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Characterization and biotransformation in the plasma and red blood cells of VIVO2+ complexes formed by ceftriaxone

04-Jan-2015 | Author(s): Daniele Sanna , Davide Fabbri , Maria Serra , Péter Buglyó , Linda Bíró , Valeria Ugone , Giovanni ..., Journal of Inorganic Biochemistry, 2015

Publication date: Available online 29 December 2014 Source:Journal of Inorganic Biochemistry Author(s): Daniele Sanna , Davide Fabbri , Maria Serra , Péter Buglyó , Linda Bíró , Valeria Ugone , Giovanni Micera , Eugenio Garribba The coordination mode and geometry in aqueous solution ...


Photoacoustic calorimetry study of ligand photorelease from the Ru(II)bis(2,2′-bipyridine)(6,6′-dimethyl-2,2′-bipyridine) complex in aqueous solution

04-Jan-2015 | Author(s): Tarah A. Word , Christi L. Whittington , Aleksandra Karolak , M. Trent Kemp , H. Lee Woodcock , Arja ..., Chemical Physics Letters, 2015

Publication date: 5 January 2015 Source:Chemical Physics Letters, Volume 619 Author(s): Tarah A. Word , Christi L. Whittington , Aleksandra Karolak , M. Trent Kemp , H. Lee Woodcock , Arjan van der Vaart , Randy W. Larsen The thermodynamics of ligand photorelease from ...


Stable quasi-solid-state dye-sensitized solar cell using ionic gel electrolyte with low molecular mass organogelator

04-Jan-2015 | Author(s): Li Tao , Zhipeng Huo , Songyuan Dai , Jun Zhu , Changneng Zhang , Xu Pan , Yang Huang , Shangfeng ..., Materials Chemistry and Physics, 2015

Publication date: 15 February 2015 Source:Materials Chemistry and Physics, Volume 152 Author(s): Li Tao , Zhipeng Huo , Songyuan Dai , Jun Zhu , Changneng Zhang , Xu Pan , Yang Huang , Shangfeng Yang , Bing Zhang , Jianxi Yao Long-term stability is essential for the application ...


Synthesis and Structure of Trinuclear W3S4 Clusters Bearing Aminophosphine Ligands and Their Reactivity toward Halides and Pseudohalides

31-Dec-2014 | Tomás F. Beltrán; Jose Ángel Pino-Chamorro; M. Jesús Fernández-Trujillo; Vicent S. Safont; Manuel G. Basallote; Rosa ..., Inorganic Chemistry, 2014

The aminophosphine ligand (2-aminoethyl)diphenylphosphine (edpp) has been coordinated to the W3(μ-S)(μ-S)3 cluster unit to afford trimetallic complex [W3S4Br3(edpp)3]+ (1+) in a one-step synthesis process with high yields. Related [W3S4X3(edpp)3]+ clusters (X = F–, Cl–, NCS–; 2+–4+) have been ...


Unraveling the Intrinsic Color of Chlorophyll

30-Dec-2014 | Bruce F. Milne, Yoni Toker, Angel Rubio, Steen Brøndsted Nielsen, Angewandte Chemie International Edition, 2014

Abstract The exact color of light absorbed by chlorophyll (Chl) pigments, the light‐harvesters in photosynthesis, is tuned by the protein microenvironment, but without knowledge of the intrinsic color of Chl it remains unclear how large this effect is. Experimental first absorption energies of ...


Dense, Highly Hydrated Polymer Brushes via Modified Atom-Transfer-Radical-Polymerization: Structure, Surface Interactions, and Frictional Dissipation

30-Dec-2014 | Odeya Tairy; Nir Kampf; Michael J. Driver; Steven P. Armes; Jacob Klein, Macromolecules, 2014

The conditions for atom transfer radical polymerization (ATRP) of poly[2-(methacryloyloxy)ethyl phosphorylcholine] (pMPC) chains are modified to enable much more efficient growth of these poly zwitterionic chains from macroinitiator-coated mica substrates using the “grafting from” technique. In ...


Robust Electrodes Based on Coaxial TiC/C–MnO2 Core/Shell Nanofiber Arrays with Excellent Cycling Stability for High‐Performance Supercapacitors

28-Dec-2014 | Xuming Zhang, Xiang Peng, Wan Li, Limin Li, Biao Gao, Guosong Wu, Kaifu Huo, Paul K. Chu, Small, 2014

A coaxial electrode structure composed of manganese oxide‐decorated TiC/C core/shell nanofiber arrays is produced hydrothermally in a KMnO4 solution. The pristine TiC/C core/shell structure prepared on the Ti alloy substrate provides the self‐sacrificing carbon shell and highly conductive TiC ...


The Paradox of Hydrogen-Bonded Anion–Anion Aggregates in Oxoanions: A Fundamental Electrostatic Problem Explained in Terms of Electrophilic···Nucleophilic Interactions

26-Dec-2014 | Ignasi Mata; Elies Molins; Ibon Alkorta; Enrique Espinosa, Journal of Physical Chemistry A, 2014

A theoretical study of anionic complexes formed by two partly deprotonated oxoacids joined by hydrogen bonds has been carried out at the MP2 computational level. In spite of the ionic repulsion, local energy minima are found both in the gas phase and in aqueous solution. Electrostatic potential ...


Poly(sulfobetaine methacrylate)s as Electrode Modifiers for Inverted Organic Electronics

26-Dec-2014 | Hyunbok Lee; Egle Puodziukynaite; Yue Zhang; John C. Stephenson; Lee J. Richter; Daniel A. Fischer; Dean M. DeLongch ..., Journal of the American Chemical Society, 2014

We demonstrate the use of poly(sulfobetaine methacrylate) (PSBMA), and its pyrene-containing copolymer, as solution-processable work function reducers for inverted organic electronic devices. A notable feature of PSBMA is its orthogonal solubility relative to solvents typically employed in the ...


Solvation and Hydration of the Ceramide Headgroup in a Non-Polar Solution

24-Dec-2014 | Richard J. Gillams; Jon V. Busto; Sebastian Busch; Félix M. Goñi; Christian D. Lorenz; Sylvia E. McLain, Journal of Physical Chemistry B, 2014

The microscopic hydration of the ceramide headgroup has been determined using a combination of experimental—both NMR and neutron diffraction techniques and computational techniques—empirical potential structure refinement (EPSR) and molecular dynamics (MD). The addition of water to ceramide in ...


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