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29,137 Newest Publications about the topic solution

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Preorganization of the catalytic Zn2+-binding site in the HNH nuclease motif – a solution study

19-Apr-2015 | Author(s): Eszter Németh , Milan Kožíšek , Gabriella K. Schilli , Béla Gyurcsik, Journal of Inorganic Biochemistry, 2015

Publication date: Available online 9 April 2015 Source:Journal of Inorganic Biochemistry Author(s): Eszter Németh , Milan Kožíšek , Gabriella K. Schilli , Béla Gyurcsik The structure of the active site in a metalloenzyme can be a key determinant of its metal ion binding affinity and ...


Cation-Exchange Porosity Tuning in a Dynamic 4d–4f–3d Framework for NiII Ion-Selective Luminescent Probe

17-Apr-2015 | Ying Wang; Xiu-Guang Wang; Bin Yuan; Cheng-Yuan Shao; Yuan-Yuan Chen; Bing-Bing Zhou; Ming-Shu Li; Xiao-Mai An; Peng ..., Inorganic Chemistry, 2015

A heterometallic complex {[Yb2(L)6Cd2][Cd(H2O)6]·6H2O}n (Yb–Cd) (H2L = oxidiacetic acid) was synthesized under hydrothermal conditions. In Yb–Cd, each L chelates to one Yb3+ center and bonds to two Cd2+ ions in an anti-anti configuration. Yb and Cd atoms are arrayed alternatively and connected by ...


Mechanism of Protection of Catalysts Supported in Redox Hydrogel Films

17-Apr-2015 | Vincent Fourmond; Stefanie Stapf; Huaiguang Li; Darren Buesen; James Birrell; Olaf Rüdiger; Wolfgang Lubitz; Wolfgan ..., Journal of the American Chemical Society, 2015

The use of synthetic inorganic complexes as supported catalysts is a key route in energy production and in industrial synthesis. However, their intrinsic oxygen sensitivity is sometimes an issue. Some of us have recently demonstrated that hydrogenases, the fragile but very efficient biological ...


Diverse application platform for hard X‐ray diffraction in SACLA (DAPHNIS): application to serial protein crystallography using an X‐ray free‐electron laser

16-Apr-2015 | Kensuke Tono, Eriko Nango, Michihiro Sugahara, Changyong Song, Jaehyun Park, Tomoyuki Tanaka, Rie Tanaka, Yasumasa J ..., Journal of Synchrotron Radiation, 2015

An experimental system for serial femtosecond crystallography using an X‐ray free‐electron laser (XFEL) has been developed. It basically consists of a sample chamber, fluid injectors and a two‐dimensional detector. The chamber and the injectors are operated under helium atmosphere at 1 atm. The ...


One-step synthesis of Ag–reduced graphene oxide–multiwalled carbon nanotubes for enhanced antibacterial activities

16-Apr-2015 | Leila Shahriary; Roopa Nair; Sushma Sabharwal; Anjali A. Athawale, New Journal of Chemistry, 2015

The present study reports a rapid one-step preparation of Ag nanoparticles decorated reduced graphene oxide–multiwalled carbon nanotube hybrids (Ag–rGO–MWCNTs) by heating a mixture of graphene oxide (GO), acid functionalized multiwalled carbon nanotubes (f-MWCNTs), and an aqueous solution of ...


Predicting accurate absolute binding energies in aqueous solution: thermodynamic considerations for electronic structure methods

16-Apr-2015 | Jan H. Jensen, Physical Chemistry Chemical Physics, 2015

Recent predictions of absolute binding free energies of host-guest complexes in aqueous solution using electronic structure theory have been encouraging for some systems, while other systems remain problematic. In this paper I summarize some of the many factors that could easily contribute 1-3 ...


Light‐Emitting Paper

15-Apr-2015 | Amir Asadpoordarvish, Andreas Sandström, Christian Larsen, Roger Bollström, Martti Toivakka, Ronald Österbacka, Ludv ..., Advanced Functional Materials, 2015

A solution‐based fabrication of flexible and light‐weight light‐emitting devices on paper substrates is reported. Two different types of paper substrates are coated with a surface‐emitting light‐emitting electrochemical cell (LEC) device: a multilayer‐coated specialty paper with an intermediate ...


Kinetics and equilibria of the chromatographic separation of maltose and trehalose

15-Apr-2015 | Dengjun He, Jiachun Zhou, Quanming Xia, Lihua Jiang, Yongjun Qiu, Liming Zhao, Journal of Separation Science, 2015

Trehalose, a non‐reducing disaccharide, has been extensively applied to food, cosmetics and pharmaceutical goods. The resultant solution of trehalose prepared by enzymatic methods includes high amounts of maltose. However, it is quite difficult to separate maltose and trehalose on an industrial ...


Structure determination of bound nitrogen-based adducts with copper(II) acetylacetonato; an EPR, ENDOR and DFT study

15-Apr-2015 | Emma Carter; Katherine M. Sharples; James A. Platts; Damien M. Murphy, Physical Chemistry Chemical Physics, 2015

The adducts of bis(acetylacetonato)–copper(ii), [Cu(acac)2], formed with a range of nitrogen heterocycles including pyridine (2), methylpyridines (3,4,5), amino-methylpyridines (6,7) and diazines (8,9,10) were investigated in frozen solution using X-band EPR and 1H ENDOR spectroscopy. The small ...


Cyano- and chloro-substituted coronene diimides as solution-processable electron-transporting semiconductors

15-Apr-2015 | Chenhao Zhang; Ke Shi; Kang Cai; Jiajun Xie; Ting Lei; Qifan Yan; Jie-Yu Wang; Jian Pei; Dahui Zhao, Chemical Communication, 2015

3,4,9,10-Tetracyano- and tetrachlorocoronene-1,6,7,12-tetracarboxy diimides with low LUMO levels at −3.9 to −4.2 eV are developed. These molecules manifest potent n-type semiconductive capability in solution-processed field-effect transistors, with electron mobilities of up to 0.16 cm2 V−1 s−1 ...


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