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Paddlewheel‐Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self‐Assembly and Disassembly Transformation Properties

25-Apr-2016 | Yusuke Kataoka, Natsumi Yano, Takashi Shimodaira, Yin‐Nan Yan, Mikio Yamasaki, Hidekazu Tanaka, Kohji Omata, Tatsuya ..., European Journal of Inorganic Chemistry, 2016

Abstract An extended one‐dimensional chain‐type coordination polymer, [Rh2(piv)4(tpy)]n (1; piv = pivalate, tpy = 2,2′:6′,2″‐terpyridine), has been synthesized and characterized by single‐crystal and powder X‐ray diffraction analyses, elemental analysis, IR spectrosopy, thermogravimetric ...

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Elimination of radiocontrast agent Diatrizoic acid from water by electrochemical advanced oxidation: Kinetics study, mechanism and mineralization pathway

25-Apr-2016 | Author(s): Elvira Bocos, Nihal Oturan, M. Ángeles Sanromán, Mehmet A. Oturan, Journal of Electroanalytical Chemistry, 2016

Publication date: 1 July 2016 Source:Journal of Electroanalytical Chemistry, Volume 772 Author(s): Elvira Bocos, Nihal Oturan, M. Ángeles Sanromán, Mehmet A. Oturan Diatrizoic acid (DIA) is an iodinated X-ray contrast media commonly used in hospitals. It is persistent and ...

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Dynamic Measurements of the Position, Orientation, and DNA Content of Individual Unlabeled Bacteriophages

22-Apr-2016 | Aaron M. Goldfain; Rees F. Garmann; Yan Jin; Yoav Lahini; Vinothan N. Manoharan, Journal of Physical Chemistry B, 2016

A complete understanding of the cellular pathways involved in viral infections will ultimately require a diverse arsenal of experimental techniques, including methods for tracking individual viruses and their interactions with the host. Here we demonstrate the use of holographic microscopy to ...

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Synthesis, characterization, and photo‐responsive properties of Y‐shaped amphiphilic azo triblock copolymer

21-Apr-2016 | Renbo Wei, Jinyi Ma, Hongxing Zhang, Yaning He, Journal of Applied Polymer Science, 2016

ABSTRACT In this study, we report the synthesis, characterization, and photo‐responsive properties of a new Y‐shaped amphiphilic azo triblock copolymer composed of two isotropic polyethylene glycol (PEG) blocks and an azobenzene liquid crystalline block. The azo block, with two ending groups ...

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Acyliridium(III) Complexes with PCN Terdentate Ligands Including Imino‐ or Iminium‐Acyl Moieties or Formation of Hydrido from Hydroxyl (Eur. J. Inorg. Chem. 12/2016)

21-Apr-2016 | Itziar Zumeta, Claudio Mendicute‐Fierro, Antonio Rodríguez‐Diéguez, José M. Seco, María A. Garralda, European Journal of Inorganic Chemistry, 2016

The cover picture shows an anionic dihydridoiridium species formed in methanol from a dihydridoirida‐β‐diketone in the presence of KOH and hydrogen release from the dihydrido species upon addition of 2‐aminoalkylpyridines to the solution. Hydrogen is transferred from hydroxyl in the solvent to ...

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Acyliridium(III) Complexes with PCN Terdentate Ligands Including Imino‐ or Iminium‐Acyl Moieties or Formation of Hydrido from Hydroxyl

21-Apr-2016 | Itziar Zumeta, Claudio Mendicute‐Fierro, Antonio Rodríguez‐Diéguez, José M. Seco, María A. Garralda, European Journal of Inorganic Chemistry, 2016

Abstract Invited for the cover of this issue is the group of María A. Garralda at Universidad del País Vasco, San Sebastián, Spain. The cover image shows an anionic dihydridoiridium species formed in methanol from a dihydridoirida‐β‐diketone and hydrogen release from the dihydrido species upon ...

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Synergistic effect of cellulose nanowhiskers reinforcement and dicarboxylic acids crosslinking towards polyvinyl alcohol properties

21-Apr-2016 | Amit Kumar Sonker, Naveen Tiwari, Rajaram Krishna Nagarale, Vivek Verma, Journal of Polymer Science Part A: Polymer Chemistry, 2016

ABSTRACT In the presented work, a significant increase in the tensile strength of the PVA composite material is reported. The obtained best value of 122 MPa and 14.6% swelling shows the excellent synergistic effect of both crosslinker and reinforcement material. The composite films were ...

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Effect of processing methods on electrical percolation and electromagnetic shielding of PC/MWCNTs nanocomposites

21-Apr-2016 | S. M. Seyedi Ghezghapan, A. Javadi, Polymer Composites, 2016

Nanocomposites of polycarbonate (PC)/multiwalled carbon nanotubes (MWCNTs) containing 0.5–3wt% of MWCNTs were prepared via two methods of melt mixing and solution mixing. The effect of CNT content and processing methods on electrical and electromagnetic properties of nanocomposite samples were ...

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Characteristics and fouling propensity of polysaccharides in the presence of different monovalent ions

20-Apr-2016 | Xiang He, Fangang Meng, Anli Lin, Jiapeng Li, Chuyang Y. Tang, AIChE Journal, 2016

Abstract In this study the fouling behavior of alginate in the presence of monovalent ions (i.e., NaCl, KCl, CsCl, NaBr and NaI) was explored. Results showed that alginate tended to be less negatively charged in the presence of monovalent ions. The cation ion identity had a more substantial ...

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Studying the Conformation of a Silaffin-Derived Pentalysine Peptide Embedded in Bioinspired Silica using Solution and Dynamic Nuclear Polarization Magic-Angle Spinning NMR

20-Apr-2016 | Yasmin Geiger; Hugo E. Gottlieb; Ümit Akbey; Hartmut Oschkinat; Gil Goobes, Journal of the American Chemical Society, 2016

Smart materials are created in nature at interfaces between biomolecules and solid materials. The ability to probe the structure of functional peptides that engineer biogenic materials at this heterogeneous setting can be facilitated tremendously by use of DNP-enhanced solid-state NMR ...

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