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Synthesis and application of 1,4-bis(triphenyl phosphonium)butane peroxodisulfate for conversion of alkyl benzenes to their corresponding acylbenzenes

04-Jan-2015 | Author(s): Rashid Badri , Maryam Adlu , Mohammad Kazem Mohammadi, Arabian Journal of Chemistry, 2015

Publication date: January 2015 Source:Arabian Journal of Chemistry, Volume 8, Issue 1 Author(s): Rashid Badri , Maryam Adlu , Mohammad Kazem Mohammadi 1,4-Bis(triphenyl phosphonium)butane peroxodisulfate (BTPPBPDS) was synthesized by treating 1,4-bis(triphenyl phosphonium)butane ...

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Micellar effect on the kinetics of oxidation of methyl blue by Ce(IV) in sulfuric acid medium

04-Jan-2015 | Author(s): Mohammed Hassan , Mohammed D. AlAhmadi , Majid Mosaid, Arabian Journal of Chemistry, 2015

Publication date: January 2015 Source:Arabian Journal of Chemistry, Volume 8, Issue 1 Author(s): Mohammed Hassan , Mohammed D. AlAhmadi , Majid Mosaid The kinetics of oxidation of methyl blue (MB) by Ce(IV) in aqueous and surfactant media has been carried out to explore the micellar ...

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Extending the photoelectrocatalytic detection range of KHP by eliminating self-inhibition at TiO2 nanoparticle electrodes

04-Jan-2015 | Author(s): Yanhe Han , Qi Cheng , Jiaqing Chen , Cuihong Zhou , Haimin Zhang , Shanqing Zhang , Huijun Zhao, Journal of Electroanalytical Chemistry, 2015

Publication date: 1 February 2015 Source:Journal of Electroanalytical Chemistry, Volume 738 Author(s): Yanhe Han , Qi Cheng , Jiaqing Chen , Cuihong Zhou , Haimin Zhang , Shanqing Zhang , Huijun Zhao The photoelectrocatalytic oxidation of potassium hydrogen phthalate (KHP) at a ...

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Auto-oxidation Products of Epigallocatechin Gallate Activate TRPA1 and TRPV1 in Sensory Neurons

01-Jan-2015 | Mako Kurogi; Yasushi Kawai; Katsuhiro Nagatomo; Michihiro Tateyama; Yoshihiro Kubo; Osamu Saitoh, Chemical Senses, 2015

The sensation of astringency is elicited by catechins and their polymers in wine and tea. It has been considered that catechins in green tea are unstable and auto-oxidized to induce more astringent taste. Here, we examined how mammalian transient receptor potential V1 (TRPV1) and TRPA1, which are ...

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The relationship between oxidation and hydrolysis in the conversion of cellulose in NaVO3–H2SO4 aqueous solution with O2

30-Dec-2014 | Muge Niu; Yucui Hou; Shuhang Ren; Wenhua Wang; Qitian Zheng; Weize Wu, Green Chemistry, 2014

Conversion of cellulose, the most abundant biomass, shows a high selectivity to yield formic acid (FA), when oxidized by O2 in NaVO3–H2SO4 aqueous solution. This conversion involves various reactions including hydrolysis and oxidation. In this work, the relationships between these reactions were ...

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Poly(ionic liquid) Core Turns Hollow Silica Spheres into Amphiphilic Nanoreactor in Water

30-Dec-2014 | Yan Yang; Martina Ambrogi; Holm Kirmse; Yongjun Men; Markus Antonietti; Jiayin Yuan, Chemistry of Materials, 2014

The stressing environmental concerns push us to move traditional organic reactions toward an eco-friendly way. Replacing organic solvents by water seems to be a promising solution yet is very challenging. The main obstacle is the poor solubility of many hydrophobic substrates in water, leading to ...

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New complex bismuth oxides in the Bi2O3–NiO–Sb2O5 system and their properties

28-Dec-2014 | Author(s): A.V. Egorysheva , O.G. Ellert , Y.V. Zubavichus , O.M. Gajtko , N.N. Efimov , R.D. Svetogorov , V.Y ..., Journal of Solid State Chemistry, 2014

Publication date: May 2015 Source:Journal of Solid State Chemistry, Volume 225 Author(s): A.V. Egorysheva , O.G. Ellert , Y.V. Zubavichus , O.M. Gajtko , N.N. Efimov , R.D. Svetogorov , V.Yu. Murzin Phase equilibria in the Bi2O3–NiO–Sb2O5 system have been investigated. The isothermal ...

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Electroanalytical application of a boron-doped diamond electrode: Improving the simultaneous voltammetric determination of amlodipine and valsartan in urine and combined dosage forms

28-Dec-2014 | Author(s): Guilherme Roberto Mansano , Ana Paula Pires Eisele , Luiz Henrique Dall’Antonia , Sabrina Afonso , El ..., Journal of Electroanalytical Chemistry, 2014

Publication date: 1 February 2015 Source:Journal of Electroanalytical Chemistry, Volume 738 Author(s): Guilherme Roberto Mansano , Ana Paula Pires Eisele , Luiz Henrique Dall’Antonia , Sabrina Afonso , Elen Romão Sartori A new voltammetric method was developed for simultaneous ...

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Hiding and Recovering Electrons in a Dimetallic Endohedral Fullerene: Air-Stable Products from Radical Additions

23-Dec-2014 | Michio Yamada; Hiroki Kurihara; Mitsuaki Suzuki; Masayoshi Saito; Zdenek Slanina; Filip Uhlik; Toshihiro Aizawa; Tat ..., Journal of the American Chemical Society, 2014

Fullerenyl radicals can be generated by addition of a free radical to a fullerene surface, by nucleophilic addition followed by one-electron oxidation, or by thermal dissociation of singly bonded fullerene dimers. However, fullerenyl radicals are usually very reactive and generally cannot be ...

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Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non‐adsorbable Aromatic Halides: A Proton‐Induced Pathway

22-Dec-2014 | Wei Chang, Chunyan Sun, Xibin Pang, Hua Sheng, Yue Li, Hongwei Ji, Wenjing Song, Chuncheng Chen, Wanhong Ma, Jincai Zhao, Angewandte Chemie International Edition, 2014

Abstract An efficient redox reaction between organic substrates in solution and photoinduced h+vb/e−cb on the surface of photocatalysts requires the substrates or solvent to be adsorbed onto the surface, and is consequentially marked by a normal kinetic solvent isotope effect (KSIE≥1). ...

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