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Photocatalysis of Bi4NbO8Cl hierarchical nanostructure for degradation of dye under Solar/UV irradiation

25-Feb-2015 | Swetha S M Bhat; Nalini Sundaram, New Journal of Chemistry, 2015

Bi4NbO8Cl nanostructure has been synthesized from solution combustion synthesis. Morphology evaluated by scanning electron microscopy (SEM), showed rattle shaped particles and nano- petals. Band gap measured for the nanostructure and bulk-Bi4NbO8Cl was found to be 3.4 eV and 2.6 eV respectively. ...

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Influence of Processing Conditions on Properties of Poly (Vinyl acetate)/Cellulose Nanocrystal Nanocomposites

19-Feb-2015 | Janak Sapkota, Sandeep Kumar, Christoph Weder, E. Johan Foster, Macromolecular Materials and Engineering, 2015

We investigated how different processing methods affect the morphology and mechanical properties of nanocomposites made from poly(vinyl acetate) (PVAc) and cellulose nanocrystals (CNCs). Homogeneously mixed reference PVAc/CNC nanocomposites of various compositions were first prepared by ...

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Self-Aggregation of Amphiphilic Dendrimer in Aqueous Solution: The Effect of Headgroup and Hydrocarbon Chain Length

19-Feb-2015 | Pei Zhang; Xiaohui Xu; Minghui Zhang; Jinben Wang; Guangyue Bai; Haike Yan, Langmuir, 2015

The self-aggregation of amphiphilic dendrimers G1QPAMCm based on poly(amidoamine) PAMAM possessing the same hydrophilic group but differing in alkyl chain length in aqueous solution was investigated. Differences in the chemical structures lead to significant specificities in the aggregate ...

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γ Irradiation effects on optical, thermal, and mechanical properties of polysulfone/MWCNT nanocomposites in argon atmosphere

18-Feb-2015 | Soumen Kumar Ghosh, Tapan Kumar Chaki, Dipak Khastgir, Richard Pinto, Journal of Applied Polymer Science, 2015

ABSTRACT Polymer‐based composites find use in many nuclear and space application for their ease of fabrication, tailor made properties and light weight. Certain polymers like PTFE, unfilled polyesters and polyamides are prone to degradation in presence of high energy radiation while polymers ...

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Printing Patterned Fine 3D Structures by Manipulating the Three Phase Contact Line

16-Feb-2015 | Lei Wu, Zhichao Dong, Minxuan Kuang, Yanan Li, Fengyu Li, Lei Jiang, Yanlin Song, Advanced Functional Materials, 2015

The preparation of fine 3D microstructures is an attractive issue; however, it is limited at large‐area fabrication process and fineness morphology manipulation. Here, we propose a strategy to fabricate controllable 3D structures and morphologies from one single droplet via ink‐jet printing. ...

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Effect of aliphatic diacyl adipic dihydrazides on the crystallization of poly (lactic acid)

16-Feb-2015 | Zhongfei Qi, Yong Yang, Zhu Xiong, Jun Deng, Ruoyu Zhang, Jin Zhu, Journal of Applied Polymer Science, 2015

ABSTRACT A series of aliphatic diacyl adipic dihydrazides (ADHs) with different alkyl moieties were synthesized by the reaction between adipic dihydrazide and acyl chloride. Then these ADHs were solution blended with PLA respectively and were evaluated as nucleating agents. Through the ...

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Branched Micelles by Living Crystallization-Driven Block Copolymer Self-Assembly under Kinetic Control

09-Feb-2015 | Huibin Qiu; Yang Gao; Van An Du; Rob Harniman; Mitchell A. Winnik; Ian Manners, Journal of the American Chemical Society, 2015

We have found that the width and shape (from rectangular to elliptical, to almost circular in cross-section) of the crystalline core of fiberlike micelles of polyferrocenyldimethylsilane (PFDMS) diblock copolymers can be varied by altering the degree of polymerization of PFDMS, and also the ...

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Design, synthesis, and aggregation behavior of sandwich mixed (phthalocyaninato)(porphyrinato) europium triple-deckers: Effect of substituent on tuning the intermolecular interaction

05-Feb-2015 | Author(s): Dameng Gao , Xia Zhang , Jsiufeng Luan , Yanli Chen, Inorganic Chemistry Communications, 2015

Publication date: Available online 4 February 2015 Source:Inorganic Chemistry Communications Author(s): Dameng Gao , Xia Zhang , Jsiufeng Luan , Yanli Chen Two new sandwich mixed (phthalocyaninato)(porphyrinato) europium triple-decker (TDMAPP)Eu2[Pc(OPh)8]2 (1) and (TPyP)Eu2[Pc(OPh)8]2 ...

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Hydrothermal Continuous Flow Synthesis and Exfoliation of NiCo Layered Double Hydroxide Nanosheets for Enhanced Oxygen Evolution Catalysis

02-Feb-2015 | Hanfeng Liang; Fei Meng; Miguel Cabán-Acevedo; Linsen Li; Audrey Forticaux; Lichen Xiu; Zhoucheng Wang; Song Jin, Nano Letters, 2015

We report the controlled synthesis of NiCo layered double hydroxide (LDH) nanoplates using a newly developed high temperature high pressure hydrothermal continuous flow reactor (HCFR), which enables direct growth onto conductive substrates in high yield and, most importantly, better control of ...

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Lysine residues in the N‐terminal huntingtin amphipathic α‐helix play a key role in peptide aggregation

19-Jan-2015 | James R. Arndt, Robert J. Brown, Kathleen A. Burke, Justin Legleiter, Stephen J. Valentine, Journal of Mass Spectrometry, 2015

Huntington's disease is a genetic neurodegenerative disorder caused by an expansion in a polyglutamine domain near the N‐terminus of the huntingtin (htt) protein that results in the formation of protein aggregates. Here, htt aggregate structure has been examined using hydrogen–deuterium exchange ...

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