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COOPERATIVE HYDROGEN-BONDING OF THE ADENINE-THYMINE PAIR AS A STRATEGY FOR LOWERING THE LIMIT OF DETECTION OF THYMINE BY SURFACE-ENHANCED RAMAN SPECTROSCOPY

26-Apr-2016 | Mónica Benicia Mamián-López; Paola Corio; Marcia Temperini, Analyst, 2016

The formation of cooperative hydrogen bonds between the thymine-adenine pair was used to indirectly determine thymine in aqueous solution by Surface-enhanced Raman Spectroscopy (SERS), therefore improving the limit of detection (LOD) values up to two orders of magnitude. The concentration of ...

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Tunable Luminescent Activity of Metallosupramolecular Cd (II) Complexes Containing Dimethylterpyridine Ligand

25-Apr-2016 | Author(s): Adam Gorczyński, Damian Marcinkowski, Dawid Pakulski, Maciej Kubicki, Jack M. Harrowfield, Artu ..., Arabian Journal of Chemistry, 2016

Publication date: Available online 19 April 2016 Source:Arabian Journal of Chemistry Author(s): Adam Gorczyński, Damian Marcinkowski, Dawid Pakulski, Maciej Kubicki, Jack M. Harrowfield, Artur R. Stefankiewicz, Zbigniew Hnatejko, Violetta Patroniak Four complexes of ...

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Cefixime detection by a novel electrochemical sensor based on glassy carbon electrode modified with surface imprinted polymer/multiwall carbon nanotubes

25-Apr-2016 | Author(s): N. Karimian, M.B. Gholivand, Gh. Malekzadeh, Journal of Electroanalytical Chemistry, 2016

Publication date: 15 June 2016 Source:Journal of Electroanalytical Chemistry, Volume 771 Author(s): N. Karimian, M.B. Gholivand, Gh. Malekzadeh A new selective voltammetric sensor based on molecularly imprinted polymer immobilized on multiwall carbon nanotube surface was reported for ...

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Effect of alkyl chain length of tri-n-alkyl phosphate extractants on the electrochemical behaviour of U(VI) in ionic liquid medium

25-Apr-2016 | Author(s): R. Rama, Alok Rout, K.A. Venkatesan, M.P. Antony, Journal of Electroanalytical Chemistry, 2016

Publication date: 15 June 2016 Source:Journal of Electroanalytical Chemistry, Volume 771 Author(s): R. Rama, Alok Rout, K.A. Venkatesan, M.P. Antony Higher homologs of trialkyl phosphates have been proposed for the separation of U(VI) from fast reactor dissolver solution by liquid – ...

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Gamma-irradiation synthesis of iron oxide nanoparticles in the presence of PEO, PVP or CTAB

24-Apr-2016 | Author(s): Tanja Jurkin, Marijan Gotić, Goran Štefanić, Irina Pucić, Radiation Physics and Chemistry, 2016

Publication date: July 2016 Source:Radiation Physics and Chemistry, Volume 124 Author(s): Tanja Jurkin, Marijan Gotić, Goran Štefanić, Irina Pucić Black hydrogels were synthesized using γ-irradiation of poly(ethylene oxide) (PEO)/iron(III) chloride precursor solutions. The magnetic ...

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How preparation and modification parameters affect PB‐PEO polymersome properties in aqueous solution

23-Apr-2016 | Joachim Habel, Anayo Ogbonna, Nanna Larsen, Simon Krabbe, Kristoffer Almdal, Claus Hélix‐Nielsen, Journal of Polymer Science Part B: Polymer Physics, 2016

ABSTRACT The effect of formation and modification methods on the physical properties of polymersomes is critical for their use in applications relying on their ability to mimic functional properties of biological membranes. In this study, we compared two formation methods for polymersomes made ...

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Controlled Electrochemical Polymerization Strategies for Electroactive Polyaniline Thin Films

22-Apr-2016 | Rohini R. Kharade, Pallavi B. Patil, Kishor V. Khot, Vishvnath B. Ghanwat, Vijay V. Kondalkar, Chaitali S. Bagade, N ..., Macromolecular Symposia, 2016

Summary Polyaniline (PANI) thin films were successfully deposited using controlled electrodeposition (ED) technique from a mixed solution of 0.1M aniline and 0.5M H2SO4 on ITO coated substrate. The effect of different deposition cycles 10, 25, 50, 75, 100 on thickness, optical and ...

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Long-Range Vibrational Dynamics Are Directed by Watson–Crick Base Pairing in Duplex DNA

22-Apr-2016 | Gordon Hithell; Daniel J. Shaw; Paul M. Donaldson; Gregory M. Greetham; Michael Towrie; Glenn A. Burley; Anthony W. ..., Journal of Physical Chemistry B, 2016

Ultrafast two-dimensional infrared (2D-IR) spectroscopy of a 15-mer A–T DNA duplex in solution has revealed structure-dependent vibrational coupling and energy transfer processes linking bases with the sugar–phosphate backbone. Duplex melting induces significant changes in the positions of ...

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Acyliridium(III) Complexes with PCN Terdentate Ligands Including Imino‐ or Iminium‐Acyl Moieties or Formation of Hydrido from Hydroxyl (Eur. J. Inorg. Chem. 12/2016)

21-Apr-2016 | Itziar Zumeta, Claudio Mendicute‐Fierro, Antonio Rodríguez‐Diéguez, José M. Seco, María A. Garralda, European Journal of Inorganic Chemistry, 2016

The cover picture shows an anionic dihydridoiridium species formed in methanol from a dihydridoirida‐β‐diketone in the presence of KOH and hydrogen release from the dihydrido species upon addition of 2‐aminoalkylpyridines to the solution. Hydrogen is transferred from hydroxyl in the solvent to ...

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Acyliridium(III) Complexes with PCN Terdentate Ligands Including Imino‐ or Iminium‐Acyl Moieties or Formation of Hydrido from Hydroxyl

21-Apr-2016 | Itziar Zumeta, Claudio Mendicute‐Fierro, Antonio Rodríguez‐Diéguez, José M. Seco, María A. Garralda, European Journal of Inorganic Chemistry, 2016

Abstract Invited for the cover of this issue is the group of María A. Garralda at Universidad del País Vasco, San Sebastián, Spain. The cover image shows an anionic dihydridoiridium species formed in methanol from a dihydridoirida‐β‐diketone and hydrogen release from the dihydrido species upon ...

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