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1,321 Newest Publications about the topic solution

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Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts

30-Aug-2015 | Author(s): Thibaut Stoll, Carmen E. Castillo, Megumi Kayanuma, Martina Sandroni, Chantal Daniel, Fabrice ..., Coordination Chemistry Reviews, 2015

Publication date: 1 December 2015 Source:Coordination Chemistry Reviews, Volumes 304–305 Author(s): Thibaut Stoll, Carmen E. Castillo, Megumi Kayanuma, Martina Sandroni, Chantal Daniel, Fabrice Odobel, Jérôme Fortage, Marie-Noëlle Collomb Solar driven water-splitting into ...

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Probing the Structure, Composition, and Spatial Distribution of Ligands on Gold Nanorods

28-Aug-2015 | Michael J. A. Hore; Xingchen Ye; Jamie Ford; Yuzhi Gao; Jiayang Fei; Qiong Wu; Stuart J. Rowan; Russell J. Composto; ..., Nano Letters, 2015

The structure and size of ligands attached to the surfaces of gold nanorods, such as adsorbed surfactants or grafted polymers, are important considerations that facilitate the use of such nanoparticles in the human body, in advanced materials for energy harvesting, or in devices for single ...

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Surfactant Directed Growth of Gold Metal Nanoplates by Chemical Vapor Deposition

27-Aug-2015 | Matthew B. E. Griffiths; Sara E. Koponen; David J. Mandia; Jennifer F. McLeod; Jason P. Coyle; Jeffrey J. Sims; Javi ..., Chemistry of Materials, 2015

Surface supported, low dimensional gold nanostructures are of interest for plasmonic applications. Low dimensional nanostructures are readily accessible by solution-phase growth, where shape control through the addition of growth-directing surfactants is well established. Yet, shape control in ...

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Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity

27-Aug-2015 | Yuesheng Liu; Lei Wang; Liang Deng, Organometallics, 2015

The reaction of [(IPr2Me2)2FePh2] with PhC≡CPh furnished a three-coordinate iron(II) dialkenyl complex, [(IPr2Me2)Fe(σ-CPh═CPh2)2] (1, IPr2Me2 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene), that represents a rare example of isolable low-coordinate iron alkenyl complexes with a high-spin ...

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Emissive Ir(III) complexes bearing thienylamido groups on a 1,10-phenanthroline scaffold

26-Aug-2015 | Ashlee J. Howarth; Marek B. Majewski; Christopher M. Brown; Francesco Lelj; Michael O. Wolf; Brian O. Patrick, Dalton Transactions, 2015

The synthesis, structures and photophysical properties of a series of bis-cyclometallated Ir(iii) complexes bearing phenylpyrazole (ppz) cyclometallating ligands and phenanthroline-based ancillary ligands containing thienyl- and bithienylamido groups are reported. All complexes are emissive in ...

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Tricarbonyl 99mTc(I) and Re(I)–thiosemicarbazone complexes: synthesis, characterization and biological evaluation for targeting bacterial infection

26-Aug-2015 | Dipak Kumar Nayak; Rinku Baishya; Ramalingam Natarajan; Tuhinadri Sen; Mita Chatterjee Debnath, Dalton Transactions, 2015

Methyl, ethyl and phenyl nitrofuryl thiosemicarbazone ligands (1, 2 and 3 respectively) were radiolabeled with freshly prepared aqueous solution of a fac[99mTc(CO)3(H2O)3]+ precursor. The radiochemical yield was around 98% as determined by thin layer chromatography and HPLC. The complexes ...

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Coordination Structure Conversion of Hydrazone–Palladium(II) Complexes in the Solid State and in Solution

25-Aug-2015 | Fumi Kitamura; Kana Sawaguchi; Asami Mori; Shoji Takagi; Takayoshi Suzuki; Atsushi Kobayashi; Masako Kato; Kiyohiko ..., Inorganic Chemistry, 2015

We prepared hydrazone–palladium(II) complexes of [PdCl2(HLn)] and [PdCl(Ln)] (n = 1–3) by the reaction of [PdCl2(cod)] or [PdCl2(PhCN)2] and the hydrazone ligands of HLn {N′-(pyridin-2-ylmethylene)picolinohydrazide (HL1), N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide (HL2), and ...

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Fine-Tuning of Magnetic Properties in Nickel(II) Trinuclear EMACs via Modifications of Equatorial Ligands

25-Aug-2015 | P. Szarek; W. Grochala, Journal of Physical Chemistry A, 2015

The relationship between equatorial ligands structures and magnetic response of [Ni3]6+ extended metal atom chain core has been investigated. The distances between metal ions in Ni metal strings are largely predefined by framework provided through equatorial ligands. The equatorial ligands thus ...

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Controlling Solid–Gas Reactions at Nanoscale for Enhanced Thin Film Morphologies and Device Performances in Solution-Processed Cu2ZnSn(S,Se)4 Solar Cells

25-Aug-2015 | Chengyang Jiang; Yao-Tsung Hsieh; Hongxiang Zhao; Huanping Zhou; Yang Yang, Journal of the American Chemical Society, 2015

Using Cu2ZnSn(S,Se)4 (CZTSSe) as a model system, we demonstrate the kinetic control of solid–gas reactions at nanoscale by manipulating the surface chemistry of both sol–gel nanoparticles (NPs) and colloidal nanocrystals (NCs). Specifically, we first identify that thiourea (commonly used as ...

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A two‐dimensional cadmium(II) polymer based on nicotinic acid and thiocyanate ligands

25-Aug-2015 | Lin Zhou, Hui‐Ting Wang, Acta Crystallographica Section C, 2015

A cadmium–thiocyanate complex, poly[[bis(nicotinic acid‐κN)di‐μ‐thiocyanato‐κ2N:S;κ2S:N‐cadmium(II)] monohydrate], {[Cd(NCS)2(C6H5NO2)2]·H2O}n, was synthesized by the reaction of nicotinic acid, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, ...

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