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Multinuclear Magnetic Resonance Spectroscopy and Density Function Theory Calculations for the Identification of the Equilibrium Species in THF Solutions of Organometallic Complexes Suitable As Electrolyte Solutions for Rechargeable Mg Batteries

17-05-2013 | Nir Pour; Yossi Gofer; Dan T. Major; Keren Keinan-Adamsky; Hugo E. Gottlieb; Doron Aurbach, Organometallics, 2013

We present a multinuclear nuclear magnetic resonance (NMR) and density functional theory (DFT) study of electrolyte solutions based on organometallic complexes with aromatic ligands. These solutions constitute a unique electrolyte family possessing a wide electrochemical window, making them ...

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Encapsulation of Photosensitizers in Hexa- and Octanuclear Organometallic Cages: Synthesis and Characterization of Carceplex and Host–Guest Systems in Solution

14-05-2013 | Julien Freudenreich; Claudio Dalvit; Georg Süss-Fink; Bruno Therrien, Organometallics, 2013

Cationic arene ruthenium assemblies of the general formulas [Ru6(p-cymene)6(tris-pvb)2(μ2-Cl)6]6+, [Ru6(p-cymene)6(tris-pvb)2(OO∩OO)3]6+ (tris-pvb = 1,3,5-tris{2-(pyridin-4-yl)vinyl}benzene), and [Ru8(p-cymene)8(NN∩NN)2(OO∩OO)4]8+ (NN∩NN = 1,2,4,5-tetrakis{2-(pyridin-4-yl)vinyl}benzene, ...

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Solution Equilibria of Anticancer Ruthenium(II)-(η6-p-Cymene)-Hydroxy(thio)pyr(id)one Complexes: Impact of Sulfur vs. Oxygen Donor Systems on the Speciation and Bioactivity

13-05-2013 | Author(s): Éva A. Enyedy , Éva Sija , Tamás Jakusch , Christian G. Hartinger , Wolfgang Kandioller , Bernhard K ..., Journal of Inorganic Biochemistry, 2013

Publication date: Available online 7 May 2013 Source:Journal of Inorganic Biochemistry Author(s): Éva A. Enyedy , Éva Sija , Tamás Jakusch , Christian G. Hartinger , Wolfgang Kandioller , Bernhard K. Keppler , Tamás Kiss Stoichiometry and stability of antitumor ...

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Heat-Induced Fibrillation of BclXL Apoptotic Repressor

13-05-2013 | Author(s): Vikas Bhat , Max B. Olenick , Brett J. Schuchardt , David C. Mikles , Brian J. Deegan , Caleb B. Mc ..., Biophysical Chemistry, 2013

Publication date: Available online 7 May 2013 Source:Biophysical Chemistry Author(s): Vikas Bhat , Max B. Olenick , Brett J. Schuchardt , David C. Mikles , Brian J. Deegan , Caleb B. McDonald , Kenneth L. Seldeen , Dmitry Kurouski , Mohd Hafeez Faridi , Mohammed M. Shareef , ...

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Enhanced Emission and Analyte Sensing by Cinchonine Iridium(III) Cyclometalated Complexes Bearing Bent Diphosphine Chelators

13-05-2013 | Shao-Xiong Luo; Lu Wei; Xin-Hai Zhang; Min Hwee Lim; K. X. Vivian Lin; M. H. Valerie Yeo; Wen-Hua Zhang; Zhi-Pan Liu ..., Organometallics, 2013

Ir(III) complexes of cyclometalating ligands derived from the natural product cinchonine and bent (4,6-bis(diphenylphosphino)phenoxazine (Nixantphos), 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (Xantphos)) and planar diphosphine ligands (1,2-bis(diphenylphosphino)benzene (dppb)) exhibit ...

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Relationships among aerosol water soluble organic matter, iron and aluminum in European, North African, and Marine air masses from the 2010 US GEOTRACES cruise

12-05-2013 | Author(s): Andrew S. Wozniak , Rachel U. Shelley , Rachel L. Sleighter , Hussain A.N. Abdulla , Peter L. Morton ..., Marine Chemistry, 2013

Publication date: Available online 9 May 2013 Source:Marine Chemistry Author(s): Andrew S. Wozniak , Rachel U. Shelley , Rachel L. Sleighter , Hussain A.N. Abdulla , Peter L. Morton , William M. Landing , Patrick G. Hatcher The atmospheric delivery of soluble and bioavailable ...

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The Al(ORF)3/H2O/Phosphane [RF = C(CF3)3] System – Protonation of Phosphanes and Absolute Brønsted Acidity

10-05-2013 | Anne Kraft, Josephine Possart, Harald Scherer, Jennifer Beck, Daniel Himmel, Ingo Krossing, European Journal of Inorganic Chemistry, 2013

Abstract The synthesis of the classical, neutral donor–acceptor adducts Ph2MeP–/Ph3P–/Ph3As–Al(ORF)3 and H2O–Al(ORF)3 [1, 2, 3, 4, ORF = OC(CF3)3] is reported. The intermediate H2O–Al(ORF)3 (4) was generated by substitution of PhF in PhF–Al(ORF)3 with H2O and was analyzed in a long‐term ...

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Identifying Nanoscale M13 Clusters in the Solid State and Aqueous Solution: Vibrational Spectroscopy and Theoretical Studies

09-05-2013 | Milton N. Jackson, Jr.; Lindsay A. Wills; I-Ya Chang; Matthew E. Carnes; Lawrence F. Scatena; Paul Ha-Yeon Cheong; D ..., Inorganic Chemistry, 2013

Raman spectroscopy, infrared spectroscopy, and quantum mechanical computations were used to characterize and assign observed spectral features, highlight structural characteristics, and investigate the bonding environments of [M13(μ3-OH)6(μ2-OH)18(H2O)24](NO3)15 (M = Al or Ga) nanoscale ...

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Zirconium complexes bearing bis(phenoxy‐imine) ligands with bulky o‐bis(aryl)methyl‐substituted aniline groups: synthesis, characterization and ethylene polymerization behavior

08-05-2013 | Aike Li, Haiyan Ma, Jiling Huang, Applied Organometallic Chemistry, 2013

A series of bis(phenoxy‐imine) zirconium complexes bearing bulky o‐bis(aryl)methyl‐substituted aryl groups on the aniline moiety have been synthesized, characterized and tested as catalyst precursors for ethylene polymerization. 1H NMR spectroscopy suggests that these complexes exist as a ...

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Mono- and Polynuclear Copper(II) Complexes of Alloferons 1 with Point Mutations (H6A) and (H12A): Stability Structure and Cytotoxicity

08-05-2013 | Mariola Kuczer; Marta Błaszak; Elzbieta Czarniewska; Grzegorz Rosiński; Teresa Kowalik-Jankowska, Inorganic Chemistry, 2013

Mononuclear and polynuclear copper(II) complexes of the alloferons 1 (Allo1) with point mutations (H6A) H1GVSGA6GQH9GVH12G-COOH (Allo6A) and (H12A) H1GVSGH6GQH9GVA12G-COOH (Allo12A) have been studied by potentiometric, UV–visible, CD, EPR spectroscopic, and mass spectrometry (MS) methods. ...

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