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Dissipative Particle Dynamics Simulation Study on Self-Assembly of Amphiphilic Hyperbranched Multiarm Copolymers with Different Degrees of Branching

02-Sep-2015 | Haina Tan; Wei Wang; Chunyang Yu; Yongfeng Zhou; Zhong-Yuan Lu; Deyue Yan, Soft Matter, 2015

Hyperbranched multiarm copolymers (HMCs) have shown great potentials to be excellent precursors in self-assembly to form various supramolecular structures in all scales and dimensions in solution. However, theoretical studies on the self-assembly of HMCs, especially the self-assembly dynamics and ...

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Reductive amination of furfural to furfurylamine using aqueous ammonia solution and molecular hydrogen: an environmentally friendly approach

02-Sep-2015 | Maya Chatterjee; Takayuki Ishizaka; Hajime Kawanami, Green Chemistry, 2015

A simple and highly efficient method was developed for the transformation of furfural (a biomass derived aldehyde) to furfurylamine by reductive amination using an aqueous solution of ammonia and molecular hydrogen as an amine source and a reducing agent, respectively. By choosing a suitable ...

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Extensional viscosity of copper nanowire suspensions in an aqueous polymer solution

02-Sep-2015 | Amarin George McDonnell; Naveen N. Jason; Leslie Yeo; James R. Friend; Wenlong Cheng; Prabhakar Ranganathan, Soft Matter, 2015

Suspensions of copper nanowires are emerging as new electronic inks for next-generation flexible electronics. Using a novel surface acoustic wave driven extensional flow technique we are able to perform currently lacking analysis of these suspensions and their complex buffer. We observe ...

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A chemical method for stabilizing a new series of solid solution in Pr1-xCexScO3 (0.0 [less-than-or-equal] x [less-than-or-equal] 1.0) system

02-Sep-2015 | Farheen N Sayed; Rakesh R Shukla; A. K. Tyagi, Dalton Transactions, 2015

A new series of Pr1-xCexScO3 (0.0 ≤ x ≤ 1.0) compounds was synthesized by a two-step synthesis route, involving combustion reaction followed by reduction while heating in low partial pressure of O2, generated by zirconium sponge that acts as an oxygen getter. For the first time, a perovskite ...

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Highly efficient visible-light-driven CO2 reduction to CO using a Ru(II)–Re(I) supramolecular photocatalyst in an aqueous solution

02-Sep-2015 | Akinobu Nakada; Kazuhide Koike; Kazuhiko Maeda; Osamu Ishitani, Green Chemistry, 2015

In an aqueous solution, [Ru(dmb)2-(BL)–Re(CO)3Cl]2+ (BL = bridging ligand) most efficiently photocatalyzed reduction of CO2 to CO under visible-light irradiation using 2-(1,3-dimethyl-2,3-dihydro-1H-benzimidazol-2-yl)benzoic acid (BI(CO2H)H) as a water-soluble sacrificial reductant (ΦCO = 13%, ...

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Alkoxide Coordination of Iron(III) Protoporphyrin IX by Antimalarial Quinoline Methanols: A Key Interaction Observed in the Solid-State and Solution

02-Sep-2015 | Johandie Gildenhuys; Chandre J Sammy; Ronel Müller; Victor A Streltsov; Tanya le Roex; David Kuter; Katherine Alliso ..., Dalton Transactions, 2015

The quinoline methanol antimalarial drug mefloquine is a structural analogue of the Cinchona alkaloids, quinine and quinidine. We have elucidated the single crystal X-ray diffraction structure of the complexes formed between racemic erythro mefloquine and ferriprotoporphyrin IX (Fe(III)PPIX) and ...

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Aluminum and its effect in the equilibrium between folded/unfolded conformation of NADH

30-Aug-2015 | Author(s): Elena Formoso, Jon I. Mujika, Slawomir J. Grabowski, Xabier Lopez, Journal of Inorganic Biochemistry, 2015

Publication date: Available online 29 August 2015 Source:Journal of Inorganic Biochemistry Author(s): Elena Formoso, Jon I. Mujika, Slawomir J. Grabowski, Xabier Lopez Nicotinamide adenine dinucleotide (NADH) is one of the most abundant cofactor employed by proteins and enzymes. The ...

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Effective regeneration of an adsorbent for the removal of organic contaminants developed based on UV radiation and toxicity evaluation

30-Aug-2015 | Author(s): Soonjae Lee, Jae-Sang Lee, Mi-Kyung Song, Jae-Chun Ryu, Byungryul An, Chang-Gu Lee, Chanhyuk ..., Reactive and Functional Polymers, 2015

Publication date: Available online 25 August 2015 Source:Reactive and Functional Polymers Author(s): Soonjae Lee, Jae-Sang Lee, Mi-Kyung Song, Jae-Chun Ryu, Byungryul An, Chang-Gu Lee, Chanhyuk Park, Sang-Hyup Lee, Jae-Woo Choi Composites of powdered activated carbon ...

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Simulation of the digestive process in the evaluation of radionuclide availability in pharmaceutical clays for internal use

30-Aug-2015 | Author(s): Donatella Desideri, Maria Assunta Meli, Carla Roselli, Laura Feduzi, Microchemical Journal, 2015

Publication date: January 2016 Source:Microchemical Journal, Volume 124 Author(s): Donatella Desideri, Maria Assunta Meli, Carla Roselli, Laura Feduzi The occurrence and mobility of natural radioactive elements such as polonium, uranium and thorium isotopes in six pharmaceutical ...

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Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts

30-Aug-2015 | Author(s): Thibaut Stoll, Carmen E. Castillo, Megumi Kayanuma, Martina Sandroni, Chantal Daniel, Fabrice ..., Coordination Chemistry Reviews, 2015

Publication date: 1 December 2015 Source:Coordination Chemistry Reviews, Volumes 304–305 Author(s): Thibaut Stoll, Carmen E. Castillo, Megumi Kayanuma, Martina Sandroni, Chantal Daniel, Fabrice Odobel, Jérôme Fortage, Marie-Noëlle Collomb Solar driven water-splitting into ...

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