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Synthesis and Self‐Assembly of o‐Nitrobenzyl‐Based Amphiphilic Hybrid Polymer with Light and pH Dual Response

16-Apr-2015 | Shasha Li, Sha Ji, Zheng Zhou, Guangxin Chen, Qifang Li, Macromolecular Chemistry and Physics, 2015

In this paper, novel light‐responsive polyhedral oligomeric silsesquioxane (POSS) end‐capped poly(o‐nitrobenzyl methacrylate) (POSS–PNBMA) are synthesized by the combination of atom transfer radical polymerization (ATRP) and click chemistry. After subsequent partial photocleavage of PNBMA ...


Growth and characterization of thin oriented Co3O4 (111) films obtained by decomposition of layered cobaltates NaxCoO2

12-Apr-2015 | Author(s): Josef Buršík , Miroslav Soroka , Radomír Kužel , Filip Mika, Journal of Solid State Chemistry, 2015

Publication date: July 2015 Source:Journal of Solid State Chemistry, Volume 227 Author(s): Josef Buršík , Miroslav Soroka , Radomír Kužel , Filip Mika The formation and structural characterization of highly (111)-oriented Co3O4 films prepared by a novel procedure from weakly ...


Electrochemical deposition of bismuth on activated graphene-nafion composite for anodic stripping voltammetric determination of trace heavy metals

12-Apr-2015 | Author(s): Sohee Lee , Sungyool Bong , Jeonghyun Ha , Minjeong Kwak , Seung-Keun Park , Yuanzhe Piao, Sensors and Actuators B: Chemical, 2015

Publication date: August 2015 Source:Sensors and Actuators B: Chemical, Volume 215 Author(s): Sohee Lee , Sungyool Bong , Jeonghyun Ha , Minjeong Kwak , Seung-Keun Park , Yuanzhe Piao In this study, we report the first example of a bismuth film electrode plated in situ using activated ...


The unique morphology role of thorn surface in determining electrochemical performance of polyaniline nano‐fibers via one‐step method

10-Apr-2015 | Hai‐yan Wang, Lan Li, Long Zhang, Fen Ran, Journal of Applied Polymer Science, 2015

ABSTRACT Polyaniline nano‐fibers with thorn surface morphology (T‐PANI) were synthesized by one‐step polymerization with adding additional aniline at later stage of chemical oxidation synthesis. In order to investigate the morphology role in determining electrochemical performance, the ...


Characterization of HA/FHA Coatings on Smooth and Rough Implant Surface by Pulsed Electrodeposition

08-Apr-2015 | Fatima Bir, Hafit Khireddine, Dalila Ksouri, Hicham Benhayoune, Anthony Maho, International Journal of Applied Ceramic Technology, 2015

In this work, hydroxyapatite (HA) and fluorohydroxyapatite (FHA) coatings have been successfully synthesized with an electrochemical deposition method, using pulsed current deposition mode on smooth and rough 316L stainless steel implant surfaces. The impact of the variation of the current ...


Effects of blend composition on the morphology of Si‐PCPDTBT:PC71BM bulk heterojunction organic solar cells

07-Apr-2015 | Rui Lin, Matthew Wright, Binesh Puthen‐Veettil, Xiaoming Wen, Murad J. Y. Tayebjee, Ashraf Uddin, physica status solidi (a), 2015

This work investigates the effects of the solution blend composition on the morphology of binary bulk heterojunction organic solar cells composed of poly[2,1,3‐benzothiadiazole‐4,7‐diyl[4,4‐bis(2‐ethylhexyl)‐4H‐cyclopenta2,1‐b:3,4‐b′]dithiophene‐siloe 2,6‐diyl]] (Si‐PCPDTBT) and [6,6]‐phenyl ...


Bio-molecule Assisted Aggregation of ZnWO4 Nanoparticles (NPs) into Chain-like Assemblies: Material for High Performance Supercapacitor and as Catalyst for Benzyl Alcohol Oxidation

06-Apr-2015 | Sivasankara Rao Ede; Ananthakumar Ramadoss; U. Nithiyanantham; S. Anantharaj; Subrata Kundu, Inorganic Chemistry, 2015

ZnWO4 nanoparticles (NPs) that are assembled and aggregated together as chain-like morphology have been synthesized via the reaction of Zn(II) salt solution with sodium tungstate in the presence of the DNA scaffold under 5 min of microwave heating. The reaction parameters have been tuned to ...


Antimicrobial polyethylene wax emulsion and its application on active paper‐based packaging material

04-Apr-2015 | Xiang Xu, Anna Zheng, Xiaodong Zhou, Yong Guan, Yuanfeng Pan, Huining Xiao, Journal of Applied Polymer Science, 2015

ABSTRACT Antimicrobial polyethylene wax (PEW) emulsions, prepared by emulsifying polyethylene wax grafted with polyhexamethylene guanidine hydrochloride (PEW‐g‐PHGH), were used as wet‐end additives or coating materials for fabricating hydrophobic and anti‐mold hand‐sheets or paper. To obtain ...


Electrochromic Bis(terpyridine)metal Complex Nanosheets

02-Apr-2015 | Kenji Takada; Ryota Sakamoto; Shi-Ting Yi; Shunsuke Katagiri; Tetsuya Kambe; Hiroshi Nishihara, Journal of the American Chemical Society, 2015

A series of electrochromic metal complex nanosheets comprising 1,3,5-tris(4-(2,2′:6′,2″-terpyridyl)phenyl)benzene or 1,3,5-tris((2,2′:6′,2″-terpyridyl)ethynyl)benzene and Fe2+ or Co2+ was synthesized. The preparation of multilayered nanosheets was achieved by liquid/liquid interfacial synthesis ...


Structural, morphological and steady state photoluminescence spectroscopy studies of red Eu3+‐doped Y2O3 nanophosphors prepared by the sol‐gel method

01-Apr-2015 | Lyes Lamiri, Lakhdar Guerbous, Madani Samah, Allaoua Boukerika, Salim Ouhenia, Luminescence, 2015

Abstract Europium trivalent (Eu3+)‐doped Y2O3 nanopowders of different concentrations (0.5, 2.5, 5 or 7 at.%) were synthesized by the sol‐gel method, at different pH values (pH 2, 5 or 8) and annealing temperatures (600°C, 800°C or 1000°C). The nanopowders samples were characterized by X‐ray ...


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