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Superior Lithium‐Ion Storage Properties of Mesoporous CuO–Reduced Graphene Oxide Composite Powder Prepared by a Two‐Step Spray‐Drying Process

14-May-2015 | Gi Dae Park, Yun Chan Kang, Chemistry - A European Journal, 2015

Abstract Mesoporous CuO–reduced graphene oxide (rGO) composite powders were prepared by using a two‐step spray‐drying process. In the first step, hollow CuO powders were prepared from a spray solution of copper nitrate trihydrate with citric acid and were wet milled to obtain a colloidal spray ...


A simplified micromechanics model for predicting the stiffness degradation in symmetric composite laminates

14-May-2015 | A. Farrokhabadi, B. Mohammadi, H. Hosseini‐Toudeshky, Fatigue & Fracture of Engineering Materials & Structures, 2015

Abstract Recently, the authors of this paper have developed a new micromechanics approach to evaluate the stress fields and material properties of an orthotropic composite ply containing specified matrix cracking density under multi‐axial loading condition. In this study, more complementary ...


The stability of aluminum‐manganese intermetallic phases under the microgalvanic coupling conditions anticipated in magnesium alloys

12-May-2015 | R. M. Asmussen, W. J. Binns, R. Partovi‐Nia, P. Jakupi, D. W. Shoesmith, Materials and Corrosion, 2015

The electrochemical behaviour of two Al‐Mn materials (Al‐ 5.5 at % Mn and Al‐ 13.5 at % Mn) has been studied in 0.275 M NaCl and 0.138 M MgCl2 solutions to simulate the cathodic environment of Al‐Mn particles during the corrosion of a Mg alloy. Upon polarization in NaCl solution to a potential ...


Novel water soluble neutral vanadium(IV)–antibiotic complex: Antioxidant, immunomodulatory and molecular docking studies

11-May-2015 | Author(s): Chitraniva Datta , Dharitri Das , Paritosh Mondal , Biswajit Chakraborty , Mahuya Sengupta , Chira R ..., European Journal of Medicinal Chemistry, 2015

Publication date: Available online 8 May 2015 Source:European Journal of Medicinal Chemistry Author(s): Chitraniva Datta , Dharitri Das , Paritosh Mondal , Biswajit Chakraborty , Mahuya Sengupta , Chira R. Bhattacharjee A novel water soluble five coordinate oxovanadium(IV) complex, ...


Density fluctuations in aqueous solution of ionic liquid with lower critical solution temperature: Mixture of tetrabutylphosphonium trifluoroacetate and water

10-May-2015 | Author(s): Ayako Nitta , Takeshi Morita , Shohei Saita , Yuki Kohno , Hiroyuki Ohno , Keiko Nishikawa, Chemical Physics Letters, 2015

Publication date: 16 May 2015 Source:Chemical Physics Letters, Volume 628 Author(s): Ayako Nitta , Takeshi Morita , Shohei Saita , Yuki Kohno , Hiroyuki Ohno , Keiko Nishikawa Aqueous solutions of tetrabutylphosphonium trifluoroacetate ([P4444]CF3COO) exhibit a LCST-type phase ...


Two phosphaalkene radical cations with inverse spin density distributions

08-May-2015 | Xiaobo Pan; Xingyong Wang; Zaichao Zhang; Xinping Wang, Dalton Transactions, 2015

Two phosphaalkene radical cations 1˙+ and 2˙+ have been reported. 1˙+ is stable in the solid state and has been structurally characterized. 2˙+ only remains persistent in solution. 1˙+ is described as a phosphorus-centered radical, while 2˙+ as a delocalized radical with little contribution from ...


Theoretical studies on the absorption spectra of cis-[Ru(4,4'-COO-2,2'-bpy)2(X)2]4-, (X = NCS, Cl) in water and panchromatic trans-terpyridyl Ru complexes in methanol solution based on time-dependent density functional theory including strong spin-orbit couplings

08-May-2015 | Kenji Mishima; Takumi Kinoshita; Michitoshi Hayashi; Ryota Jono; Hiroshi Segawa; Koichi Yamashita; Sheng Hsien Lin, Physical Chemistry Chemical Physics, 2015

In this paper, we theoretically and experimentally investigate the photophysical and chemical characteristics and absorption spectra of various ruthenium complexes in solution used as efficient dye-sensitized solar cells. The target molecules are two well-known complexes, ...


Explicit Correlated Exciton-Vibrational Dynamics of the FMO Complex

08-May-2015 | J. Schulze; O. Kühn, Journal of Physical Chemistry B, 2015

The coupled exciton-vibrational dynamics of a three-site model of the Fenna–Matthews–Olson complex is investigated using the numerically exact multilayer multiconfiguration time-dependent Hartree approach. Thereby the specific coupling of the vibrational modes to local electronic transitions is ...


Aqueous Biphasic Systems Composed of Ionic Liquids and Acetate-Based Salts: Phase Diagrams, Densities, and Viscosities

07-May-2015 | Maria V. Quental; Helena Passos; Kiki A. Kurnia; João A. P. Coutinho; Mara G. Freire, Journal of Chemical & Engineering Data, 2015

Ionic-liquid-based aqueous biphasic systems (IL-based ABS) have been largely investigated as promising extraction and purification routes. In this context, the determination of their phase diagrams and the physical properties of the coexisting phases are of high relevance when envisaging their ...


Production of Spray‐Dried Sapodilla (Manilkara Zapota) Powder from Enzyme‐Aided Liquefied Puree

06-May-2015 | Siew Yee Chong, Chen Wai Wong, Journal of Food Processing and Preservation, 2015

Abstract Sapodilla puree was naturally viscous and was liquefied with enzymes (Pectinex Ultra SP‐L and Celluclast 1.5L) acting individually or in combinations at varying concentrations (0.5–2.5% v/w), times (0.5–2.5 h) and temperatures (35–55C) prior to the drying process. Treatment with ...


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