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Crack patterns in superlattices made of maghemite nanocrystals

15-05-2013 | Anh-Tu Ngo; Johannes Richardi; Marie-Paule Pileni, Physical Chemistry Chemical Physics, 2013

Here, 11 nm γ-Fe2O3 nanocrystals characterized by a low size distribution of 5% and dispersed in chloroform are deposited onto a substrate as well-defined films. The film thickness is controlled by the initial concentration of the colloidal solution. After drying, the film shows a network of ...

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Solution Equilibria of Anticancer Ruthenium(II)-(η6-p-Cymene)-Hydroxy(thio)pyr(id)one Complexes: Impact of Sulfur vs. Oxygen Donor Systems on the Speciation and Bioactivity

13-05-2013 | Author(s): Éva A. Enyedy , Éva Sija , Tamás Jakusch , Christian G. Hartinger , Wolfgang Kandioller , Bernhard K ..., Journal of Inorganic Biochemistry, 2013

Publication date: Available online 7 May 2013 Source:Journal of Inorganic Biochemistry Author(s): Éva A. Enyedy , Éva Sija , Tamás Jakusch , Christian G. Hartinger , Wolfgang Kandioller , Bernhard K. Keppler , Tamás Kiss Stoichiometry and stability of antitumor ...

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Micelle formation of sodium hyodeoxycholate

13-05-2013 | Author(s): Keisuke Matsuoka , Kaede Takagi , Chikako Honda, Chemistry and Physics of Lipids, 2013

Publication date: Available online 7 May 2013 Source:Chemistry and Physics of Lipids Author(s): Keisuke Matsuoka , Kaede Takagi , Chikako Honda Sodium hyodeoxycholate (NaHDC) is the main component of hog bile salts, which play a role in the absorption of sparingly soluble materials ...

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Study of phase relationships in the Sr3(PO4)2–CePO4 system. Phase diagram and thermal characteristics of phases

13-05-2013 | Author(s): Aleksandra Matraszek, Journal of Solid State Chemistry, 2013

Publication date: July 2013 Source:Journal of Solid State Chemistry, Volume 203 Author(s): Aleksandra Matraszek A diagram representing phase relationships in the Sr3(PO4)2–CePO4 phosphate system has been developed on the basis of results obtained by thermal analysis (DTA/DSC/TGA) and ...

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Low‐Temperature Transformation of Titania Thin Films from Amorphous Nanowires to Crystallized Nanoflowers for Heterogeneous Photocatalysis

11-05-2013 | Jing Sun, Wei Wen, Jin‐Ming Wu, Journal of the American Ceramic Society, 2013

Titania thin films with ordered nanostructures are of general interest in fields of photocatalysis, gas sensors, energy storages, energy conversions, etc. In this study, we report a low‐temperature crystallization and the simultaneously occurred morphology change of titania thin films in a ...

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The viscoelastic behavior of concentrated polyacrylonitrile/1‐butyl‐3‐methylimidazolium chloride from solution to gel

11-05-2013 | Xinjun Zhu, Hina Saba, Yumei Zhang, Huaping Wang, Polymer Engineering and Science, 2013

Abstract The viscoelastic behavior of concentrated polyacrylonitrile (PAN) /1‐butyl‐3‐methylimidazolium chloride ([BMIM]Cl) solutions at different concentrations and temperatures has been investigated by rheology. For concentrated polymer solutions at low temperature (40°C), the shear ...

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Design of a Solid‐State Electrochemiluminescence Biosensor for Detection of PML/RARα Fusion Gene Using Ru(bpy)${{{2+\hfill \atop 3\hfill}}}$‐AuNPs Aggregations on Gold Electrode

10-05-2013 | Yun Lei, Yajing Lin, Yanjie Zheng, Ming Dai, Kun Wang, Xinhua Lin, Electroanalysis, 2013

Abstract A solid‐state electrochemiluminescence (ECL) biosensor based on special ferrocene‐labeled molecular beacon (Fc‐MB) for highly sensitive detection of promyelocytic leukemia/retinoic acid receptor alpha (PML/RARα) fusion gene was developed successfully using ...

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Nanofibers with Very Fine Core–Shell Morphology from Anisotropic Micelle of Amphiphilic Crystalline-Coil Block Copolymer

10-05-2013 | Fei-Yu Zhai; Wei Huang; Gang Wu; Xin-Ke Jing; Mei-Jia Wang; Si-Chong Chen; Yu-Zhong Wang; In-Joo Chin; Ya Liu, ACS Nano, 2013

A novel and facile strategy, combining anisotropic micellization of amphiphilic crystalline-coil copolymer in water and reassembly during single spinneret electrospinning, was developed for preparing nanofibers with very fine core–shell structure. Polyvinyl alcohol (PVA) and polyethylene ...

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Decoration of Microparticles by Highly Charged Nanoparticles

10-05-2013 | Haohao Huang; Eli Ruckenstein, Journal of Physical Chemistry B, 2013

A negatively charged microparticle is immersed into an aqueous solution containing highly negatively charged nanoparticles and an electrolyte. Using a modified Poisson–Boltzmann equation which takes into account the van der Waals interactions between microparticle and nanoparticles and in ...

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Novel ethylene/norbornene copolymers as nonreleasing antioxidants for food‐contact polyolefinic materials

08-05-2013 | Paola Stagnaro, Giorgio Mancini, Achille Piccinini, Simona Losio, Maria Carmela Sacchi, Caterina Viglianisi, Stefano ..., Journal of Polymer Science Part B: Polymer Physics, 2013

ABSTRACT An efficient procedure for the copolymerization of ethylene (E) with a novel norbornenic comonomer (NArOH) bearing a stabilizing moiety analogous to commercial antioxidant 2,6‐di‐tert‐butyl‐4‐methylphenol (BHT) is successfully developed. This study is aimed at: i) tuning the ...

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