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Improved speed of hydrogen detection by Schottky diodes on InP with electrophoretically deposited Pt nanoparticles and graphite contacts

20-05-2013 | Author(s): Karel Zdansky , James H. Dickerson, Sensors and Actuators B: Chemical, 2013

Publication date: 31 July 2013 Source:Sensors and Actuators B: Chemical, Volume 184 Author(s): Karel Zdansky , James H. Dickerson The electrophoretic deposition (EPD) of nanoparticles (NPs) of the catalytic metal platinum (Pt) onto semiconductor wafers of indium phosphide (InP) from ...

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Raman Second Hyperpolarizability Determination Using Computational Raman Activities and a Comparison with Experiments

17-05-2013 | Wei Zhao; Anqi He; Yizhuang Xu, Journal of Physical Chemistry A, 2013

Doubly vibrationally enhanced (DOVE) four-wave mixing spectroscopy, an optical analogue to 2D NMR, involves two infrared transitions and a Raman transition. The magnitude of the DOVE second hyperpolarizability γ (or third-order susceptibility χ(3)) can be theoretically estimated if the values ...

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Multinuclear Magnetic Resonance Spectroscopy and Density Function Theory Calculations for the Identification of the Equilibrium Species in THF Solutions of Organometallic Complexes Suitable As Electrolyte Solutions for Rechargeable Mg Batteries

17-05-2013 | Nir Pour; Yossi Gofer; Dan T. Major; Keren Keinan-Adamsky; Hugo E. Gottlieb; Doron Aurbach, Organometallics, 2013

We present a multinuclear nuclear magnetic resonance (NMR) and density functional theory (DFT) study of electrolyte solutions based on organometallic complexes with aromatic ligands. These solutions constitute a unique electrolyte family possessing a wide electrochemical window, making them ...

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Interpreting “Acidity” as a Global Property Controlling Comonomer Reactivity in Olefin Polymerization

17-05-2013 | Lorella Izzo; Massimo Mella, Organometallics, 2013

A possible rationale for the different catalytic behaviors of systems based on rac-(ethylenebis(1-indenyl))zirconium dichloride (rac-EBIZrCl2), rac-(ethylenebis(1-indenyl))hafnium dichloride (rac-EBIHfCl2), and rac-(isopropylidenebis(1-indenyl))zirconium dichloride (rac-iPrBIZrCl2) toward ...

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Electronic Properties of [Core+exo]-type Gold Clusters: Factors Affecting the Unique Optical Transitions

16-05-2013 | Yukatsu Shichibu; Katsuaki Konishi, Inorganic Chemistry, 2013

Unusual visible absorption properties of [core+exo]-type Au6 (1), Au8 (2), and Au11 (3) clusters were studied from experimental and theoretical aspects, based on previously determined crystal structures. Unlike conventional core-only clusters having no exo gold atoms, these nonspherical ...

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Biofuel Cell Operating in Vivo in Rat

15-05-2013 | Jorge A. Castorena‐Gonzalez, Christopher Foote, Kevin MacVittie, Jan Halámek, Lenka Halámková, Luis A. Martinez‐Lemu ..., Electroanalysis, 2013

Abstract Biocatalytic electrodes made of buckypaper were modified with PQQ‐dependent glucose dehydrogenase on the anode and with laccase on the cathode. The enzyme modified electrodes were assembled in a biofuel cell which was first characterized in human serum solution and then the ...

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Intramolecular Halogen–Halogen Bonds?

15-05-2013 | Mikael P. Johansson; Marcel Swart, Physical Chemistry Chemical Physics, 2013

By analysing the properties of the electron density in the structurally simple perhalogenated ethanes, X3C–CY3 (X, Y = F, Cl), a previously overlooked non-covalent attraction between halogens attached to opposite carbon atoms is found. Quantum chemical calculations extrapolated towards the ...

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Nanocomposites of Surface‐Modified BaTiO3 Nanoparticles Filled Ferroelectric Polymer with Enhanced Energy Density

13-05-2013 | Ke Yu, Yujuan Niu, Yongcun Zhou, Yuanyuan Bai, Hong Wang, Journal of the American Ceramic Society, 2013

We report nanocomposites of increased dielectric permittivity, enhanced electric breakdown strength and high‐energy density based on surface‐modified BaTiO3 (BT) nanoparticles filled poly(vinylidene fluoride) polymer. Polyvinylprrolidone (PVP) is used as the surface modification agent and ...

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Electrical characterization of liquid‐phase‐deposited SiON on (NH4)2S‐treated GaAs

13-05-2013 | Chih‐Feng Yen, Jung‐Chan Lee, Chi‐Hsuan Cheng, Ming‐Kwei Lee, physica status solidi (a), 2013

Abstract The electrical characteristics of liquid‐phase‐deposited (LPD) silicon oxynitride film on ammonium‐sulfide‐treated p‐type (100) gallium arsenide (GaAs) substrate were investigated. Hydrofluosilicic acid, ammonia, and boric acid aqueous solutions were used as precursors. The ...

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Surface Modification of Silicon Oxide with Trialkoxysilanes toward Close-Packed Monolayer Formation

13-05-2013 | Mutsuo Tanaka; Takahiro Sawaguchi; Masashi Kuwahara; Osamu Niwa, Langmuir, 2013

In order to scrutinize potential of trialkoxysilanes to form close-packed monolayer, surface modification of silicon oxide was carried out with the trialkoxysilanes bearing a ferrocene moiety for analysis by electrochemical methods. As it was found that hydrogen-terminated silicon reacts with ...

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