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Platinum electrode modified with polyterthiophene doped with metallic nanoparticles, as sensitive sensor for the electroanalysis of ascorbic acid (AA)

24-May-2015 | Author(s): Naima Maouche , Belkacem Nessark , Idriss Bakas, Arabian Journal of Chemistry, 2015

Publication date: Available online 5 May 2015 Source:Arabian Journal of Chemistry Author(s): Naima Maouche , Belkacem Nessark , Idriss Bakas A novel electrochemical sensor for ascorbic acid (AA) detection based on platinum electrode modified with polyterthiophene (P3T) and doped with ...

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Water treatment by photodegradation on orthorhombic antimony sulphide powder and effect of key operational parameters using methyl orange as a model pollutant

24-May-2015 | Author(s): Muhammad Muneeb , Bushra Ismail , Tanzeela Fazal , Rafaqat Ali Khan , Asad Muhammad Khan , Muhammad ..., Arabian Journal of Chemistry, 2015

Publication date: Available online 23 May 2015 Source:Arabian Journal of Chemistry Author(s): Muhammad Muneeb , Bushra Ismail , Tanzeela Fazal , Rafaqat Ali Khan , Asad Muhammad Khan , Muhammad Bilal , Bakhtiar Muhammad , Abdur Rehman Khan Photocatalytic treatment of colored waste ...

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Recent developments in preparation of activated carbons by microwave: Study of residual errors

24-May-2015 | Author(s): Ashly Leena Prasad , T. Santhi , S. Manonmani, Arabian Journal of Chemistry, 2015

Publication date: May 2015 Source:Arabian Journal of Chemistry, Volume 8, Issue 3 Author(s): Ashly Leena Prasad , T. Santhi , S. Manonmani The application of microwave activated Acacia nilotica leaves (MVM) and chemically activated A. nilotica leaves (CVM) for the removal of crystal ...

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Synthesis and controlled release properties of β-naphthoxyacetic acid intercalated Mg–Al layered double hydroxides nanohybrids

24-May-2015 | Author(s): Shifeng Li , Yanming Shen , Min Xiao , Dongbin Liu , Lihui Fan, Arabian Journal of Chemistry, 2015

Publication date: Available online 5 May 2015 Source:Arabian Journal of Chemistry Author(s): Shifeng Li , Yanming Shen , Min Xiao , Dongbin Liu , Lihui Fan Controlled release formulations have been proven to have potential in overcoming the drawbacks of conventional plant growth ...

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Supramolecular Assembly of Isocyanorhodium(I) Complexes: An Interplay of Rhodium(I)···Rhodium(I) Interactions, Hydrophobic–Hydrophobic Interactions, and Host–Guest Chemistry

18-May-2015 | Alan Kwun-Wa Chan; Keith Man-Chung Wong; Vivian Wing-Wah Yam, Journal of the American Chemical Society, 2015

A series of tetrakis(isocyano)rhodium(I) complexes with different chain lengths of alkyl substituents has been found to exhibit a strong tendency toward solution state aggregation upon altering the concentration, temperature and solvent composition. Temperature- and solvent-dependent UV–vis ...

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An Ultimate Stereocontrol in Asymmetric Synthesis of Optically Pure Fully Aromatic Helicenes

18-May-2015 | Michal Šámal; Serghei Chercheja; Jiří Rybáček; Jana Vacek Chocholoušová; Jaroslav Vacek; Lucie Bednárová; David Šama ..., Journal of the American Chemical Society, 2015

The role of the helicity of small molecules in enantioselective catalysis, molecular recognition, self-assembly, material science, biology, and nanoscience is much less understood than that of point-, axial-, or planar-chiral molecules. To uncover the envisaged potential of helically chiral ...

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Frustrated Lewis Pair Chemistry: Development and Perspectives

14-May-2015 | Douglas W. Stephan, Gerhard Erker, Angewandte Chemie International Edition, 2015

Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in solution that are deterred from strong adduct formation by steric and/or electronic factors. This opens pathways to novel cooperative reactions with added substrates. Small‐molecule binding and activation ...

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Computational Study of Monosubstituted Azo(tetrazolepentazolium)-Based Ionic Dimers

13-May-2015 | Ian S. O. Pimienta, Journal of Physical Chemistry A, 2015

The structures of monosubstituted azo(tetrazolepentazolium) cations (N11CHR+), oxygen-rich anions such as N(NO2)2–, NO3–, and ClO4–, and the corresponding ion pairs are investigated using ab initio quantum chemistry calculations. The substituents (R) used are H, F, CH3, CN, NH2, OH, OCH3, N3, ...

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From Chemical Gardens to Fuel Cells: Generation of Electrical Potential and Current Across Self‐Assembling Iron Mineral Membranes

12-May-2015 | Laura M. Barge, Yeghegis Abedian, Michael J. Russell, Ivria J. Doloboff, Julyan H. E. Cartwright, Richard D. Kidd, I ..., Angewandte Chemie International Edition, 2015

Abstract We examine the electrochemical gradients that form across chemical garden membranes and investigate how self‐assembling, out‐of‐equilibrium inorganic precipitates—mimicking in some ways those generated in far‐from‐equilibrium natural systems—can generate electrochemical energy. ...

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Supramolecular Columnar Liquid Crystals Formed by Hydrogen Bonding between a Clicked Star‐Shaped s‐Triazine and Benzoic Acids

11-May-2015 | Beatriz Feringán, Pilar Romero, José Luis Serrano, Raquel Giménez, Teresa Sierra, Chemistry - A European Journal, 2015

Abstract A star‐shaped tris(triazolyl)triazine is shown to establish hydrogen‐bond interactions with polycatenar benzoic acids. The formation of hydrogen‐bonded triazine/acid complexes has been demonstrated both in solution and in bulk by different techniques. The complexes, mainly formed by ...

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