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Highly stable, luminescent core-shell type methylammonium-octylammonium lead bromide layered perovskite nanoparticles

04-May-2016 | Saikat Bhaumik; Sjoerd Veldhuis; Yan Fong Ng; Mingjie Li; Subas Kumar Muduli; Tze Chien Sum; Bahulayan Damodaran; Su ..., Chemical Communication, 2016

A new protocol for the synthesis of highly stable (over 2 months in ambient) solution-processed core-shell type structure of mixed methylammonium-octylammonium lead bromide perovskite nanoparticles (5-12 nm), with spherical shape, color tunability in the blue to green spectral region (438-521 nm) ...


Catalyst-Free Aldol Reaction in a Water Medium

04-May-2016 | Yao, Weirong; Cui, Yanli; Wang, Peipei; Mao, Yangyi, Letters in Organic Chemistry, 2016

Abstract: Background: With growing interest in developing environmentally friendly reactions and atom-economic processes in recent years, the utilization of water as a solvent has attracted a great deal of attention. This is not only for its low-cost, safe and environmentally benign nature, ...


New (green) methodology for efficient hydrazine cleavage

04-May-2016 | Lenka Kubovicova; Kristýna Bürglová; Jan Hlavac, Organic & Biomolecular Chemistry, 2016

An efficient method for removal of hydrazine group from (hetero)aromatic substrates has been developed. It can be realized both on solid support and in solution by synthesis employing low concentrated solution of trimethylsilanolate in tetrahydrofuran or N,N-dimethylformamide. For water-soluble ...


A New Insight into the Isotropic - Nematic Phase Transition in Lyotropic Solutions of Semiflexible Polymers: Density-Functional Theory Tested by Molecular Dynamics

04-May-2016 | Sergei Egorov; Andrey Ivanov Milchev; Peter Virnau; Kurt Binder, Soft Matter, 2016

Semiflexible polymers in solution are studied for a wide range of both contour length $L$ and persistence length $\ell_p$ as function of monomer concentration under good solvent conditions. Both density-functional theory (DFT) and Molecular Dynamics (MD) simulation methods are used, and very good ...


Amperometric detection of cholesterol using cobalt (II) chloride as an electrocatalyst in aprotic media

02-May-2016 | Author(s): Alisa N. Kozitsina, Andrei V. Okhokhonin, Anatoly I. Matern, Journal of Electroanalytical Chemistry, 2016

Publication date: 1 July 2016 Source:Journal of Electroanalytical Chemistry, Volume 772 Author(s): Alisa N. Kozitsina, Andrei V. Okhokhonin, Anatoly I. Matern The determination of cholesterol concentration in the blood is an important characteristic of the state of health. Modern ...


A study on corrosion and deactivation mechanism of Pt/Nb anodes in sodium chlorate containing solution using EIS

02-May-2016 | Author(s): M. Noori, K. Jafarzadeh, A. Kashi, G.H. Shirafkan, Journal of Electroanalytical Chemistry, 2016

Publication date: 1 July 2016 Source:Journal of Electroanalytical Chemistry, Volume 772 Author(s): M. Noori, K. Jafarzadeh, A. Kashi, G.H. Shirafkan Due to their high price, the corrosion resistance and lifetime of Pt/Nb anodes, which are usually manufactured through an ...


Coordination Engineering toward High Performance Organic–inorganic Hybrid Perovskites

01-May-2016 | Author(s): Xin Guo, Clemens Burda, Coordination Chemistry Reviews, 2016

Publication date: Available online 30 April 2016 Source:Coordination Chemistry Reviews Author(s): Xin Guo, Clemens Burda In this review we present how engineering of the coordination sphere of group IV transition metals allows to tune the structure and properties of organic-inorganic ...


Evaluation of an alternative chlorine production process for energy saving toward sustainability

30-Apr-2016 | Ali Ghannadzadeh, Majid Sadeqzadeh, Environmental Progress, 2016

Exergetic‐based solutions are proposed in this work to reduce the energy footprint of an alternative chlorine production process. By presenting exergy analysis results in the form of visualized exergetic process flowsheets using a solution panel, this study does not only find the ...


Thin film composite forward osmosis membranes with poly(2‐hydroxyethyl methacrylate) grafted nano‐TiO2 as additive in substrate

30-Apr-2016 | Wu Kuang, Zhongnan Liu, Guodong Kang, Dandan Liu, Meiqing Zhou, Yiming Cao, Journal of Applied Polymer Science, 2016

ABSTRACT The poly(2‐hydroxyethyl methacrylate) grafted titanium dioxide nanoparticles were synthesized and added to the substrate of flat‐sheet thin film composite forward osmosis (TFC‐FO) membranes. The hydrophilicity of substrate was improved, which was advantageous to enhance the water flux ...


Surface Nanostructures of Au‐Thiolated Cyclodextrin‐Fe Species: Gas and Liquid Phase Preparation

29-Apr-2016 | Sona Halaszova, Monika Jerigova, Dusan Lorenc, Michal Prochazka, Dusan Velic, ChemPhysChem, 2016

Supramolecular surface nanostructures have application potential as functional devices. The complex preparation and formation between thiolated cyclodextrin chemisorbed on Au surface (Au‐S‐CD) and deposited Fe species are studied by using secondary ion mass spectrometry. The Fe species are ...


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