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New synthesis of phenyl-isothiocyanates C-functionalised cyclams. Bioconjugation and 64Cu phenotypic PET imaging studies of multiple myeloma with the te2a derivative

01-Oct-2015 | Zakaria Halme; Mathieu Frindel; Nathalie Camus; Pierre-Yves Orain; Marie Lacombe; Michel Cherel; Jean-Francois Gesti ..., Organic & Biomolecular Chemistry, 2015

Azamacrocyclic bifunctional chelating agents (BCAs) are essential for the development of radiopharmaceuticals in nuclear medicine and we wish to prove that their bioconjugation by a function present on a carbon atom of the macrocyclic skeleton is a solution of choice to maintain their in vivo ...


Hierarchical flower-like NiO hollow microspheres for non-enzymatic glucose sensors

27-Sep-2015 | Author(s): Zhenzhen Cui, Haoyong Yin, Qiulin Nie, Dongyu Qin, Weiwei Wu, Xiaolong He, Journal of Electroanalytical Chemistry, 2015

Publication date: 15 November 2015 Source:Journal of Electroanalytical Chemistry, Volume 757 Author(s): Zhenzhen Cui, Haoyong Yin, Qiulin Nie, Dongyu Qin, Weiwei Wu, Xiaolong He Hierarchical flower-like NiO hollow microspheres were controllably prepared by a facile hydrothermal ...


Electrochemistry of myoglobin on graphene-SnO2 nanocomposite modified electrode and its electrocatalysis

27-Sep-2015 | Author(s): Wencheng Wang, Lifeng Dong, Shixing Gong, Ying Deng, Jianhua Yu, Hongzhou Dong, Tianyou Wan ..., Arabian Journal of Chemistry, 2015

Publication date: Available online 26 September 2015 Source:Arabian Journal of Chemistry Author(s): Wencheng Wang, Lifeng Dong, Shixing Gong, Ying Deng, Jianhua Yu, Hongzhou Dong, Tianyou Wang, Wei Sun In this paper direct electrochemistry and electrocatalysis of myoglobin ...


Intrinsic Folding Proclivities in Cyclic β‐Peptide Building Blocks: Configuration and Heteroatom Effects Analyzed by Conformer‐Selective Spectroscopy and Quantum Chemistry

25-Sep-2015 | Mohammad Alauddin, Eric Gloaguen, Valérie Brenner, Benjamin Tardivel, Michel Mons, Anne Zehnacker‐Rentien, Valérie D ..., Chemistry - A European Journal, 2015

Abstract This work describes the use of conformer‐selective laser spectroscopy following supersonic expansion to probe the local folding proclivities of four‐membered ring cyclic β‐amino acid building blocks. Emphasis is placed on stereochemical effects as well as on the structural changes ...


Preparation of novel high copper ions removal membranes by embedding organosilane‐functionalized multi‐walled carbon nanotube

23-Sep-2015 | Guangyong Zeng, Yi He, Zongxue Yu, Xi Yang, Ranran Yang, Lei Zhang, Journal of Chemical Technology & Biotechnology, 2015

Abstract Background Multi‐walled carbon nanotubes (MWCNTs) have attracted considerable interests in membrane field. But they are prone to aggregate in the polymer matrix and cause the defects of membranes. Different from blending MWCNTs in the casting solution, we embedded different ratios ...


Preparation of HMWCNT/PLLA nanocomposite scaffolds for application in nerve tissue engineering and evaluation of their physical, mechanical and cellular activity properties

22-Sep-2015 | Shokoufeh Mounesi Rad, Mohammad Taghi Khorasani, Morteza Daliri Joupari, Polymers for Advanced Technologies, 2015

This study was aimed to prepare biodegradable and porous nanocomposite scaffolds with microtubular orientation structure as a model for nerve tissue engineering by thermally induced phase separation (TIPS) method using dioxane as the solvent, crystalline poly (L-lactic acid) (PLLA) and ...


Changing the Action of Iron from Stoichiometric to Electrocatalytic in the Hydrogenation of Ketones in Aqueous Acidic Media

18-Sep-2015 | Marina Gottardo, Max Easton, Viktoria Fabos, Si‐Xuan Guo, Jie Zhang, Alvise Perosa, Maurizio Selva, Alan M. Bond, An ..., ChemSusChem, 2015

Abstract Cyclohexanone, a model compound chosen to conveniently represent small oxygenates present in the aqueous phase of biomass hydrothermal upgrading streams, was hydrogenated in the presence of electrodeposited iron(0) using aqueous formic or sulfuric acid as a hydrogen donor. Under these ...


3D Woven‐Like Carbon Micropattern Decorated with Silicon Nanoparticles for Use in Lithium‐Ion Batteries

18-Sep-2015 | Da‐Young Kang, Cheolho Kim, Donghee Gueon, Gyulim Park, Jung Sub Kim, Joong Kee Lee, Jun Hyuk Moon, ChemSusChem, 2015

Abstract Carbon/silicon composite materials are a promising anode substrate for use in lithium‐ion batteries. In this study, we suggest a new architecture for a composite electrode made of a woven‐like carbon material decorated with silicon nanoparticles. The 3D woven‐like carbon (WLC) ...


Solid- and Solution-State Nuclear Magnetic Resonance Analyses of Ecuadorian Asphaltenes: Quantitative Solid-State Aromaticity Determination Supporting the “Island” Structural Model. Aliphatic Structural Information from Solution-State 1H–13C Heteronuclear Single-Quantum Coherence Experiments

18-Sep-2015 | Lawrence B. Alemany; Manjusha Verma; W. E. Billups; Scott L. Wellington; Michael Shammai, Energy & Fuels, 2015

Solid- and solution-state nuclear magnetic resonance (NMR) studies of six Ecuadorian asphaltenes have provided insight into using NMR to characterize asphaltenes. For these asphaltenes, free radicals prevent obtaining quantitatively meaningful 1H–13C cross-polarization magic angle spinning ...


Isolation of Pristine Electronics Grade Semiconducting Carbon Nanotubes by Switching the Rigidity of the Wrapping Polymer Backbone on Demand

15-Sep-2015 | Yongho Joo; Gerald J. Brady; Matthew J. Shea; M. Belén Oviedo; Catherine Kanimozhi; Samantha K. Schmitt; Bryan M. Wo ..., ACS Nano, 2015

Conjugated polymers are among the most selective carbon nanotube sorting agents discovered and enable the isolation of ultrahigh purity semiconducting singled-walled carbon nanotubes (s-SWCNTs) from heterogeneous mixtures that contain problematic metallic nanotubes. The strong selectivity though ...


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