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1,512 Newest Publications about the topic solution

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p‐Si/SnO2/Fe2O3 Core/Shell/Shell Nanowire Photocathodes for Neutral pH Water Splitting

21-Mar-2015 | Alireza Kargar, Sung Joo Kim, Paniz Allameh, Chulmin Choi, Namseok Park, Huisu Jeong, Yusin Pak, Gun Young Jung, Xia ..., Advanced Functional Materials, 2015

Silicon is one of the promising materials for solar water splitting and hydrogen production; however, it suffers from two key factors, including the large external potential required to drive water splitting reactions at its surface and its instability in the electrolyte. In this study, a ...

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Modified kaolinites‐polyalkyl methacrylate nanocomposites: Exploring relations between solubility parameters and thermal properties for in situ solution polymerization

20-Mar-2015 | Ruhan Benlikaya, Vural Bütün, Mahir Alkan, Polymer Composites, 2015

Poly(methyl methacrylate) (PMMA), poly(ethyl methacrylate) (PEMA), and their nanocomposites (Kao‐PMMAs and Kao‐PEMAs) with various kaolinite intercalation compounds were prepared in several solution polymerization media in order to examine relations between solubility parameters of ...

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A new two‐dimensional anionic cadmium(II) polymer constructed through thiocyanate coordination bridges

19-Mar-2015 | Hui‐Ting Wang, Xiao‐Li Wang, Acta Crystallographica Section C, 2015

A new cadmium–thiocyanate complex, poly[4‐(dimethylamino)pyridin‐1‐ium [di‐μ‐thiocyanato‐κ2N:S;κ2S:N‐thiocyanato‐κN‐cadmium(II)]], {(C7H11N2)[Cd(NCS)3]}n, was synthesized by the reaction of cadmium thiocyanate and 4‐(dimethylamino)pyridine hydrochloride in aqueous solution. In the crystal ...

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Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation

17-Mar-2015 | Robert M. Edkins; Elliott Hayden; Jonathan W. Steed; Katharina Fucke, Chemical Communication, 2015

Two tetrahydocarbazolone derivatives were found to show multiple unsolvated crystal forms. A persistent dimer motif was detected in solution by FTIR spectroscopy that is maintained in the kinetic crystal forms. Rationally introduced steric bulk induces the formation of a more stable catemeric ...

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Determinants of oligosaccharide specificity of the carbohydrate binding modules of AMP-activated protein kinase

16-Mar-2015 | Mobbs J; Koay A; Di Paolo A; Bieri M; Petrie E; Gorman M; Doughty L; Parker M; Stapleton D; Griffin M; Gooley P, Biochemical Journal, 2015

AMPK-activated protein kinase (AMPK) is a αβγ heterotrimer that is important in regulating energy metabolism in all eukaryotes. The β-subunit exists in two isoforms (β1 and β2) and contains a carbohydrate binding module (CBM) that interacts with glycogen. The two CBM isoforms (β1- and β2-CBM) are ...

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Photoinduced Formation of an Azobenzene‐Based CD‐Active Supramolecular Cyclic Dimer

12-Mar-2015 | Hiromitsu Sogawa, Kayo Terada, Yu Miyagi, Masashi Shiotsuki, Yoshihito Inai, Toshio Masuda, Fumio Sanda, Chemistry - A European Journal, 2015

Abstract A series of new photo‐responsive amino acid‐derived azobenzenedicarboxylic acid derivatives (S)‐1 a–e were synthesized. Compound (S)‐1 a in the trans form exhibited no circular dichroism (CD) signal in DMF under ambient conditions, whereas intense Cotton effects were observed upon UV ...

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Allosterically Controlled Threading of Polymers through Macrocyclic Dimers

12-Mar-2015 | Seda Cantekin; Albert J. Markvoort; Johannes A. A. W. Elemans; Alan E. Rowan; Roeland J. M. Nolte, Journal of the American Chemical Society, 2015

As part of an ongoing study to construct a molecular Turing machine in which a polymer chain is encoded via allosteric information transfer between macrocyclic complexes, we describe the thermodynamic and kinetic characterization of a multicomponent self-assembled system based on a zinc porphyrin ...

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Coke Deposition on Ni/HZSM-5 in Bio-oil Hydrodeoxygenation Processing

10-Mar-2015 | Yu Li; Changsen Zhang; Yonggang Liu; Xiaoxue Hou; Ruiqin Zhang; Xiaoyan Tang, Energy & Fuels, 2015

The deactivation of bifunctional Ni/HZSM-5 catalysts is essentially due to the formation of heavy secondary products (i.e., coke) in the hydrodeoxygenation (HDO) of bio-oil. Coke deposited on the Ni/HZSM-5 catalyst was characterized using analytical techniques, including Fourier transform ...

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Hydrogen Bond, π–π, and CH–π Interactions Governing the Supramolecular Assembly of Some Hydrazone Ligands and Their MnII Complexes – Structural and Theoretical Interpretation

05-Mar-2015 | Dipali Sadhukhan, Monami Maiti, Guillaume Pilet, Antonio Bauzá, Antonio Frontera, Samiran Mitra, European Journal of Inorganic Chemistry, 2015

Abstract The hydrazone Schiff base ligands (E)‐N′‐(2‐hydroxybenzylidene)acetohydrazide (HL1) and (E)‐N′‐(2,3‐dihydroxybenzylidene)acetohydrazide (H2L2) with a functional group variation in the aromatic moiety have been synthesized. The ligands have been used to synthesize the following MnII ...

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Effect of gluconate ions on electroreduction phenomena during manganese deposition on glassy carbon in acidic chloride and sulfate solutions

01-Mar-2015 | Author(s): Ewa Rudnik, Journal of Electroanalytical Chemistry, 2015

Publication date: 15 March 2015 Source:Journal of Electroanalytical Chemistry, Volume 741 Author(s): Ewa Rudnik Cathodic processes occurring during manganese deposition from acidic baths (pH 3.5) were investigated using glassy carbon rotating disk electrode. Cyclic voltammetry, linear ...

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