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Micellar and vesicular nanoassemblies of triazole-based amphiphilic probes triggered by mercury(II) ions in a 100% aqueous medium

22-10-2014 | Inhye Kim; Na-Eun Lee; Yoo-Jeong Jeong; Young-Ho Chung; Byoung-Ki Cho; Eunji Lee, Chemical Communication, 2014

ABA-type amphiphiles bearing a triazole-based aromatic block were easily synthesized using click chemistry, which act as fluorescent turn-off Hg2+–chemoprobes in an aqueous solution. Interestingly, the metal-binding process of amphiphiles induced nanoassemblies even below the CMCs, and the ...

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Fluorescent probes and bioimaging: alkali metals, alkaline earth metals and pH

22-10-2014 | Jun Yin; Ying Hu; Juyoung Yoon, Chemical Society Reviews, 2014

All living species and life forms have an absolute requirement for bio-functional metals and acid–base equilibrium chemistry owing to the critical roles they play in biological processes. Hence, a great need exists for efficient methods to detect and monitor biometals and acids. In the last few ...

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Excited-State Proton Coupled Electron Transfer Between Photolyase and the Damaged DNA Through Water Wire: A Photo-Repair Mechanism

22-10-2014 | Xuebo Chen; Hongjuan Wang; Wei-hai Fang, Physical Chemistry Chemical Physics, 2014

Phys. Chem. Chem. Phys., 2014, Accepted ManuscriptDOI: 10.1039/C4CP04130E, Paper Xuebo Chen, Hongjuan Wang, Wei-hai FangThis is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online ...

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Zipping Up Fullerenes into Polymers Using Rhodium(II) Acetate Dimer and N(CH2CH2)2NC60 as Building Blocks

22-10-2014 | Amineh Aghabali; Marilyn Olmstead; A L Balch, Chemical Communication, 2014

Chem. Commun., 2014, Accepted ManuscriptDOI: 10.1039/C4CC06995A, Communication Amineh Aghabali, Marilyn Olmstead, A L BalchThis is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published ...

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Synthesis of PS/PO-Chimeric Oligonucleotides Using Mixed Oxathiaphospholane and Phosphoramidite Chemistry

22-10-2014 | Janina Baraniak; Ewa Radzikowska, Organic & Biomolecular Chemistry, 2014

Chimeric oligonucleotides containing phosphodiester and phosphorothioate linkages have been obtained using the solid phase synthesis. The oligonucleotide parts possessing natural internucleotide phosphate bonds were assembled using commercially available nucleoside ...

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Phosphine Complexes of Lone Pair Bearing Lewis Acceptors

21-10-2014 | Saurabh Chitnis; Neil Burford, Dalton Transactions, 2014

An overview of the synthesis, structures and reaction chemistry of coordination complexes featuring an acceptor with at least one lone pair and at least one phosphine donor is presented. One or more examples of complexes have been structurally-characterized for the majority of p-block elements ...

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Development of GSK's acid and base selection guides

21-10-2014 | Richard K. Henderson; Alan P. Hill; Anikó M. Redman; Helen F. Sneddon, Green Chemistry, 2014

Further to the introduction of solvent and reagent guides at GSK, the reagent guide methodology has been adapted to score common acids and bases for use in situations where the chemistry is tolerant of a number of options. The pKa of each acid and base, and information as to whether they are ...

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Hot off the press

21-10-2014 | Robert A. Hill; Andrew Sutherland, Natural Product Reports, 2014

A personal selection of 32 recent papers is presented covering various aspects of current developments in bioorganic chemistry and novel natural products such as sinulariaoid A from a Sinularia species.

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Tripodal tris(hydroxypyridinone) ligands for immunoconjugate PET imaging with 89Zr4+: comparison with desferrioxamine-B

21-10-2014 | Michelle Ma; Levente K Meszaros; Brett Michael Paterson; David Berry; Maggie S Cooper; Yongmin Ma; Robert Hider; Phi ..., Dalton Transactions, 2014

Dalton Trans., 2014, Accepted ManuscriptDOI: 10.1039/C4DT02978J, Paper Michelle Ma, Levente K Meszaros, Brett Michael Paterson, David Berry, Maggie S Cooper, Yongmin Ma, Robert Hider, Philip J BlowerThis is an Accepted Manuscript, which has been through the RSC Publishing peer review process and ...

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Green photocatalytic organic transformations by polyoxometalates vs mesoporous TiO2 nanoparticles: Selective aerobic oxidation of alcohols. the article is invited paper for the “Special Issue of 8TH EUROPEAN MEETING ON SOLAR CHEMISTRY AND PHOTOCATALYSIS: ENVIRONMENTAL APPLICATIONS (SPEA 8)”

21-10-2014 | Ioannis Lykakis; Theodoros S Symeonidis; Ioannis Tamiolakis; Gerasimos S Armatas, Photochemical & Photobiological Sciences, 2014

In this study, the catalytic activity of decatungstate (W10O324-) supported on mesoporous TiO2 assemblies (DT-MTA) was compared with that of homogeneous [Bu4N]4W10O32 catalysts under mild conditions. Our experiments showed that both catalytic systems achieve exceptionally high activity and ...

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