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Alkoxide Coordination of Iron(III) Protoporphyrin IX by Antimalarial Quinoline Methanols: A Key Interaction Observed in the Solid-State and Solution

02-Sep-2015 | Johandie Gildenhuys; Chandre J Sammy; Ronel Müller; Victor A Streltsov; Tanya le Roex; David Kuter; Katherine Alliso ..., Dalton Transactions, 2015

The quinoline methanol antimalarial drug mefloquine is a structural analogue of the Cinchona alkaloids, quinine and quinidine. We have elucidated the single crystal X-ray diffraction structure of the complexes formed between racemic erythro mefloquine and ferriprotoporphyrin IX (Fe(III)PPIX) and ...

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Aluminum and its effect in the equilibrium between folded/unfolded conformation of NADH

30-Aug-2015 | Author(s): Elena Formoso, Jon I. Mujika, Slawomir J. Grabowski, Xabier Lopez, Journal of Inorganic Biochemistry, 2015

Publication date: Available online 29 August 2015 Source:Journal of Inorganic Biochemistry Author(s): Elena Formoso, Jon I. Mujika, Slawomir J. Grabowski, Xabier Lopez Nicotinamide adenine dinucleotide (NADH) is one of the most abundant cofactor employed by proteins and enzymes. The ...

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Oxygen electroreduction on MN4-macrocycle modified graphene/multi-walled carbon nanotube composites

30-Aug-2015 | Author(s): Karl-Kalev Türk, Ivar Kruusenberg, Jayanta Mondal, Protima Rauwel, Jekaterina Kozlova, Leonard ..., Journal of Electroanalytical Chemistry, 2015

Publication date: 1 November 2015 Source:Journal of Electroanalytical Chemistry, Volume 756 Author(s): Karl-Kalev Türk, Ivar Kruusenberg, Jayanta Mondal, Protima Rauwel, Jekaterina Kozlova, Leonard Matisen, Väino Sammelselg, Kaido Tammeveski In this work the electrocatalysis ...

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Tris(trifluoromethyl)germylethynyl derivatives of biphenyl and anthracene: Synthesis, structure, and evidence of the intramolecular charge transfer on the germanium center

30-Aug-2015 | Author(s): Nikolai L. Ermolaev, Ilya V. Lenin, Georgii K. Fukin, Andrei S. Shavyrin, Mikhail A. Lopatin, O ..., Journal of Organometallic Chemistry, 2015

Publication date: 15 November 2015 Source:Journal of Organometallic Chemistry, Volume 797 Author(s): Nikolai L. Ermolaev, Ilya V. Lenin, Georgii K. Fukin, Andrei S. Shavyrin, Mikhail A. Lopatin, Olga V. Kuznetsova, Boris A. Andreev, Denis I. Kryzhkov, Stanislav K. Ignatov, ...

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Benzimidazo[2,1-a]benz[de]isoquinoline-7-one-12-carboxylic acid based fluorescent sensors for pH and Fe3+

30-Aug-2015 | Author(s): Yingying Zhao, Guangyou Zhang, Zheng Liu, Chaoxia Guo, Cuina Peng, Meishan Pei, Ping Li, Journal of Photochemistry and Photobiology A: Chemistry, 2015

Publication date: 1 January 2016 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volume 314 Author(s): Yingying Zhao, Guangyou Zhang, Zheng Liu, Chaoxia Guo, Cuina Peng, Meishan Pei, Ping Li Photophysical properties of two new naphthalimide derivatives, ...

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Ab initio molecular dynamics simulation of aqueous solution of nitric oxide in different formal oxidation states

30-Aug-2015 | Author(s): Mateus F. Venâncio, Willian R. Rocha, Chemical Physics Letters, 2015

Publication date: 1 October 2015 Source:Chemical Physics Letters, Volume 638 Author(s): Mateus F. Venâncio, Willian R. Rocha Ab initio molecular dynamics simulations were used to investigate the early chemical events involved in the dynamics of nitric oxide (NO), nitrosonium cation ...

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Electrochemical surface plasmon resonance sensing with absorptive redox mediator film

30-Aug-2015 | Author(s): Sergiy Patskovsky, Anne-Marie Dallaire, Michel Meunier, Sensors and Actuators B: Chemical, 2015

Publication date: January 2016 Source:Sensors and Actuators B: Chemical, Volume 222 Author(s): Sergiy Patskovsky, Anne-Marie Dallaire, Michel Meunier Surface plasmon resonance (SPR) spectroscopy has been used for the detection of reversible refractive index changes that occur in a ...

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A bis(pyridine-2-ylmethyl)amine-based selective and sensitive colorimetric and fluorescent chemosensor for Cu2+

30-Aug-2015 | Author(s): Xu Zheng, Kum Hee Lee, Hongguang Liu, So-Young Park, Seung Soo Yoon, Jin Yong Lee, Yang-Gyun ..., Sensors and Actuators B: Chemical, 2015

Publication date: January 2016 Source:Sensors and Actuators B: Chemical, Volume 222 Author(s): Xu Zheng, Kum Hee Lee, Hongguang Liu, So-Young Park, Seung Soo Yoon, Jin Yong Lee, Yang-Gyun Kim A new bis(pyridine-2-ylmethyl)amine derivative (1) was synthesized as a colorimetric ...

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Comparison Studies on Covalently and Non‐covalently Modified MWNTs Using Chitosan and Their Starch Nanocomposites

28-Aug-2015 | Zhenqiong Gou, Dan Xu, Quan Dong, Xiyu Wu, Starch - Stärke, 2015

Multi‐walled carbon nanotubes (MWNTs) were separately modified using chitosan (CS) through covalent grafting (MWNTs‐CS) and non‐covalent blending (MWNTs/CS). The modified MWNTs were characterized by FTIR, SEM, XRD, thermogravimetric analysis (TGA) and UV‐vis spectroscopy. Then, they were ...

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Photolithographic Encoding of Metal Complexes

28-Aug-2015 | Christiane Lang, Sebastian Bestgen, Alexander Welle, Rouven Müller, Peter W. Roesky, Christopher Barner‐Kowollik, Chemistry - A European Journal, 2015

Abstract A platform technology for the creation of spatially resolved surfaces encoded with a monolayer consisting of different metal complexes was developed. The concept entails the light‐triggered activation of a self‐ assembled monolayer (SAM) of UV‐labile anchors, that is, ...

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