Krissada Surawathanawises; Kathryn Kundrod; Xuanhong Cheng, Analyst, 2016

There is a need to develop inexpensive, portable and easy-to-use devices for viral sample processing for resource-limited settings. Here we offer a solution to efficient virus capture by incorporating macroporous materials with regular structures into microfluidic devices for affinity ...


Supramolecular aggregation of Ni(salen) with (C6F5)2Hg and [o-C6F4Hg]3

09-Feb-2016 | Mitsukimi Tsunoda; Martin Fleischmann; James Jones; Nattamai Bhuvanesh; Manfred Scheer; F P Gabbai, Dalton Transactions, 2016

As part of our ongoing interest in metallophilic bonding, we have investigated the interaction of bis(pentafluorophenyl)mercury ((C6F5)2Hg), and trimeric (perfluoro-o-phenylene)mercury ([o-C6F4Hg]3), with nickel(II) N,N′-di(salicylidene)ethylenediamine) (Ni(salen)). While solution studies ...


Platinum phosphinothiolato hydride complexes: synthesis, structure and evaluation as tin-free hydroformylation catalysts

09-Feb-2016 | Julio Real; Esther Prat-Gil; Montserrat Pagès-Barenys; Alfonso Polo; Joan F. Piniella; Ángel Álvarez-Larena, Dalton Transactions, 2016

Ligand 2-diphenylphosphinothiophenol (Hsarp) reacted with Pt(PPh3)4 to yield trans-[PtH(sarp)(PPh3)], which undergoes fast exchange with free PPh3 on the NMR time scale and very slowly and reversibly formed some cis-[PtH(sarp)(PPh3)] over time in solution (11%, 24 h). Reaction of ...


Bio-inspired stabilization of sulfenyl iodide RS-I in a Zr(IV)-based metal-organic framework

09-Feb-2016 | Ka-Kit Yee; Yan-Lung Wong; Zhengtao Xu, Dalton Transactions, 2016

A Zr(IV)-based metal-organic framework (MOF) appended with free-standing thiol (–SH) groups was found to react readily with I2 molecules to form sulfenyl iodide (S-I) units. In contrast to its solution chemistry of facile disproportionation into disulfide and I2, the sulfenyl iodide (SI) ...


Electrochemical fabrication and interfacial charge-transfer process of Ni/GaN(0001) electrodes

09-Feb-2016 | Shuang-Jiao Qin; Fei Peng; Xue-Qing Chen; Ge-Bo Pan, Physical Chemistry Chemical Physics, 2016

The electrodeposition of Ni on single-crystal n-GaN(0001) film from acetate solution was investigated using scanning electron microscopy, X-ray diffraction, energy dispersive X-ray analysis, atomic force microscopy, and electrochemical techniques. The as-deposited Ni/n-GaN(0001) had a flat band ...


Neutral, heteroleptic copper(I)-4H-imidazolate complexes: synthesis and characterization of their structural, spectral and redox properties

09-Feb-2016 | Martin Schulz; Fabian Dröge; Felix Herrmann; Julian Schindler; Helmar Görls; Martin Presselt, Dalton Transactions, 2016

Facile synthetic access to four novel, neutral, heteroleptic copper(I)-complexes, incorporating 4H-imidazolates as well as the bisphosphane ligands XantPhos and DPEPhos is reported. The complexes were characterized in the solid state as well as in solution by means of single crystal X-ray ...


A simple Schiff base molecular logic gate for detection of Zn2+ in water and its bio-imaging application in plant system

07-Feb-2016 | Author(s): Barnali Naskar, Ritwik Modak, Yeasin Sikdar, Dilip K. Maiti, Avishek Banik, Tushar Kanti Dang ..., Journal of Photochemistry and Photobiology A: Chemistry, 2016

Publication date: 1 May 2016 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volume 321 Author(s): Barnali Naskar, Ritwik Modak, Yeasin Sikdar, Dilip K. Maiti, Avishek Banik, Tushar Kanti Dangar, Subhrakanti Mukhopadhyay, Debasish Mandal, Sanchita Goswami ...


Entropy, Vol. 18, Pages 55: Stability Analysis and Synchronization for a Class of Fractional-Order Neural Networks

06-Feb-2016 | Li, Guanjun ; Liu, Heng, Entropy, 2016

Stability of a class of fractional-order neural networks (FONNs) is analyzed in this paper. First, two sufficient conditions for convergence of the solution for such systems are obtained by utilizing Gronwall–Bellman lemma and Laplace transform technique. Then, according to the fractional-order ...


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