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Organogold oligomers: exploiting iClick and aurophilic cluster formation to prepare solution stable Au4 repeating units.

27-May-2015 | Xi Yang; Shanshan Wang; Ion Ghiviriga; Khalil A Abboud; Adam Steven Veige, Dalton Transactions, 2015

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Generation of chlorine by-products in simulated wash water

24-May-2015 | Author(s): Cangliang Shen , Pauline Norris , Olivia Williams , Stephanie Hagan , KaWang Li, Food Chemistry, 2015

Publication date: 1 January 2016 Source:Food Chemistry, Volume 190 Author(s): Cangliang Shen , Pauline Norris , Olivia Williams , Stephanie Hagan , KaWang Li Free chlorine (FC) reacting with organic matter in wash water promotes the formation of chlorine by-products. This study aims to ...


Exploiting Conjugated Polyelectrolyte Photophysics toward Monitoring Real-Time Lipid Membrane-Surface Interaction Dynamics at the Single-Particle Level

23-May-2015 | Christina F. Calver; Hsiao-Wei Liu; Gonzalo Cosa, Langmuir, 2015

Herein we report the real-time observation of the interaction dynamics between cationic liposomes flowing in solution and a surface-immobilized charged scaffolding formed by the deposition of conjugated polyanion poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene (MPS-PPV) onto ...


Inclusion of Two Push–Pull N-Methylpyridinium Salts in Anionic Surfactant Solutions: A Comprehensive Photophysical Investigation

22-May-2015 | Alessio Cesaretti; Benedetta Carlotti; Giuseppe Consiglio; Tiziana Del Giacco; Anna Spalletti; Fausto Elisei, Journal of Physical Chemistry B, 2015

Two N-methylpyridinium salts with push–pull properties have been investigated in the aqueous solution of anionic micelles of sodium dodecyl sulfate (SDS) and potassium p-(octyloxy)benzenesulfonate (pOoBSK) surfactants. These molecules are known to be extremely sensitive to the local environment, ...


Tris-[8]annulenyl Isocyanurate Trianion Triradical and Hexa-anion from the Alkali Metal Reduction of [8]Annulenyl Isocyanate

22-May-2015 | Steven J. Peters; Joseph R. Klen, The Journal of Organic Chemistry, 2015

The solution phase alkali metal reduction of [8]annulenyl isocyanate (C8H7NCO) yields an EPR spectrum, which reveals electron couplings to seven protons and only one nitrogen. Although this strongly suggested that the C8H7NCO anion radical was generated, experiments on the oxidized product reveal ...


Effect of Induced Self-Organization in Mixtures of Amphiphilic Macromolecules with Different Stiffness

22-May-2015 | Mikhail K. Glagolev; Valentina V. Vasilevskaya; Alexei R. Khokhlov, Macromolecules, 2015

Effect of induced self-organization and liquid-crystal ordering of disordered globules of flexible amphiphilic macromolecules was observed in 1:1 mixtures of flexible and stiff helical macromolecules of similar composition. Mixtures of fully flexible macromolecules and helical macromolecules with ...


Influence of Backbone Fluorination in Regioregular Poly(3-alkyl-4-fluoro)thiophenes

21-May-2015 | Zhuping Fei; Pierre Boufflet; Sebastian Wood; Jessica Wade; John Moriarty; Eliot Gann; Erin L. Ratcliff; Christopher ..., Journal of the American Chemical Society, 2015

We report two strategies toward the synthesis of 3-alkyl-4-fluorothiophenes containing straight (hexyl and octyl) and branched (2-ethylhexyl) alkyl groups. We demonstrate that treatment of the dibrominated monomer with 1 equiv of alkyl Grignard reagent leads to the formation of a single ...


Heterogeneous Degradation of Organic Pollutants by Persulfate Activated by CuO-Fe3O4: Mechanism, Stability, and Effects of pH and Bicarbonate Ions

21-May-2015 | Yang Lei; Chuh-Shun Chen; Yao-Jen Tu; Yao-Hui Huang; Hui Zhang, Environmental Science & Technology, 2015

Magnetic CuO-Fe3O4 composite was fabricated by a simple hydrothermal method and characterized as a heterogeneous catalyst for phenol degradation. The effects of pH and bicarbonate ions on catalytic activity were extensively evaluated in view of the practical applications. The results indicated ...


Effective Nitrogen Removal and Recovery from Dewatered Sewage Sludge Using a Novel Integrated System of Accelerated Hydrothermal Deamination and Air Stripping

21-May-2015 | Chao He; Ke Wang; Yanhui Yang; Prince Nana Amaniampong; Jing-Yuan Wang, Environmental Science & Technology, 2015

In order to reduce considerable emissions of N-containing pollutants from combustion of sewage sludge derived solid fuel, an integrated system of hydrothermal deamination and air stripping was developed to effectively remove and recover nitrogen from dewatered sewage sludge (DSS). Three ...


Self-Assembly of [3]Catenanes and a [4]Molecular Necklace Based on a Cryptand/Paraquat Recognition Motif

21-May-2015 | Yang Ye; Shu-Ping Wang; Bin Zhu; Timothy R. Cook; Jing Wu; Shijun Li; Peter J. Stang, Organic Letters, 2015

Hierarchical self-assembly centered on metallacyclic scaffolds greatly facilitates the construction of mechanically interlocked structures. The formation of two [3]catenanes and one [4]molecular necklace is presented by utilizing the orthogonality of coordination-driven self-assembly and crown ...


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