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Temperature Affects Human Sweet Taste via At Least Two Mechanisms

01-Jul-2015 | Barry G. Green; Danielle Nachtigal, Chemical Senses, 2015

The reported effects of temperature on sweet taste in humans have generally been small and inconsistent. Here, we describe 3 experiments that follow up a recent finding that cooling from 37 to 21 °C does not reduce the initial sweetness of sucrose but increases sweet taste adaptation. In ...

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Effects of Ce on inclusions and corrosion resistance of low‐nickel austenite stainless steel

26-Jun-2015 | G.‐J. Cai, C.‐S. Li, Materials and Corrosion, 2015

Effects of Ce on the corrosion resistance of low‐nickel austenite stainless steel containing Ce from 0.005 to 0.022 wt% were investigated in 3.5 wt% NaCl solution, 5 wt% H2SO4 solution, 1 mol/L NaHCO3 and 0.5 mol/L Na2CO3 solution. The results demonstrate that addition of Ce to low‐nickel ...

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Corrosion behaviour of Ti–10Nb–10Zr–5Ta alloys in artificial saliva solution with fluoride content

26-Jun-2015 | M. Braic, A. Vladescu, V. Braic, C.M. Cotrut, D. Stanciu, Materials and Corrosion, 2015

Ti‐10Nb‐5Zr‐5Ta alloy was produced in levitation melting furnace with cold crucible in argon protective atmosphere. This alloy was chosen as a possible candidate to replace the Ti6Al4V alloy in dentistry. To prove this, the corrosion behaviour of the Ti‐10Nb‐5Zr‐5Ta alloy in NaF enriched saliva ...

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Novel concepts on the growth of corrosion fatigue small and short cracks

26-Jun-2015 | M. Lukaszewicz, S. Zhou, A. Turnbull, Materials and Corrosion, 2015

Corrosion fatigue small, short and long crack growth rates have been determined for a 12Cr steam turbine steel in aerated 300 ppb Cl‐ + 300 ppb SO42‐ solution and in air at 90 °C. The crack growth rate for short and long cracks was monitored by direct current potential drop (DCPD) and for the ...

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Photochemical reactions of halogenated aromatic 1,3-diketones in solution studied by steady state, one- and two-color laser flash photolyses

26-Jun-2015 | Minoru Yamaji; Yurie Suwa; Rieko Shimokawa; Cecilia Paris; Miguel Miranda, Photochemical & Photobiological Sciences, 2015

Photochemical processes of 4-tert-butyl-4’-methoxydibenzoylmethane (avobenzone, AB), 4-phenylbenzoylbenzoyl-, 4-phenylbenzoyl-2'-furanyl- and 4-phenylbenzoyl-2'-thenoylmethanes (PB@Ph, PB@F and PB@T, respectively) substituted with Br and Cl at the C2 position were studied by stationary and laser ...

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MOF crystal growth: UV resonance Raman investigation of metal-ligand binding in solution and accelerated crystal growth methods

26-Jun-2015 | Thomas Petersen; Gurusamy Balakrishnan; Colin Weeks, Dalton Transactions, 2015

Determining the mechanism of metal-organic framework (MOF) crystal growth is important for the development of more efficient and reliable synthetic methods. Resonance Raman spectroscopy has been used for the first time to detect interactions in solution between metal ions and bridging ligands as ...

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Like-charge ion pairs of hydronium and hydroxide in aqueous solution?

26-Jun-2015 | Manik Kumer Ghosh; Tae Hoon Choi; Cheol Ho Choi, Physical Chemistry Chemical Physics, 2015

The like-charge ion pairings of hydronium and hydroxide were investigated using both ab initio cluster calculations and QM/MM-MD aqueous simulations. While only a two-water-bridged H3O+(H2O)2H3O+ is found in hydronium cluster calculations, three clusters of HO−(H2O)2HO−, HO−(H2O)3HO− and ...

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Towards Single Biomolecule Imaging via Optical Nanoscale Magnetic Resonance Imaging

25-Jun-2015 | Alberto Boretti, Lorenzo Rosa, Stefania Castelletto, Small, 2015

Nuclear magnetic resonance (NMR) spectroscopy is a physical marvel in which electromagnetic radiation is charged and discharged by nuclei in a magnetic field. In conventional NMR, the specific nuclei resonance frequency depends on the strength of the magnetic field and the magnetic properties of ...

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Corrosion Protection Efficiency of Bilayer Porphyrin‐Polyaniline Film Deposited on Carbon Steel

25-Jun-2015 | Iuliana Popa, Eugenia Fagadar‐Cosma, Bogdan‐Ovidiu Taranu, Mihaela Birdeanu, Gheorghe Fagadar‐Cosma, Ioan Taranu, Macromolecular Symposia, 2015

Summary Polyaniline (PANI) based composites and multilayers as well as porphyrin derivatives have been previously reported as efficient anti‐corrosion coatings. In our studies, 5,10,15,20‐tetra(4‐methylphenyl)‐21H,23H‐porphyrin (TMP) was adsorbed on carbon steel surface before PANI ...

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ChemInform Abstract: FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster.

25-Jun-2015 | Szymon Chorazy, Robert Podgajny, Koji Nakabayashi, Jan Stanek, Michal Rams, Barbara Sieklucka, Shin‐ichi Ohkoshi, ChemInform, 2015

Abstract Single crystals of title compound (IV) are grown by self‐assembly in a MeOH solution.

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