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One-pot hydrothermal synthesis carbon nanocages-reduced graphene oxide composites for simultaneous electrochemical detection of catechol and hydroquinone

22-Feb-2015 | Author(s): Yi Hong Huang , Jian Hua Chen , Xue Sun , Zhen Bo Su , Hai Tao Xing , Shi Rong Hu , Wen Weng , Hon ..., Sensors and Actuators B: Chemical, 2015

Publication date: June 2015 Source:Sensors and Actuators B: Chemical, Volume 212 Author(s): Yi Hong Huang , Jian Hua Chen , Xue Sun , Zhen Bo Su , Hai Tao Xing , Shi Rong Hu , Wen Weng , Hong Xu Guo , Wen Bing Wu , Ya San He Facile and stable nanocomposites, carbon nanocages ...


Photocatalytically active fluorinated nano-titania synthesized by microwave-assisted hydrothermal treatment

22-Feb-2015 | Author(s): A.A. Sadovnikov , A.E. Baranchikov , Y.V. Zubavichus , O.S. Ivanova , V.Y. Murzin , V.V. Kozik , V. ..., Journal of Photochemistry and Photobiology A: Chemistry, 2015

Publication date: 15 April–1 May 2015 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volumes 303–304 Author(s): A.A. Sadovnikov , A.E. Baranchikov , Y.V. Zubavichus , O.S. Ivanova , V.Y. Murzin , V.V. Kozik , V.K. Ivanov Nanocrystalline fluorinated titania has been ...


Toward Ion-Free Polyelectrolyte Multilayers: Cyclic Salt Annealing

22-Feb-2015 | Hadi M. Fares; Yara E. Ghoussoub; Richard L. Surmaitis; Joseph B. Schlenoff, Langmuir, 2015

Polyelectrolyte multilayers (PEMUs) are made from various combinations of polyanions and polycations. It is now understood that these ultrathin films of polyelectrolyte complex may also incorporate counterions derived from the solutions from which the PEMU was deposited or exchanged into the film ...


Effect of fluid velocity on radioactive ion retention by fluidized bed reactor

21-Feb-2015 | Mohamed Abdelaziz, Azza H. Ali, Hesham F. Elbakhshawangy, Sameh H. Othman, The Canadian Journal of Chemical Engineering, 2015

This study is concerned with the design, construction, simulation, and pre‐operation of a fluidized bed reactor for low level radioactive waste treatment by a new chelating resin. In this respect a new mathematical model is suggested to account for the effect of fluid velocity and to determine ...


Fluorescent probe for detection of Cu2+ using core‐shell CdTe/ZnS quantum dots

20-Feb-2015 | Wei Bian, Fang Wang, Hao Zhang, Lin Zhang, Li Wang, Shaomin Shuang, Luminescence, 2015

Abstract Core‐shell CdTe/ZnS quantum dots capped with 3‐mercaptopropionic acid (MPA) were successfully synthesized in aqueous medium by hydrothermal synthesis. These quantum dots have advantages compared to traditional quantum dots with limited biological applications, high toxicity and ...


An Interconverting Family of Coordination Cages and a meso-Helicate; Effects of Temperature, Concentration, and Solvent on the Product Distribution of a Self-Assembly Process

20-Feb-2015 | William Cullen; Christopher A. Hunter; Michael D. Ward, Inorganic Chemistry, 2015

The self-assembly between a water-soluble bis-bidentate ligand L18w and Co(II) salts in water affords three high-spin Co(II) products: a dinuclear meso-helicate [Co2(L18w)3]X4; a tetrahedral cage [Co4(L18w)6]X8; and a dodecanuclear truncated-tetrahedral cage [Co12(L18w)18]X24 (X = BF4 or ClO4). ...


Poly(ethylene glycol) Conjugated Poly(lactide)-Based Polyelectrolytes: Synthesis and Formation of Stable Self-Assemblies Induced by Stereocomplexation

19-Feb-2015 | Zibiao Li; Du Yuan; Xiaoshan Fan; Beng H. Tan; Chaobin He, Langmuir, 2015

A series of pH-responsive amphiphilic poly(N,N-dimethylaminoethyl methacrylate)-block-poly(d-lactic acid)-block-poly(N,N-dimethylaminoethyl methacrylate) conjugated with poly(ethylene glycol) (D-PDLA-D@PEG) and D-PLLA-D@PEG copolymers were synthesized using a combination of ring-opening ...


Lead(II) Complex Formation with l-Cysteine in Aqueous Solution

19-Feb-2015 | Farideh Jalilehvand; Natalie S. Sisombath; Adam C. Schell; Glenn A. Facey, Inorganic Chemistry, 2015

The lead(II) complexes formed with the multidentate chelator l-cysteine (H2Cys) in an alkaline aqueous solution were studied using 207Pb, 13C, and 1H NMR, Pb LIII-edge X-ray absorption, and UV–vis spectroscopic techniques, complemented by electrospray ion mass spectrometry (ESI-MS). The ...


Adsorption of Proteins at the Solution/Air Interface Influenced by Added Nonionic Surfactants at Very Low Concentrations for Both Components. 3. Dilational Surface Rheology

19-Feb-2015 | V. B. Fainerman; E. V. Aksenenko; S. V. Lylyk; M. Lotfi; R. Miller, Journal of Physical Chemistry B, 2015

The influence of the addition of the nonionic surfactants C12DMPO, C14DMPO, C10OH, and C10EO5 at concentrations between 10–5 and 10–1 mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10–5 mmol/L on the dilational surface rheology is studied. A maximum in ...


Supramolecular Assembly of Achiral Alkynylplatinum(II) Complexes and Carboxylic β‐1,3‐Glucan into Different Helical Handedness Stabilized by Pt⋅⋅⋅Pt and/or π–π Interactions

18-Feb-2015 | Clive Yik‐Sham Chung, Shun‐ichi Tamaru, Seiji Shinkai, Vivian Wing‐Wah Yam, Chemistry - A European Journal, 2015

Abstract Two‐component ensembles of alkynylplatinum(II) terpyridine (tpy) complexes and carboxylic β‐1,3‐glucan (CurCOOH) have been investigated by using spectroscopic and microscopic techniques, as well as time‐dependent UV/Vis absorption and circular dichroism (CD) experiments. Microscopic ...


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